File name: Pandora103s1_Downsview_20180113_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T225037.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180113_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180113 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180113T125550.0Z 6587.538773 1 1 36.01 2 89.87 120.55 67.31 152.30 0.00 1 0.00 1 0 22 9.298e-02 8.939e-02 9.443e-02 9.197e-02 -7.427527e+03 4.742008e+03 1.193084e+03 -6.000000e+00 4.618865e+03 271.92 -2.00 20.00 -2.00 505.15 0.00e+00 3.396497e-03 2.392380e-03 1.892672e-04 -6.000000e+00 2.481160e-03 271.92 -2.00 20.00 -2.00 499.90 0.00e+00 3.740924e+00 1.824913e+00 7.283589e-02 -6.000000e+00 1.792290e+00 223.32 -2.00 3.57 -2.00 501.56 0.00e+00 20.552 0.169 489.00 513.00 1 9.9037e+00 1.3893e-01 3.7599e-02 -6.0000e+00 1.3639e-01 1.3911e-01 3.7019e-02 2.0723e-03 -6.0000e+00 3.6351e-02 4.1141e-06 -9.9528e-03 6.8803e-03 1.6561e-04 -6.0000e+00 7.2509e-03 1.4741e-02 1.4072e-04 12 8 8 10 0 0 79.01 15.00 6.50 0.01474 -0.05430 9 1 1 4 0 4000.000 21.98 15.00 19.03 -15250 7531 -11791 2801 -1936 13842 -1695 -6585 -8524 10825 5347 2441 6053 -2945 106 11373 -2521 -1023 -6507 -7259 14106 7015 -2991 -2617 -9119 -2097 20156 -9098 -3979 -7849 -10497 -753 3510 2056 16295 -10610 15547 8218 26809 9036 12685 -12344 9260 -3273 7170 -4074 5294 3904 -3307 8536 2667 12914 -8388 -3123 -8395 11509 6687 -5411 -2120 13299 -243 2496 -3756 5403 -1672 3585 -12690 -5214 -3018 -7798 3566 6377 8719 4395 24038 564 17771 3746 -4164 -8669 5971 -21620 256 948 438 3799 1546 3615 3926 10578 9661 -6440 201 -1030 -17529 30410 -18309 5059 -477 3966 -10153 13856 1499 7482 -4725 6281 -6032 -6889 -3272 4222 10427 -7418 8455 -4609 -5582 11359 23896 -3671 -5774 -5023 7092 8466 7916 2322 18590 4872 11652 7093 -128 -5698 2555 -2192 8466 7309 7124 -6528 -7803 -1851 1638 -6389 -10782 4011 -3661 1801 -15683 17147 -3560 -10645 -1517 4676 900000 -17364 6873 -13301 2859 -2145 13419 -1949 -8085 -10722 11197 5712 2636 6231 -3246 112 10693 -2722 -1106 -7652 -8836 13991 7428 -3485 -3035 -11330 -2453 18968 -11316 -4658 -9191 -12057 -777 3500 2137 15455 -13414 15155 8446 22702 8954 12053 -14998 9225 -3726 7479 -4779 5668 4189 -3743 8452 2711 11471 -8921 -3123 -8960 10529 6621 -6128 -2329 12481 -258 2585 -4159 5474 -1806 3628 -14716 -5508 -3084 -8232 3302 5692 7646 4061 18675 553 14483 3397 -4008 -8658 5165 -24634 238 873 407 3449 1437 3285 3548 8987 8313 -6520 195 -1034 -20851 22738 -21941 4784 -462 3553 -10156 10928 1349 6537 -4767 5652 -5945 -6667 -2994 3580 8474 -7336 7363 -4673 -5803 10096 18852 -3760 -5944 -5022 6205 7244 6764 2113 14651 4381 9797 6227 -119 -5653 2352 -2086 7100 6060 5803 -6042 -7478 -1724 1501 -6382 -11270 3617 -3554 1674 -17418 13894 -3473 -10748 -1349 3838 900000 SO 20180113T125748.0Z 6587.540139 3 1 36.02 2 89.56 120.89 67.15 152.76 0.00 1 0.00 1 0 22 9.379e-02 9.071e-02 7.898e-02 7.679e-02 3.243624e+03 4.397344e+03 2.053358e+02 -6.000000e+00 4.658086e+03 271.92 -2.00 20.00 -2.00 505.19 0.00e+00 6.461447e-04 1.984699e-03 7.860836e-05 -6.000000e+00 2.503263e-03 271.92 -2.00 20.00 -2.00 499.85 0.00e+00 1.958159e+00 1.516933e+00 2.851553e-02 -6.000000e+00 1.808791e+00 223.32 -2.00 3.57 -2.00 501.51 0.00e+00 20.079 0.158 489.00 513.00 1 9.9319e+00 1.1540e-01 3.5696e-02 -6.0000e+00 1.3764e-01 1.5058e-01 3.0745e-02 2.0465e-03 -6.0000e+00 3.6701e-02 4.9545e-06 -5.5960e-03 5.7154e-03 3.3802e-05 -6.0000e+00 7.3127e-03 -4.6572e-02 4.7717e-04 12 8 8 10 0 0 0.16 15.00 6.72 -0.04657 -0.08539 9 1 1 4 0 4000.000 21.98 15.00 19.05 -5941 623 -8936 14778 -1553 18654 -10012 1596 -7497 9419 7342 13175 -12064 2684 -4488 -1931 -4008 6918 3107 1114 21257 -14309 -6310 2127 5335 -1266 4448 -6998 923 5403 3275 5374 384 -6149 998 -4379 657 10271 -5438 5175 2098 -4187 -5457 -858 9830 16258 1142 19108 1936 16629 -9898 -6646 -6104 2059 -13073 8402 -8635 6662 6367 8840 -5299 -4191 30919 -11296 734 948 -1348 -21533 11742 -12921 5037 -4838 19986 -8696 2492 -1647 13414 -10263 3210 4006 6737 11668 11161 -7066 13313 8127 -15260 773 2292 6363 7224 26460 -11255 11088 1549 -4806 -516 3906 -12171 -992 800 14816 -17127 5035 -4926 15658 4633 -17615 -1302 -9551 6755 1300 7987 -12627 11661 3084 8682 3649 -7107 -1334 11288 -7356 13463 8430 16543 -890 5097 10790 -3902 -4025 -6291 1099 7939 1829 1756 2581 1739 -1521 -15273 7843 2418 -1965 8609 -3956 -14328 1523 10242 -3640 9741 -4120 900000 -6165 608 -9838 13478 -1715 17242 -12487 1809 -9329 9862 7687 12847 -14836 2807 -4966 -2076 -4424 7005 3375 1265 19873 -18862 -7683 2383 5826 -1482 4900 -8574 1033 5562 3302 5268 399 -7026 1114 -5266 744 10425 -6337 5358 2223 -4728 -6297 -956 10005 15639 1269 17607 2072 15120 -11268 -7074 -6306 1950 -14620 7936 -9927 6697 6414 8620 -5884 -4622 24407 -13425 772 980 -1395 -26606 10388 -14321 4599 -4837 15832 -9216 2413 -1663 11459 -10721 2896 3561 5819 9689 9384 -7105 11100 7219 -17048 737 2140 5702 6430 19723 -12336 9906 1502 -4844 -488 3439 -12170 -867 675 10956 -17733 4412 -4964 13035 4232 -19550 -1208 -9569 5876 1214 7085 -13811 10109 2908 7803 3473 -7489 -1307 9584 -7334 10801 7137 13107 -835 4507 9014 -3732 -3861 -6182 986 6508 1568 1492 2190 1531 -1415 -16447 6829 2236 -1898 7533 -3937 -15821 1438 8748 -3449 7853 -3750 900000 SO 20180113T125942.0Z 6587.541458 5 1 36.00 2 89.27 121.22 67.00 153.21 0.00 1 0.00 1 0 15 7.446e-02 7.123e-02 6.610e-02 6.457e-02 3.147582e+02 3.420194e+03 2.129034e+02 -6.000000e+00 3.698028e+03 271.92 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