File name: Pandora103s1_Downsview_20180130_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T230018.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180130_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180130 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180130T124246.0Z 6604.529699 1 1 36.00 2 89.86 114.89 99.30 306.95 0.00 1 0.00 1 0 29 4.008e-02 3.928e-02 3.794e-02 3.717e-02 2.953954e+03 2.178172e+03 2.862669e+02 -6.000000e+00 1.989708e+03 271.77 -2.00 20.00 -2.00 505.16 0.00e+00 2.521519e-03 9.710362e-04 8.508249e-05 -6.000000e+00 1.069585e-03 271.77 -2.00 20.00 -2.00 499.65 0.00e+00 2.068905e+00 7.493823e-01 1.832275e-02 -6.000000e+00 7.745319e-01 224.00 -2.00 3.57 -2.00 501.33 0.00e+00 20.546 0.169 489.00 513.00 1 9.0922e+00 5.7156e-02 3.7160e-02 -6.0000e+00 5.8913e-02 1.7709e-01 1.5104e-02 2.0964e-03 -6.0000e+00 1.5739e-02 1.0484e-05 6.3814e-03 2.8284e-03 3.8150e-05 -6.0000e+00 3.1253e-03 3.4880e-03 7.4748e-05 12 8 8 10 0 0 -0.22 15.00 1.29 0.00349 0.04775 9 1 1 4 0 4000.000 21.98 15.00 19.02 -465 -1285 5254 -3661 -2198 -2099 5135 -2981 -473 1425 -3905 -4850 4165 -3126 -1696 -1711 1528 -2728 -2061 2543 -2479 328 -3513 -3251 2340 2062 2216 9491 -5428 7815 1013 8368 -1451 5593 -3196 2626 346 2077 -4003 1341 -3790 3081 2865 -129 1983 -2355 -3030 318 3774 -4823 7474 -3338 -3240 -7304 4350 4735 1901 3121 -2088 -3683 5541 7474 -6060 4067 1744 4367 -505 2614 -5532 6345 -4010 3416 353 514 -3303 2421 3624 -4023 -5606 3806 -2396 -2653 -4400 5140 1580 4253 -667 -1430 4219 -8934 1521 -3700 8863 4730 5273 871 4982 416 -3363 -3972 -6793 -4945 12027 4346 5903 1879 2201 3373 -5722 -578 -1019 -5112 -6669 2157 2195 2282 -521 387 6225 2927 -4924 1636 -6511 4237 -1968 -1570 2742 -3351 -873 -1315 4948 -2745 1477 560 -532 -6235 1365 -4050 1790 2607 1023 1188 926 -2344 3555 1595 -934 -1726 -5699 -1403 900000 -467 -1325 5281 -4177 -2526 -2454 5709 -3616 -558 1618 -4580 -5669 4378 -3468 -1840 -1860 1629 -3118 -2412 2869 -2922 376 -4171 -3864 2653 2343 2500 9896 -6348 7659 1038 8015 -1562 5884 -3787 2938 389 2262 -4557 1434 -4267 3269 3083 -144 2202 -2731 -3507 351 3949 -5337 7070 -3407 -3254 -7701 4237 4766 2008 3272 -2288 -4066 5584 7443 -6905 4181 1812 4335 -515 2545 -5766 5777 -3982 3168 340 503 -3392 2319 3332 -3897 -5465 3364 -2257 -2528 -4269 4565 1471 3878 -636 -1364 3791 -9120 1408 -3668 7930 4409 4797 808 4335 367 -2993 -3467 -6046 -4390 9400 3839 5244 1720 1969 2915 -5345 -519 -940 -4987 -6692 2001 2039 2125 -503 371 5564 2646 -4712 1441 -6184 3673 -1822 -1445 2420 -3119 -791 -1202 4214 -2454 1244 470 -449 -5683 1188 -3772 1592 2321 927 1075 845 -2217 3175 1438 -841 -1510 -5064 -1196 900000 SO 20180130T124444.0Z 6604.531065 3 1 36.01 2 89.54 115.23 99.57 307.30 0.00 1 0.00 1 0 29 3.227e-02 3.140e-02 2.859e-02 2.811e-02 2.435872e+03 1.613820e+03 1.941457e+01 -6.000000e+00 1.602011e+03 271.77 -2.00 20.00 -2.00 505.17 0.00e+00 1.449654e-03 7.342566e-04 7.306387e-05 -6.000000e+00 8.606081e-04 271.77 -2.00 20.00 -2.00 499.78 0.00e+00 2.137578e+00 5.628250e-01 5.748746e-02 -6.000000e+00 6.225755e-01 224.00 -2.00 3.57 -2.00 501.44 0.00e+00 20.038 0.157 489.00 513.00 1 8.8858e+00 4.2957e-02 3.5758e-02 -6.0000e+00 4.7370e-02 1.5860e-01 1.1351e-02 2.1443e-03 -6.0000e+00 1.2629e-02 1.3995e-05 -2.2239e-03 2.1123e-03 1.7802e-05 -6.0000e+00 2.5162e-03 2.4599e-02 7.4187e-05 12 8 8 10 0 0 -6.42 15.00 2.30 0.02460 0.00917 9 1 1 4 0 4000.000 21.98 15.00 19.03 -5616 -927 -3998 -1360 -3548 -1258 1478 5030 780 3315 -2542 1393 -2459 886 167 -2545 -1031 638 -1400 -234 1745 2425 -1749 -1263 790 568 121 1847 6791 -1482 -3274 -3630 -2299 -2026 4267 202 3408 1925 2499 2960 -4522 172 1502 3800 -1128 2841 -3913 2353 -785 3278 -6658 -612 -732 5274 -496 2711 -1424 -2572 1644 3672 -2255 4977 179 3957 3086 1151 1173 -3389 1027 -1437 3877 2260 1350 -3699 1618 -4462 -4154 -2827 -829 -3533 1739 -2985 560 -295 -3493 2222 3094 6153 -1677 -1438 -1534 2080 1685 898 -305 -784 -9158 2490 -521 4710 3737 7516 -2265 -1245 -270 1523 156 -759 4564 1442 -1750 -1433 -2932 743 -3383 -1697 6825 3250 -1028 -2099 5428 1300 836 -6691 9509 -3513 4074 -4780 1418 521 -129 877 -2249 -497 2176 63 1347 1960 -1617 1703 1914 346 -2255 7246 4185 945 -2195 -4769 -4691 -9856 900000 -5830 -929 -4269 -1476 -4042 -1426 1668 5556 898 3674 -2922 1521 -2744 940 177 -2756 -1111 693 -1603 -269 1965 2711 -2032 -1460 902 652 138 2069 7102 -1605 -3489 -3879 -2461 -2250 4651 231 3729 2102 2674 3110 -5096 186 1622 4059 -1279 3110 -4551 2536 -858 3362 -7257 -609 -714 4848 -496 2731 -1534 -2826 1729 3750 -2427 5024 191 4046 3156 1177 1174 -3487 1002 -1412 3553 2102 1279 -3734 1575 -4585 -4146 -2712 -771 -3350 1566 -2844 517 -275 -3408 2070 2857 5488 -1606 -1373 -1470 1948 1618 876 -297 -750 -9292 2192 -459 3837 3031 5934 -2029 -1160 -257 1425 146 -697 3910 1279 -1632 -1357 -2856 705 -3349 -1656 6174 3061 -1001 -2026 4775 1167 746 -6492 7956 -3331 3587 -4570 1269 472 -118 772 -1997 -428 1809 54 1179 1740 -1503 1549 1746 321 -2153 6345 3785 877 -2058 -4431 -4229 -9282 900000 SO 20180130T124638.0Z 6604.532384 5 1 36.00 2 89.23 115.56 99.83 307.65 0.00 1 0.00 1 0 15 2.499e-02 2.465e-02 2.149e-02 2.117e-02 1.377534e+03 1.175498e+03 1.224760e+02 -6.000000e+00 1.240448e+03 271.77 -2.00 20.00 -2.00 505.19 0.00e+00 2.159223e-03 5.529891e-04 1.092171e-04 -6.000000e+00 6.665676e-04 271.77 -2.00 20.00 -2.00 499.82 0.00e+00 2.840317e+00 4.229928e-01 2.305561e-02 -6.000000e+00 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