File name: Pandora103s1_Downsview_20180105_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T225455.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180105_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180105 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180105T125808.0Z 6579.540370 1 1 36.00 2 89.87 122.28 64.56 261.05 0.00 1 0.00 1 0 15 1.502e-02 1.510e-02 1.330e-02 1.319e-02 4.706622e+02 6.882157e+02 1.212283e+01 -6.000000e+00 7.471933e+02 272.42 -2.00 20.00 -2.00 505.25 0.00e+00 1.642470e-03 3.439331e-04 7.439710e-05 -6.000000e+00 4.013698e-04 272.42 -2.00 20.00 -2.00 500.06 0.00e+00 2.725967e+00 2.575088e-01 1.870347e-02 -6.000000e+00 2.895444e-01 223.00 -2.00 3.57 -2.00 501.71 0.00e+00 20.545 0.169 489.00 513.00 1 7.9908e+00 1.9621e-02 3.7172e-02 -6.0000e+00 2.2034e-02 1.1747e-01 5.2068e-03 2.0529e-03 -6.0000e+00 5.8787e-03 3.0562e-05 6.6154e-04 1.0018e-03 1.8911e-05 -6.0000e+00 1.1712e-03 7.7048e-03 1.1205e-04 12 8 8 10 0 0 83.18 15.00 1.34 0.00770 0.01229 9 1 1 4 0 4000.000 21.88 15.00 18.88 -4495 -1248 -2371 -638 -3270 2078 2144 -107 1384 -1541 -1139 -542 -1444 -2733 -1584 -818 1435 -2911 1460 -540 986 822 3791 2640 504 349 -165 606 -756 394 -742 -1709 -2049 105 1381 446 -932 1928 -2074 1298 1400 -664 738 1246 957 2003 1902 378 1458 1408 1227 -1736 966 -1758 -220 -1776 2579 -529 456 -1234 2355 540 -41 77 1248 -1142 -1584 -385 -248 856 -583 388 1926 -379 828 1017 729 927 -2067 -1674 -1473 29 -1021 2095 -1153 1330 -445 1478 -1694 -221 888 271 1865 2411 1119 1850 -1269 -343 1183 -3748 1034 -81 -168 895 713 -431 -2780 -1020 -856 541 2124 -173 -1738 1184 1662 2392 -897 3256 834 812 -1264 1115 -1204 398 -1699 835 -584 -34 -2036 -322 372 -307 -40 64 62 -1925 -2142 -530 948 -1397 1393 -1540 1421 -2455 86 -477 1507 -2470 -879 -24 900000 -4417 -1205 -2395 -661 -3566 2192 2311 -119 1523 -1720 -1241 -580 -1536 -2894 -1643 -843 1462 -3172 1577 -604 1083 905 4049 2857 561 390 -184 669 -827 407 -753 -1752 -2144 112 1517 498 -1040 2061 -2272 1360 1464 -713 790 1344 1047 2178 2059 410 1536 1449 1222 -1724 917 -1717 -218 -1857 2651 -565 481 -1311 2409 566 -43 81 1291 -1187 -1620 -383 -244 819 -556 368 1813 -371 812 989 693 858 -1949 -1564 -1375 27 -963 1923 -1106 1256 -427 1389 -1635 -211 840 261 1811 2349 1091 1761 -1222 -319 1053 -3406 887 -71 -152 839 688 -417 -2701 -953 -787 494 1949 -165 -1715 1149 1613 2313 -900 3151 817 781 -1219 1034 -1134 374 -1643 786 -558 -32 -1958 -306 351 -285 -36 57 55 -1764 -2027 -504 899 -1370 1335 -1518 1370 -2474 85 -471 1429 -2350 -802 -22 900000 SO 20180105T130006.0Z 6579.541736 3 1 36.01 2 89.57 122.62 64.91 261.39 0.00 1 0.00 1 0 22 1.265e-02 1.260e-02 1.094e-02 1.085e-02 -4.417652e+02 5.687127e+02 3.620073e+01 -6.000000e+00 6.294835e+02 272.42 -2.00 20.00 -2.00 505.24 0.00e+00 1.803742e-03 2.832143e-04 8.521188e-05 -6.000000e+00 3.381713e-04 272.42 -2.00 20.00 -2.00 500.05 0.00e+00 3.226517e+00 2.123064e-01 1.825371e-02 -6.000000e+00 2.439810e-01 223.00 -2.00 3.57 -2.00 501.70 0.00e+00 20.081 0.158 489.00 513.00 1 7.8136e+00 1.6189e-02 3.5703e-02 -6.0000e+00 1.8566e-02 1.0590e-01 4.2877e-03 1.9789e-03 -6.0000e+00 4.9549e-03 3.7483e-05 2.3408e-03 8.2678e-04 2.1956e-05 -6.0000e+00 9.8676e-04 1.7539e-02 3.5289e-05 12 8 8 10 0 0 83.67 15.00 1.12 0.01754 0.03378 9 1 1 4 0 4000.000 21.88 15.00 18.90 -3092 -3006 -873 1759 -485 -6 2166 -1255 1351 -582 1766 -1444 1016 -965 25 -1535 -1234 -877 -316 828 511 -1050 -610 1235 697 1646 2013 2532 392 -865 -1318 -685 -2207 1089 473 1476 -1206 1185 -1417 -647 -663 -76 840 1277 1274 1854 652 9 890 -1426 345 -2071 -2189 -698 668 -1251 -425 597 -1227 -1082 2322 750 2014 1664 518 -172 929 941 -183 -219 826 -562 -1147 -536 33 -676 -1689 -134 -2530 -689 -2286 97 -327 1634 2354 627 -65 680 -328 686 -759 472 -900 747 502 153 2919 -1196 -1771 170 961 -2182 -1417 -1004 1622 735 559 -501 -2130 -1686 651 1227 1660 728 1623 884 205 1221 -1253 1163 -224 1518 -1673 1321 -564 630 -922 -236 75 365 -687 210 -2222 -453 -1112 1206 -657 -1421 937 -763 1762 318 74 -803 2302 -216 238 -942 -993 -1971 900000 -3000 -2959 -873 1787 -516 -6 2338 -1416 1487 -642 1870 -1558 1055 -1004 26 -1594 -1293 -940 -348 915 564 -1177 -680 1356 775 1818 2205 2744 423 -903 -1346 -697 -2322 1158 525 1634 -1349 1276 -1543 -691 -708 -82 901 1381 1393 2022 714 10 943 -1506 346 -2062 -2144 -677 659 -1306 -450 631 -1314 -1148 2377 785 2091 1729 539 -177 925 924 -180 -212 777 -537 -1112 -525 32 -666 -1636 -125 -2390 -636 -2150 90 -306 1504 2178 594 -62 641 -311 646 -727 453 -896 737 492 148 2705 -1122 -1624 149 826 -1957 -1302 -960 1546 699 522 -463 -1970 -1566 604 1155 1582 709 1574 867 204 1200 -1246 1109 -213 1398 -1583 1231 -539 594 -884 -223 71 346 -653 194 -2056 -406 -997 1075 -615 -1366 891 -745 1684 308 73 -798 2229 -213 229 -883 -907 -1812 900000 SO 20180105T130200.0Z 6579.543056 5 1 36.00 2 89.28 122.95 65.24 261.73 0.00 1 0.00 1 0 22 1.108e-02 1.097e-02 9.528e-03 9.455e-03 -1.200682e+02 4.940475e+02 5.450413e+01 -6.000000e+00 5.512748e+02 272.42 -2.00 20.00 -2.00 505.24 0.00e+00 2.428812e-03 2.469341e-04 1.205629e-04 -6.000000e+00 2.961350e-04 272.42 -2.00 20.00 -2.00 500.09 0.00e+00 2.959126e+00 1.845306e-01 2.189037e-02 -6.000000e+00 2.136409e-01 223.00 -2.00 3.57 -2.00 501.74 0.00e+00 19.508 0.145 489.00 513.00 1 7.7587e+00 1.4071e-02 3.4030e-02 -6.0000e+00 1.6258e-02 1.0280e-01 3.7234e-03 1.8804e-03 -6.0000e+00 4.3380e-03 4.3321e-05 3.0032e-03 7.1999e-04 3.0501e-05 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