File name: Pandora103s1_Downsview_20180103_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T225354.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180103_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180103 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180103T125816.0Z 6577.540463 1 1 36.01 2 89.87 122.60 80.34 285.20 0.00 1 0.00 1 0 15 4.111e-02 4.054e-02 4.228e-02 4.166e-02 4.340409e+03 2.479565e+03 2.485489e+02 -6.000000e+00 2.046436e+03 272.54 -2.00 20.00 -2.00 505.21 0.00e+00 5.637798e-03 1.089944e-03 2.904300e-04 -6.000000e+00 1.098612e-03 272.54 -2.00 20.00 -2.00 499.94 0.00e+00 2.391434e+00 8.269326e-01 6.206997e-02 -6.000000e+00 7.920750e-01 222.92 -2.00 3.57 -2.00 501.57 0.00e+00 20.547 0.169 489.00 513.00 1 9.1364e+00 6.3096e-02 3.8049e-02 -6.0000e+00 6.0284e-02 1.3864e-01 1.6566e-02 2.2830e-03 -6.0000e+00 1.6076e-02 9.3151e-06 3.0433e-03 3.1285e-03 7.6252e-05 -6.0000e+00 3.2054e-03 4.3323e-02 -7.8879e-05 12 8 8 10 0 0 -4.33 15.00 2.41 0.04332 0.06443 9 1 1 4 0 4000.000 21.98 15.00 18.97 -2135 1238 -9223 2271 3994 -1527 -3089 3558 3313 5509 -5595 2079 -7899 -1103 3497 -1879 -1088 2199 -2721 3702 -2332 2006 10781 4681 1539 -3789 -84 -1089 5727 -2581 3650 -3870 -2017 -139 1204 -4857 -2382 -1413 4821 -1545 8587 136 -2938 3928 1831 -2619 3378 1916 -7409 -933 1079 2708 2521 8230 -3736 1126 5381 3035 -4049 48 -3061 4314 53 -1477 729 -5787 6040 572 -1193 -657 -620 -947 -994 -4910 3971 -6546 9722 1762 -4722 -3453 352 2268 -663 -854 -2900 -959 -438 9745 1063 198 4529 763 -8935 -1114 5434 1845 -2983 52 -4564 2380 -9785 -521 1642 60 2359 294 3943 -3684 -4442 512 -2600 -1501 2737 1963 8940 -977 -1545 -181 -764 1633 -2077 -233 4179 1589 7202 6150 3162 10502 7167 4390 -2923 -3903 -1635 -482 -3722 7655 -2451 -1510 -1447 3094 -6811 -2573 -852 -9073 -2403 3671 -2170 -2094 4362 3977 900000 -2100 1201 -10300 2364 4183 -1718 -3603 3922 3644 5816 -6440 2192 -9012 -1158 3479 -1972 -1145 2302 -3080 3969 -2636 2174 10709 4959 1698 -4414 -94 -1222 5843 -2721 3535 -4052 -2118 -150 1328 -5693 -2682 -1552 4919 -1663 8412 146 -3304 4195 2022 -3030 3664 2077 -8647 -996 1091 2619 2407 7503 -3958 1182 5544 3217 -4581 52 -3401 4499 58 -1631 779 -6462 5882 579 -1214 -653 -607 -932 -987 -5144 3857 -6956 8569 1641 -4639 -3329 328 2086 -628 -812 -2844 -927 -419 8371 986 185 4075 725 -9555 -1108 4981 1711 -2826 46 -4144 1965 -8988 -442 1415 55 2164 273 3472 -3421 -4117 458 -2459 -1433 2545 1857 7928 -959 -1540 -179 -751 1539 -1989 -215 3677 1455 6297 5432 2882 8874 6241 3951 -2801 -3679 -1479 -426 -3381 6344 -2304 -1428 -1381 2854 -6937 -2515 -823 -9536 -2368 3378 -2060 -1919 3665 3357 900000 SO 20180103T130013.0Z 6577.541817 3 1 36.01 2 89.57 122.94 80.67 285.50 0.00 1 0.00 1 0 22 3.946e-02 3.774e-02 3.710e-02 3.656e-02 -2.433502e+03 1.923559e+03 2.303700e+02 -6.000000e+00 1.964052e+03 272.54 -2.00 20.00 -2.00 505.22 0.00e+00 5.649220e-03 9.533304e-04 2.750080e-04 -6.000000e+00 1.054922e-03 272.54 -2.00 20.00 -2.00 499.92 0.00e+00 3.448348e+00 7.251714e-01 3.798770e-02 -6.000000e+00 7.608942e-01 222.92 -2.00 3.57 -2.00 501.57 0.00e+00 20.091 0.158 489.00 513.00 1 9.0008e+00 5.5224e-02 3.6350e-02 -6.0000e+00 5.7900e-02 1.2590e-01 1.4698e-02 2.0113e-03 -6.0000e+00 1.5459e-02 1.0657e-05 7.8976e-04 2.7792e-03 7.2170e-05 -6.0000e+00 3.0765e-03 1.4018e-02 2.8279e-05 12 8 8 10 0 0 23.08 15.00 4.84 0.01402 0.01950 9 1 1 4 0 4000.000 21.98 15.00 18.98 -4239 390 -3104 4637 -35 -3044 2741 -5120 -4493 -2189 -1262 2779 1686 -3684 1046 4056 3728 -3117 8313 2179 -2237 -4086 4661 -2976 1884 -2196 -3809 6027 1870 2837 -735 1464 -2449 -907 2528 -495 -1490 -492 238 -684 811 5389 817 -634 -2857 2691 -1406 9770 -1416 3466 -2782 -4932 -1748 -4564 3263 -429 -1780 -58 -43 3773 -2198 -690 -3659 -5240 377 7259 9207 3483 -725 1589 1754 -5101 -1477 2813 1461 -654 -1674 -16 4342 1278 839 372 -3564 18616 -3961 47 -3391 2697 2397 7483 2542 -2072 -2133 1430 2916 -1082 -3829 -3118 2943 4790 4181 -131 785 -864 1146 1360 -2625 -1040 -4038 -3314 -445 -2485 2909 711 603 -4502 6401 6291 2545 -4847 2693 -5778 -6753 4057 -4456 1631 -7279 2901 -438 6037 665 -966 -2965 2559 -4948 878 2557 6443 352 -4448 1613 2706 -3378 4650 -6699 -2420 3971 -8625 8229 2899 900000 -4255 379 -3233 4680 -38 -3462 3010 -6144 -5350 -2509 -1400 2922 1763 -3985 1068 4019 3737 -3418 8413 2376 -2535 -4707 4925 -3396 2072 -2525 -4433 6342 2005 2875 -746 1454 -2568 -975 2742 -558 -1671 -538 254 -731 855 5487 883 -704 -3291 2953 -1599 9829 -1562 3564 -2937 -5153 -1737 -4672 3184 -452 -1949 -63 -47 3906 -2404 -748 -4106 -5960 403 7111 8658 3404 -730 1536 1661 -5159 -1453 2690 1435 -651 -1640 -15 3870 1166 770 346 -3446 14483 -3870 44 -3304 2462 2184 6490 2322 -2008 -2123 1396 2796 -1069 -3839 -3029 2610 4044 3486 -114 695 -806 1069 1249 -2447 -933 -3679 -3028 -405 -2364 2689 684 586 -4620 5928 5819 2408 -4829 2455 -5647 -6639 3640 -4387 1512 -7372 2654 -413 5376 622 -899 -2751 2210 -4543 769 2270 5626 330 -4403 1506 2493 -3317 4256 -6878 -2372 3571 -8445 6629 2445 900000 SO 20180103T130208.0Z 6577.543148 5 1 36.01 2 89.28 123.27 80.99 285.80 0.00 1 0.00 1 0 29 3.568e-02 3.502e-02 3.417e-02 3.375e-02 -1.533531e+02 1.773433e+03 4.858576e+01 -6.000000e+00 1.776083e+03 272.54 -2.00 20.00 -2.00 505.21 0.00e+00 5.836974e-03 8.805685e-04 2.751371e-04 -6.000000e+00 9.535747e-04 272.54 -2.00 20.00 -2.00 499.97 0.00e+00 2.463456e+00 6.664619e-01 3.823820e-02 -6.000000e+00 6.875089e-01 222.92 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