File name: Pandora103s1_Downsview_20180104_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T225340.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180104_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180104T125812.0Z 6578.540417 1 1 36.01 2 89.87 122.44 71.91 273.56 0.00 1 0.00 1 0 22 1.907e-02 1.899e-02 1.878e-02 1.859e-02 1.497136e+03 1.021860e+03 1.565971e+02 -6.000000e+00 9.489709e+02 272.48 -2.00 20.00 -2.00 505.22 0.00e+00 3.216789e-03 4.848411e-04 1.499196e-04 -6.000000e+00 5.097724e-04 272.48 -2.00 20.00 -2.00 499.96 0.00e+00 2.193618e+00 3.671496e-01 2.110633e-02 -6.000000e+00 3.677326e-01 222.96 -2.00 3.57 -2.00 501.61 0.00e+00 20.550 0.169 489.00 513.00 1 8.3614e+00 2.7992e-02 3.7321e-02 -6.0000e+00 2.7983e-02 1.4208e-01 7.4122e-03 2.0533e-03 -6.0000e+00 7.4697e-03 2.1396e-05 2.7527e-03 1.4092e-03 4.1945e-05 -6.0000e+00 1.4872e-03 2.7218e-02 -3.6407e-05 12 8 8 10 0 0 58.81 15.00 1.99 0.02722 0.04631 9 1 1 4 0 4000.000 21.88 15.00 18.88 -4015 -2414 -4792 3041 -3066 1746 66 669 2846 -2386 -1970 1538 -2404 3114 250 -181 -721 -2452 -760 1773 1604 -347 1888 2556 2744 -947 1641 39 451 -3745 -1014 -4182 -740 738 1250 -1162 352 -1526 -815 175 3650 1974 1284 2596 300 1978 -806 -202 79 774 -1019 1785 -2382 985 -1553 94 2061 2028 -942 960 -184 -342 233 192 1177 -835 -1991 3544 569 229 -2850 -2054 2263 -1227 -937 1105 1656 -2220 400 -1181 1343 -1006 -2752 845 -5 -969 799 3560 1547 1225 1790 3672 1975 -1451 409 1893 1424 544 -367 -2109 -2452 -3095 1764 -1144 687 -506 1851 -2046 -1639 -1795 -731 -1245 1395 665 1488 792 1138 -454 3904 -2638 1616 -977 -1435 -924 -3554 2345 1302 -179 -1335 848 1234 1780 266 -2283 291 -1644 -2549 303 941 1821 -1613 -1977 1991 3034 2973 -2165 -3041 748 -420 -4446 900000 -4001 -2406 -5068 3110 -3407 1885 74 754 3132 -2717 -2188 1631 -2604 3142 257 -187 -757 -2686 -846 1947 1757 -387 2058 2777 3001 -1075 1809 43 488 -4021 -1032 -4399 -767 787 1379 -1318 387 -1685 -881 185 3743 2074 1375 2782 333 2166 -901 -221 85 805 -1041 1723 -2353 947 -1579 98 2154 2135 -1016 1009 -196 -365 249 205 1231 -874 -2063 3427 560 222 -2804 -2010 2145 -1221 -942 1080 1566 -2129 370 -1104 1227 -949 -2648 787 -5 -936 758 3266 1440 1145 1671 3418 1912 -1462 399 1788 1324 496 -328 -1865 -2150 -2761 1551 -1083 654 -484 1695 -1903 -1498 -1661 -684 -1194 1326 644 1434 771 1112 -452 3681 -2598 1500 -914 -1341 -871 -3462 2154 1209 -168 -1262 790 1137 1594 237 -2054 253 -1484 -2390 281 878 1701 -1561 -1920 1871 2839 2789 -2119 -2929 671 -371 -4072 900000 SO 20180104T130010.0Z 6578.541782 3 1 36.01 2 89.57 122.78 72.25 273.87 0.00 1 0.00 1 0 15 1.806e-02 1.783e-02 1.656e-02 1.641e-02 1.548358e+03 8.975571e+02 1.064863e+02 -6.000000e+00 8.987964e+02 272.48 -2.00 20.00 -2.00 505.23 0.00e+00 2.915373e-03 4.278109e-04 1.498027e-04 -6.000000e+00 4.827163e-04 272.48 -2.00 20.00 -2.00 500.04 0.00e+00 2.505564e+00 3.215376e-01 2.802066e-02 -6.000000e+00 3.481511e-01 222.96 -2.00 3.57 -2.00 501.68 0.00e+00 20.090 0.158 489.00 513.00 1 8.2768e+00 2.4502e-02 3.5889e-02 -6.0000e+00 2.6495e-02 1.2124e-01 6.4870e-03 2.0044e-03 -6.0000e+00 7.0685e-03 2.4350e-05 3.0339e-03 1.2450e-03 3.9361e-05 -6.0000e+00 1.4085e-03 2.5993e-02 3.4995e-06 12 8 8 10 0 0 50.25 15.00 0.47 0.02599 0.04704 9 1 1 4 0 4000.000 21.88 15.00 18.90 -3204 -930 2134 -1147 2888 -521 -1831 1188 -348 3489 2258 -1008 -2983 1514 510 -2624 -1549 -1089 -14 -535 2176 -1192 370 2798 -876 135 2184 1827 979 -800 858 -1954 1596 -1673 3328 425 895 -1111 1080 -1729 356 -2342 -1670 -549 425 1428 1007 -397 1639 -933 -651 -1342 -2990 1332 -3372 -30 -1222 727 982 530 -964 2326 709 2379 1802 1218 -1446 -1640 -2812 1122 976 -2153 459 -199 406 184 149 -388 -1588 -1603 3674 -3111 1 -1065 1748 -1939 -691 -3433 2601 2463 -357 1616 504 1948 -180 -407 872 -939 -3542 837 -2233 929 -1492 1471 1289 3084 -4483 97 -3069 -677 -1045 1535 -50 -427 -602 -279 -718 3359 -48 3227 1584 -2603 2158 -64 2114 -2874 3178 -809 3638 -302 324 1661 1566 -2190 -1375 -1908 -770 2350 889 1318 865 103 1694 2032 15 -979 -2554 -2502 -2938 411 900000 -3128 -904 2090 -1209 2997 -569 -2068 1317 -391 3710 2382 -1085 -3216 1537 518 -2754 -1628 -1170 -15 -597 2354 -1333 407 3017 -987 150 2382 1986 1044 -829 853 -2006 1614 -1826 3591 473 976 -1218 1142 -1860 376 -2558 -1837 -606 469 1567 1102 -434 1726 -982 -660 -1329 -2961 1274 -3488 -31 -1316 774 1037 557 -1027 2420 752 2475 1867 1245 -1486 -1663 -2854 1076 924 -2106 443 -196 402 181 143 -365 -1498 -1504 3283 -2998 1 -1012 1636 -1893 -665 -3374 2401 2278 -341 1539 496 1901 -177 -393 815 -867 -3262 720 -1958 801 -1362 1366 1227 2858 -4382 88 -2861 -624 -987 1442 -48 -420 -595 -276 -719 3239 -47 3021 1480 -2489 1963 -61 1965 -2800 2923 -770 3308 -287 304 1502 1390 -1988 -1233 -1751 -720 2169 841 1255 829 99 1621 1950 15 -963 -2486 -2351 -2704 366 900000 SO 20180104T130204.0Z 6578.543102 5 1 36.00 2 89.28 123.11 72.59 274.18 0.00 1 0.00 1 0 15 1.359e-02 1.344e-02 1.370e-02 1.359e-02 1.089583e+03 7.312753e+02 8.745344e+01 -6.000000e+00 6.763383e+02 272.48 -2.00 20.00 -2.00 505.23 0.00e+00 3.008643e-03 3.547470e-04 1.507341e-04 -6.000000e+00 3.632241e-04 272.48 -2.00 20.00 -2.00 500.06 0.00e+00 2.415338e+00 2.662744e-01 2.416005e-02 -6.000000e+00 2.619526e-01 222.96 -2.00 3.57 -2.00 501.69 0.00e+00 19.520 0.145 489.00 513.00 1 8.1663e+00 2.0291e-02 3.4147e-02 -6.0000e+00 1.9936e-02 1.1808e-01 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