File name: Pandora103s1_Downsview_20171210_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T223512.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20171210_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20171210 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171210T124726.0Z 6553.532940 1 1 36.00 2 89.87 122.84 41.73 209.13 0.00 1 0.00 1 0 26 1.138e-01 1.021e-01 1.029e-01 9.811e-02 3.878546e+03 6.112955e+03 2.298230e+02 -6.000000e+00 5.707574e+03 274.31 -2.00 20.00 -2.00 505.18 0.00e+00 -9.783214e-04 2.583641e-03 7.501152e-05 -6.000000e+00 3.054678e-03 274.31 -2.00 20.00 -2.00 499.57 0.00e+00 2.626412e+00 1.998640e+00 3.392379e-02 -6.000000e+00 2.184781e+00 222.25 -2.00 3.57 -2.00 501.27 0.00e+00 20.519 0.168 489.00 513.00 1 1.0089e+01 1.5278e-01 3.7198e-02 -6.0000e+00 1.6646e-01 1.7259e-01 4.0158e-02 2.1569e-03 -6.0000e+00 4.4253e-02 3.8364e-06 -1.1930e-03 7.1969e-03 3.1710e-05 -6.0000e+00 8.8746e-03 3.1615e-02 1.4079e-04 12 8 8 10 0 0 11.52 15.00 6.87 0.03162 0.02334 9 1 1 4 0 4000.000 21.88 15.00 18.81 -10386 8620 10951 -9947 -15199 5689 -967 -1086 -3815 6978 3614 36867 2431 -497 -5875 25284 7442 -125 -15821 -1618 3438 8010 991 3457 489 8275 10243 -5964 -5797 -4382 5384 -9698 9816 -11557 15024 -14629 5897 -3352 10923 182 -7604 813 -6212 11349 -5760 10838 -3757 11629 -8179 -3381 -1298 10254 -779 7381 -16422 3362 -7201 20889 1733 3770 -5864 10487 387 -5404 11300 -10150 11317 10504 10781 -12190 4620 11019 -9135 2551 -9334 9074 15772 -10014 11878 -7133 1235 12679 35402 4687 222 -2503 9877 32894 -11099 3206 4164 28866 -6980 4870 -20527 -1658 1228 17638 -15805 12234 7820 24536 5192 -6718 -7890 37336 8683 -4310 -4937 -1889 -9643 7252 -2764 15608 5803 7360 -19437 -4425 -3049 -13959 -3964 -13853 25900 1285 -4206 -7176 -1758 -4336 1571 7191 -7108 11587 279 2080 -13997 827 8880 14946 11877 8170 1088 -2164 22202 5475 891 -3320 -8437 -10148 1584 -249 900000 -11671 8181 10524 -12181 -20044 6236 -1155 -1315 -4738 7687 4037 29543 2673 -553 -6818 21735 7698 -144 -21811 -1968 3968 8847 1167 3980 583 9130 11012 -7453 -7044 -5012 5460 -11413 9738 -14730 15357 -19994 6497 -3974 11100 202 -9092 899 -7415 11543 -6975 11174 -4423 11602 -9702 -3726 -1349 9234 -766 6733 -19452 3411 -8276 18384 1824 3850 -6551 10059 410 -6040 10627 -11519 10207 9401 9519 -13194 4186 9410 -9574 2427 -10096 8124 12867 -10223 9711 -6961 1114 10345 23295 4168 209 -2441 8540 22680 -11648 2929 3781 20923 -7275 4521 -23845 -1564 1096 13054 -15719 9065 6002 16314 4325 -6619 -8102 24686 7432 -4086 -4632 -1732 -9696 6277 -2660 12630 5161 6461 -22309 -4417 -2973 -14830 -3745 -14098 17824 1133 -3937 -6890 -1601 -4025 1371 5975 -6728 8931 235 1705 -13344 697 7136 11530 9545 6886 986 -2028 16553 4821 821 -3163 -8255 -9766 1328 -212 900000 SO 20171210T124924.0Z 6553.534306 3 1 36.00 2 89.57 123.18 41.91 209.80 0.00 1 0.00 1 0 15 8.865e-02 8.205e-02 8.185e-02 7.944e-02 8.078920e+03 5.080092e+03 9.137848e+02 -6.000000e+00 4.442103e+03 274.31 -2.00 20.00 -2.00 505.16 0.00e+00 7.387165e-04 2.065499e-03 9.746605e-06 -6.000000e+00 2.380208e-03 274.31 -2.00 20.00 -2.00 499.76 0.00e+00 -1.163238e+00 1.591726e+00 2.501029e-02 -6.000000e+00 1.706314e+00 222.25 -2.00 3.57 -2.00 501.42 0.00e+00 20.064 0.157 489.00 513.00 1 1.0184e+01 1.2081e-01 3.5633e-02 -6.0000e+00 1.2992e-01 2.2060e-01 3.2318e-02 2.0047e-03 -6.0000e+00 3.4681e-02 4.7883e-06 -1.8349e-03 5.8530e-03 9.7054e-05 -6.0000e+00 6.9122e-03 6.1111e-02 -2.7360e-04 12 8 8 10 0 0 71.05 15.00 1.51 0.06111 0.04838 9 1 1 4 0 4000.000 21.88 15.00 18.81 -1494 292 4372 1790 3419 1770 3713 673 -6282 -2139 -4354 -2603 -9360 -1326 -7834 -2044 2523 6037 -3051 3061 -3715 -832 -2548 -8864 -424 16676 6594 3435 6152 -1016 9356 -533 6387 5466 6538 -99 2252 -10951 4568 -276 -467 819 10335 -7947 10735 -1896 11676 -6957 -660 -6887 -3222 9841 19127 5917 -12922 -5819 -8102 -6990 -1633 5282 -2359 10265 197 1534 5612 9648 -15107 1127 -3403 15832 -8052 9109 -1126 -2083 4211 8607 2634 -1640 4508 -12865 7053 -8344 16041 -14083 14456 -2796 10441 5488 -285 -9329 1091 16304 5418 9525 14847 5921 -10418 20621 11063 -6051 -8189 -3818 -7177 6574 -14299 16378 -1065 1854 -8511 5062 -16459 -953 7824 -543 8667 -51 9140 1243 941 -216 22304 -12713 9317 -5866 13620 -10859 15513 -16245 760 -14365 -5627 -6811 9683 -5870 12997 28555 -1165 -2460 21083 1232 15379 1005 2858 -9930 -4015 2257 5596 3507 -2231 -12548 900000 -1513 293 4344 1901 3673 1965 4129 782 -7812 -2522 -5135 -2977 -11252 -1446 -8988 -2210 2630 6219 -3547 3418 -4417 -961 -2982 -11017 -488 16314 7068 3775 6463 -1094 8791 -549 6234 5583 6905 -113 2481 -13484 4768 -297 -502 874 10155 -9430 10756 -2157 11597 -8165 -717 -7770 -3389 8821 15340 5380 -14462 -6328 -9273 -8006 -1773 5316 -2544 9853 210 1613 5636 9165 -17872 1120 -3500 13329 -8393 8032 -1107 -2098 4063 7949 2516 -1590 4064 -13627 6154 -8528 13042 -15395 12155 -2814 9256 5079 -277 -9862 1045 13638 5137 8734 12671 5338 -10662 15147 8684 -5471 -7445 -3360 -6755 5725 -15959 13733 -1045 1732 -8612 4493 -18310 -926 7038 -531 7747 -49 8194 1218 924 -211 17081 -13313 7739 -5665 11009 -11107 12273 -17415 685 -14998 -5385 -6435 7608 -5297 9698 18536 -1036 -2255 15533 1112 12196 917 2569 -10133 -3865 2033 4791 2970 -1938 -11915 900000 SO 20171210T125118.0Z 6553.535625 5 1 36.00 2 89.29 123.51 42.08 210.44 0.00 1 0.00 1 0 22 6.058e-02 5.918e-02 6.707e-02 6.533e-02 -3.679520e+03 3.553907e+03 4.405316e+02 -6.000000e+00 3.035695e+03 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