File name: Pandora39s1_DearbornMI_20250220_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250221T060158.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20250220_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20250220 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250220T140612.4Z 9182.587644 258 1 48.00 2 73.04 122.68 78.31 218.30 0.00 1 0.00 1 0 17 3.599e-01 8.840e-03 2.566e-01 6.563e-03 6.292246e-01 3.500586e-03 7.091896e-03 -6.000000e+00 2.065385e-01 224.95 -2.00 3.54 -2.00 320.78 0.00e+00 9.954919e-04 1.390853e-03 7.905573e-04 -6.000000e+00 8.924973e-03 273.43 -2.00 20.00 -2.00 320.31 0.00e+00 3.377 0.001 302.00 328.00 3 4.6013e+00 1.0671e-02 4.6664e-02 -6.0000e+00 5.1124e-01 7.3885e-02 1.4027e-02 3.3213e-02 -6.0000e+00 5.5644e-01 -4.3301e-02 1.4582e-02 1.8019e-02 -6.0000e+00 3.3043e-01 1.4344e-03 7.2674e-03 6.0862e-03 -6.0000e+00 1.4146e-01 8.9144e-05 5.6590e-05 1.9235e-04 7.2892e-05 -6.0000e+00 1.0188e-02 8.6144e-03 -8.2856e-05 11 8 0 10 0 0 98.41 21.80 0.36 0.00861 0.00904 21 5 1 5 0 2285.470 25.90 20.00 21.80 -1.65 21.1 895.54 900000 -152592 -130181 47541 88598 -134029 195013 -95517 -67876 -35056 978 -103864 -103729 -3810 6170 158636 8921 -18483 36298 -7678 14139 11920 -2164 -35751 10694 -92 4072 -4846 14423 7007 5343 43973 -15316 10909 -13106 4898 -83 -8923 3537 -26 -2012 471 -3649 915 6248 -7544 897 1454 -1307 5544 1873 -3724 4834 -1504 -1329 3668 1983 -1169 1765 881 4583 4954 3913 962 2411 3897 -1462 -260 1773 1206 1181 3359 -1053 1738 -1194 -2653 624 -274 -2577 -3774 -245 -1220 -543 -2119 -1717 -410 -770 -611 387 778 814 1731 30 250 -394 -422 397 1284 45 22 434 -1495 -658 135 -1060 -74 -609 -1169 -256 1324 518 -287 185 302 -1108 -107 324 99 657 -721 643 -38 381 296 352 449 -115 812 -110 -715 266 -664 -289 446 -83 -355 21 1008 -22 -142 303 -740 -242 900000 -2441 -1811 304 567 -1790 1248 -1116 -680 -286 6 -2052 -2489 -45 81 1015 149 -429 545 -188 283 249 -56 -1363 289 -3 119 -150 385 215 198 1358 -898 532 -751 251 -5 -683 293 -3 -233 57 -479 117 766 -1083 121 201 -195 833 313 -732 953 -343 -320 873 491 -296 421 210 1095 1301 1175 330 843 1308 -515 -94 693 541 579 1669 -537 810 -521 -1056 226 -102 -1096 -1909 -139 -792 -382 -1543 -1329 -333 -655 -530 331 636 641 1263 22 183 -323 -382 410 1491 56 28 511 -1625 -650 132 -1119 -81 -712 -1468 -347 1889 820 -483 310 487 -1709 -156 469 148 1036 -1197 1048 -61 579 450 511 626 -156 1121 -170 -1196 482 -1299 -570 920 -182 -827 51 2411 -54 -332 663 -1546 -502 SS 20250220T144249.0Z 9182.613067 285 1 49.24 2 67.59 130.28 82.74 225.11 0.00 1 0.00 1 0 17 2.737e-01 7.714e-03 2.317e-01 7.749e-03 4.911526e-01 4.049985e-03 5.652506e-03 -6.000000e+00 1.572179e-01 224.95 -2.00 3.54 -2.00 320.17 0.00e+00 3.848045e-03 1.313215e-03 3.003076e-04 -6.000000e+00 6.737065e-03 273.44 -2.00 20.00 -2.00 319.67 0.00e+00 2.601 0.000 302.00 328.00 3 5.0682e+00 1.1724e-02 3.6177e-02 -6.0000e+00 3.8921e-01 -7.3102e-04 1.4225e-02 2.6054e-02 -6.0000e+00 4.2338e-01 4.4478e-02 1.2978e-02 1.3809e-02 -6.0000e+00 2.5133e-01 -3.3874e-02 6.7250e-03 6.7306e-03 -6.0000e+00 1.0690e-01 1.3620e-04 9.2099e-04 2.3622e-04 6.5831e-05 -6.0000e+00 7.7140e-03 6.5962e-03 1.2285e-04 11 9 0 11 8 0 99.98 21.80 0.18 0.00660 0.01352 115 26 1 5 0 428.120 25.90 20.00 21.80 -1.04 20.9 899.09 185495 116388 -12632 195570 -75519 -11753 42734 71781 -23406 -1161 3447 -15024 18543 4309 -5887 11803 5127 -353 -830 -7566 -12440 -131 -15593 1663 -11324 3272 301 -1483 -6619 -5381 16664 864 6103 -8507 -96 -1935 4099 -4829 -1441 35 2349 -1176 -6605 1282 -3248 -1074 -3449 -2135 672 3274 2492 4304 2865 -2190 3292 2181 -1237 -2232 350 1630 540 2395 1921 3761 -2200 1477 690 -1452 -1094 574 984 69 654 -259 427 -1439 -1440 -2215 1686 508 -1883 -42 -1479 -1265 -521 160 -205 164 1654 148 1579 1160 356 -641 423 -1281 1679 10 -295 -821 355 -665 -813 583 203 -1612 -1307 -378 -495 -43 154 560 284 269 100 -190 765 -102 310 -184 -746 258 183 143 -282 357 35 1741 667 -113 3 -1020 333 -533 146 -287 15 917 -30 5 -385 -41 -276 1402 879 -171 1478 -1598 -140 341 542 -407 -18 53 -307 336 107 -197 382 196 -15 -37 -382 -671 -6 -921 89 -727 190 18 -88 -409 -357 1025 68 515 -858 -9 -178 397 -581 -203 6 411 -227 -1406 258 -694 -229 -761 -473 149 745 601 1118 815 -702 1044 720 -430 -778 116 533 187 892 803 1687 -1067 662 303 -661 -541 317 591 43 404 -153 230 -710 -660 -1018 816 288 -1254 -31 -1144 -1030 -449 146 -197 161 1598 139 1360 967 282 -516 367 -1229 1779 12 -385 -1067 428 -741 -839 596 223 -1907 -1618 -492 -694 -66 253 954 479 433 151 -272 1078 -151 483 -301 -1239 414 285 214 -403 486 46 2375 963 -180 5 -1880 628 -1061 306 -637 33 2102 -71 10 -830 -84 -546 SS 20250220T155043.6Z 9182.660227 331 1 49.14 2 59.22 146.46 92.27 236.57 0.00 1 0.00 1 0 17 5.380e-02 7.933e-03 5.195e-02 6.175e-03 3.664610e-01 3.131310e-03 4.335229e-03 -6.000000e+00 3.089405e-02 224.95 -2.00 3.54 -2.00 319.06 0.00e+00 -1.140933e-04 7.192816e-04 1.985206e-04 -6.000000e+00 1.324419e-03 273.44 -2.00 20.00 -2.00 318.52 0.00e+00 1.946 0.000 302.00 328.00 3 5.9519e+00 8.5717e-03 2.6812e-02 -6.0000e+00 7.6480e-02 2.0172e-02 9.8579e-03 1.8689e-02 -6.0000e+00 8.3204e-02 4.1432e-03 7.2139e-03 9.4386e-03 -6.0000e+00 4.9392e-02 -1.2418e-02 3.8054e-03 2.7671e-03 -6.0000e+00 2.1002e-02 1.2514e-04 2.6416e-04 1.8759e-04 3.1900e-05 -6.0000e+00 1.5166e-03 7.4066e-03 6.1505e-05 11 9 0 11 8 0 99.99 21.81 0.53 0.00741 0.00939 33 7 1 5 0 1488.910 26.00 20.00 21.81 1.06 21.3 913.80 -8152 9124 -7837 -16307 -8452 13889 -28391 38962 7086 -2363 -790 9330 13077 1113 -4057 2129 4201 -1708 5878 -1067 -1602 -2449 -10336 -2459 1318 -968 -6682 629 -9593 -2094 1715 2709 45 5158 1465 -4803 1198 -4838 810 -1381 -1271 -287 2057 -738 121 45 -3467 1358 -1688 2871 2008 -51 2186 -862 39 188 2899 -97 -82 -110 1298 2213 2222 1982 -49 -631 -1352 2624 931 140 -68 -558 -498 554 882 -1590 1268 -1601 946 -1822 -1497 -2246 -2134 -757 -576 269 -47 1069 345 1348 -96 1401 98 -151 444 -980 514 1119 759 -325 -145 -1275 -893 40 -1243 -1114 -517 -802 61 258 406 228 39 -166 -299 -452 616 -679 587 -29 -796 608 982 370 380 372 -322 1321 -173 -85 -85 -623 -20 79 777 248 -162 309 78 -88 263 -813 -644 -315 323 -332 -696 -305 422 -1382 1142 304 -117 -39 454 715 77 -345 189 388 -177 592 -120 -183 -283 -1354 -319 175 -136 -988 81 -1312 -274 237 410 8 847 236 -834 218 -1104 202 -411 -412 -97 699 -260 42 16 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