File name: Pandora103s1_Downsview_20180107_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T225336.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180107_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180107 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180107T125747.0Z 6581.540127 1 1 36.00 2 89.87 121.91 54.62 232.88 0.00 1 0.00 1 0 22 2.054e-02 2.024e-02 1.834e-02 1.826e-02 3.248371e+03 1.020274e+03 2.260270e+02 -6.000000e+00 1.021799e+03 272.29 -2.00 20.00 -2.00 505.38 0.00e+00 3.798663e-03 4.787247e-04 2.023942e-04 -6.000000e+00 5.486091e-04 272.29 -2.00 20.00 -2.00 500.72 0.00e+00 2.465549e+00 3.466851e-01 4.440880e-02 -6.000000e+00 3.956811e-01 223.08 -2.00 3.57 -2.00 502.27 0.00e+00 20.552 0.169 489.00 513.00 1 8.3081e+00 2.6374e-02 3.7629e-02 -6.0000e+00 3.0117e-02 4.0082e-02 6.8702e-03 2.1739e-03 -6.0000e+00 8.0242e-03 2.1876e-05 3.2417e-03 1.3990e-03 5.9196e-05 -6.0000e+00 1.6017e-03 1.3905e-02 1.5473e-04 12 8 8 10 0 0 44.55 15.00 2.04 0.01390 0.03639 9 1 1 4 0 4000.000 21.88 15.00 18.90 -5207 -349 212 1221 -1696 1338 -599 509 -2683 1073 93 -1296 3283 -755 762 -2930 1599 -702 3184 949 4487 -1665 2357 439 2001 -2909 -689 -517 -1712 -670 -1465 -422 -4151 122 2404 2286 -1279 4572 -994 642 -1270 1010 -2096 2388 -1854 1830 1835 825 1321 1253 -2683 45 -1162 -1398 -486 316 1100 1738 -2253 1669 1727 -1296 -265 -2251 4992 154 2473 -1769 43 -3416 -4938 -394 494 1585 -1148 961 2683 2205 -189 -866 -1330 2518 -943 -787 -4941 3966 -1651 1717 -1394 1414 609 2242 -1234 315 608 -889 -104 176 399 -2832 -1319 -4247 6487 -1550 1245 -1801 1084 -3201 413 -1021 0 507 1218 326 -1142 271 2932 239 -782 1643 1762 -4242 -157 3388 -490 4379 -1716 -342 647 1152 -55 3778 582 812 -2014 1269 -511 -2454 -847 593 1486 -1283 1914 -311 -262 -1260 1145 -1698 158 -3165 900000 -4683 -306 192 1145 -1675 1309 -610 519 -2812 1066 91 -1279 3050 -719 710 -2841 1505 -696 3137 965 4393 -1734 2361 451 2046 -3125 -723 -538 -1752 -649 -1401 -402 -4199 125 2480 2364 -1349 4498 -1020 643 -1303 1025 -2224 2465 -2020 1930 1925 862 1352 1251 -2689 42 -1104 -1347 -481 323 1141 1802 -2419 1714 1776 -1385 -281 -2434 4985 158 2437 -1794 42 -3424 -4963 -381 479 1549 -1165 944 2524 2043 -178 -817 -1266 2333 -905 -759 -5029 3726 -1635 1636 -1364 1347 589 2178 -1268 320 605 -880 -100 164 362 -2583 -1177 -3966 5673 -1538 1229 -1818 1045 -3155 390 -993 0 508 1230 336 -1198 282 3006 252 -826 1665 1752 -4398 -157 3312 -501 4277 -1783 -350 655 1169 -56 3619 566 780 -1983 1239 -522 -2601 -895 625 1557 -1385 2018 -337 -285 -1370 1187 -1751 157 -3254 900000 SO 20180107T125945.0Z 6581.541493 3 1 36.01 2 89.57 122.25 54.90 233.35 0.00 1 0.00 1 0 8 2.117e-02 2.094e-02 1.959e-02 1.951e-02 1.431226e+03 1.038276e+03 4.424449e+01 -6.000000e+00 1.052683e+03 272.29 -2.00 20.00 -2.00 505.29 0.00e+00 3.325493e-03 5.101237e-04 1.823609e-04 -6.000000e+00 5.656257e-04 272.29 -2.00 20.00 -2.00 500.40 0.00e+00 1.645494e+00 3.755032e-01 3.835124e-02 -6.000000e+00 4.082906e-01 223.08 -2.00 3.57 -2.00 502.00 0.00e+00 20.088 0.158 489.00 513.00 1 8.5123e+00 2.8576e-02 3.6033e-02 -6.0000e+00 3.1068e-02 9.5611e-02 7.5582e-03 2.0189e-03 -6.0000e+00 8.2922e-03 2.0409e-05 6.6561e-04 1.4872e-03 4.4466e-05 -6.0000e+00 1.6511e-03 2.7060e-02 -2.4155e-05 12 8 8 10 0 0 91.80 15.00 1.44 0.02706 0.03168 9 1 1 4 0 4000.000 21.98 15.00 18.92 -4623 -2302 -2665 102 -628 168 1197 685 1860 273 -2811 -1198 1816 -2843 857 -1974 -1927 1219 -202 3004 -609 -1954 -1465 1410 4006 2392 -1012 232 291 1719 -357 -316 955 -2091 568 -71 1991 1077 -981 3783 -2427 1143 -276 -29 2385 -626 -33 -577 1087 2195 -197 -797 279 1559 -3546 -1203 660 734 1860 -1924 2108 2432 5355 384 1289 -2418 -3196 -1888 426 1989 -2063 324 1681 538 383 -2535 -2335 -2759 104 1990 1398 6699 -562 369 386 774 -4550 -3725 -4143 -505 1075 1491 -1428 -141 293 -1260 2503 1094 -4102 -238 311 541 -1545 -975 -1107 3337 1655 901 -1288 -3135 825 -554 3413 3335 3052 2482 2085 295 3004 574 2260 4221 -4053 214 -888 114 -3328 909 -3173 880 -1129 -37 -1245 -2442 -859 -2605 -691 2514 4123 2829 718 -677 980 -1701 1683 -1915 -2837 -2931 1922 -2603 900000 -4348 -2148 -2584 101 -641 173 1249 728 1954 286 -2982 -1236 1792 -2884 831 -1967 -1939 1220 -211 3103 -649 -2111 -1573 1477 4132 2516 -1096 247 303 1687 -347 -307 934 -2196 606 -77 2086 1121 -1029 3747 -2556 1173 -291 -31 2519 -685 -36 -620 1131 2210 -196 -774 264 1460 -3598 -1242 687 772 1929 -2056 2162 2506 5396 405 1339 -2562 -3342 -1920 420 1900 -2017 310 1603 527 382 -2585 -2317 -2685 97 1823 1290 5934 -536 350 371 747 -4621 -3737 -4156 -490 1031 1446 -1460 -144 295 -1263 2374 1024 -3927 -214 275 481 -1444 -949 -1110 3189 1579 848 -1220 -3049 790 -549 3311 3278 3025 2483 2110 305 2997 575 2190 3946 -4077 209 -886 112 -3403 890 -3218 863 -1126 -36 -1190 -2330 -800 -2504 -671 2417 3947 2772 720 -689 987 -1770 1701 -1993 -2915 -2912 1772 -2496 900000 SO 20180107T130139.0Z 6581.542813 5 1 36.01 2 89.28 122.58 55.18 233.81 0.00 1 0.00 1 0 22 1.777e-02 1.767e-02 1.710e-02 1.701e-02 2.460993e+03 9.465900e+02 1.607633e+02 -6.000000e+00 8.838572e+02 272.29 -2.00 20.00 -2.00 505.30 0.00e+00 3.222973e-03 4.443709e-04 1.706836e-04 -6.000000e+00 4.747300e-04 272.29 -2.00 20.00 -2.00 500.34 0.00e+00 2.061016e+00 3.293428e-01 3.506499e-02 -6.000000e+00 3.426215e-01 223.08 -2.00 3.57 -2.00 501.95 0.00e+00 19.513 0.145 489.00 513.00 1 8.4190e+00 2.5047e-02 3.4248e-02 -6.0000e+00 2.6073e-02 8.6506e-02 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