File name: Pandora103s1_Downsview_20171219_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T225309.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20171219_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20171219 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171219T125404.0Z 6562.537546 1 1 36.00 2 89.87 123.55 97.68 111.37 0.00 1 0.00 1 0 8 9.961e-02 9.288e-02 8.816e-02 8.549e-02 -6.030985e+02 4.588438e+03 1.656707e+02 -6.000000e+00 4.978286e+03 273.48 -2.00 20.00 -2.00 505.21 0.00e+00 3.170479e-03 2.262410e-03 1.932916e-04 -6.000000e+00 2.668699e-03 273.48 -2.00 20.00 -2.00 499.90 0.00e+00 3.889655e+00 1.711953e+00 5.998530e-02 -6.000000e+00 1.915166e+00 222.32 -2.00 3.57 -2.00 501.55 0.00e+00 20.538 0.169 489.00 513.00 1 9.7999e+00 1.3141e-01 3.7656e-02 -6.0000e+00 1.4586e-01 1.1656e-01 3.4476e-02 2.2042e-03 -6.0000e+00 3.8818e-02 4.4374e-06 -2.2575e-03 6.4453e-03 5.3912e-05 -6.0000e+00 7.7680e-03 -2.9961e-02 4.5520e-04 12 8 8 10 0 0 -1.64 15.00 7.59 -0.02996 -0.04562 9 1 1 4 0 4000.000 21.98 15.00 19.01 -8391 20989 -7202 -8920 -3503 17317 7457 7953 -4768 6095 1226 -1109 2713 1260 12085 -4845 4169 2556 1827 -3872 7123 -6048 -12222 9342 22185 6711 -4291 -5894 17728 -10907 35136 7886 2596 -11237 1820 -9154 -10477 -8614 -2414 4686 -3588 1427 -4422 3164 -1 3371 1357 1401 -8243 776 -9633 12133 -9202 10980 21365 22256 -8281 6816 18586 -242 8707 -2103 1163 5191 554 453 -13207 -15751 11098 860 1129 -19548 1339 -8412 2028 -11978 4655 4554 6220 910 13624 5747 -435 -37 -1452 789 -8417 10315 -5001 -3905 -9378 4001 -2686 28168 -2118 509 -1640 6561 1683 -9435 -5994 15793 3753 -15959 11874 6034 -7036 22828 13581 12531 3018 -10873 -8274 3596 441 2614 17916 -6153 5547 1644 11484 -12240 7937 -10917 -12333 -15950 4780 6775 22038 7054 1978 11420 -2939 417 7860 -9810 -3008 9160 -5066 9515 -16214 14755 3042 9112 -3106 935 3344 12362 3228 -7007 900000 -8812 16787 -7827 -10293 -3945 16221 7856 8451 -5734 6506 1343 -1227 2848 1318 11260 -5316 4230 2697 2007 -4573 7533 -7265 -15569 9670 20452 7216 -5110 -7098 16628 -12897 25750 7516 2644 -13623 2029 -11467 -13100 -10408 -2708 4846 -4016 1532 -5088 3426 -2 3704 1513 1539 -9779 824 -10921 10787 -9862 9682 17514 18799 -9654 6925 16792 -260 8544 -2305 1240 5313 588 473 -15381 -18485 9929 834 1074 -22686 1279 -8954 1980 -13313 4287 4091 5434 832 11017 5062 -408 -35 -1390 744 -8666 8813 -4935 -3812 -9686 3678 -2696 21215 -2120 489 -1585 5705 1489 -9028 -5462 11743 3221 -17301 10074 5371 -6958 16534 10595 9949 2684 -11304 -8551 3360 427 2491 14800 -6427 5112 1544 9643 -12741 6758 -11303 -13070 -17488 4293 5950 16647 6200 1822 9392 -2719 368 6392 -9592 -2838 7847 -5041 8302 -18209 12267 2848 8110 -3125 901 3076 10059 2788 -6651 900000 SO 20171219T125602.0Z 6562.538912 3 1 36.01 2 89.58 123.89 97.36 111.68 0.00 1 0.00 1 0 15 7.558e-02 7.405e-02 6.960e-02 6.816e-02 7.655327e+03 4.331731e+03 8.231579e+02 -6.000000e+00 3.776376e+03 273.48 -2.00 20.00 -2.00 505.26 0.00e+00 3.395021e-03 1.782833e-03 2.100505e-04 -6.000000e+00 2.024067e-03 273.48 -2.00 20.00 -2.00 499.96 0.00e+00 8.088667e-01 1.357273e+00 3.084337e-02 -6.000000e+00 1.451971e+00 222.32 -2.00 3.57 -2.00 501.61 0.00e+00 20.086 0.158 489.00 513.00 1 9.8411e+00 1.0311e-01 3.6069e-02 -6.0000e+00 1.1059e-01 1.5969e-01 2.7386e-02 2.0404e-03 -6.0000e+00 2.9421e-02 5.6158e-06 -2.2320e-04 4.9726e-03 9.8196e-05 -6.0000e+00 5.8927e-03 3.5169e-02 9.1198e-05 12 8 8 10 0 0 -6.81 14.99 3.88 0.03517 0.03362 9 1 1 4 0 4000.000 21.98 14.99 19.03 5763 -4127 -7818 10516 1734 10529 -9489 7860 -2786 507 -2751 11169 -3559 -10066 2168 -13399 -5050 3871 2936 2063 2824 16427 -4617 3524 81 3012 6204 -1541 -6777 -8929 -5021 -2192 12715 -12114 -6865 8522 -414 6107 2820 355 -577 5312 9139 3049 2189 21187 -10508 14856 -4494 -3046 -8752 -7382 2284 2370 -13120 6165 -10789 -3627 11443 11575 10128 7314 -3707 -7000 -1822 8087 1128 -7851 -3270 -510 8860 -4738 -2637 1308 5269 11316 8721 -5581 16822 10585 3935 -583 3095 -5201 591 -2294 -5676 4749 3672 2798 2159 8389 5823 16763 -4314 10476 -8822 3545 10223 2483 -2350 -2758 7410 -2948 5008 -2800 55 -4124 10791 -2520 -3298 -12807 3982 -5248 -922 -4479 7884 -10077 2679 -668 1071 -9129 15338 -8636 -265 -14970 -1586 -10310 7679 4597 10099 -272 -7862 5383 -1215 2918 -5471 -3901 -1018 7813 -7900 9503 -1089 18157 -522 6203 644 -11678 4060 11695 900000 5271 -4226 -8610 10101 1856 10536 -11779 8322 -3261 565 -3097 10843 -3918 -11597 2198 -15815 -5558 4011 3166 2268 3065 15622 -5375 3804 91 3301 6558 -1744 -7856 -10079 -5320 -2267 11607 -14715 -8224 8816 -460 6269 2948 376 -619 5422 9109 3270 2396 19341 -12972 14122 -5070 -3303 -9680 -7827 2169 2267 -15080 6105 -12901 -4071 11053 11077 9821 7349 -4163 -8099 -1984 7852 1148 -8588 -3387 -505 7897 -4834 -2663 1292 5073 10162 7811 -5612 13480 8951 3553 -555 2850 -5218 568 -2284 -5820 4366 3384 2594 2024 7530 5471 14161 -4366 8913 -8780 3035 8000 2043 -2006 -2402 6086 -2825 4587 -2764 52 -3974 8890 -2389 -3219 -13925 3714 -5380 -907 -4574 7232 -11110 2590 -654 1008 -9264 12167 -8750 -249 -16254 -1514 -10664 6638 4116 8495 -246 -7519 4484 -1076 2530 -5292 -3768 -965 6883 -8142 8286 -1056 14661 -505 5568 596 -11783 3435 9180 900000 SO 20171219T125756.0Z 6562.540231 5 1 36.00 2 89.29 124.22 97.05 111.98 0.00 1 0.00 1 0 15 6.506e-02 6.258e-02 6.033e-02 5.912e-02 3.235683e+03 3.461993e+03 3.999086e+02 -6.000000e+00 3.250766e+03 273.47 -2.00 20.00 -2.00 505.18 0.00e+00 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