File name: Pandora103s1_Downsview_20180131_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T230010.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180131_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180131 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180131T124141.0Z 6605.528947 1 1 36.00 2 89.86 114.48 91.67 294.68 0.00 1 0.00 1 0 15 1.166e-01 1.069e-01 1.006e-01 9.665e-02 3.101397e+03 5.631175e+03 1.163383e+02 -6.000000e+00 5.785374e+03 271.77 -2.00 20.00 -2.00 505.20 0.00e+00 1.097997e-03 2.519743e-03 1.178427e-04 -6.000000e+00 3.104341e-03 271.77 -2.00 20.00 -2.00 499.91 0.00e+00 -4.909086e-02 1.921170e+00 4.871626e-02 -6.000000e+00 2.231656e+00 224.04 -2.00 3.57 -2.00 501.57 0.00e+00 20.547 0.169 489.00 513.00 1 1.0239e+01 1.4644e-01 3.7376e-02 -6.0000e+00 1.7000e-01 2.0018e-01 3.8876e-02 2.1934e-03 -6.0000e+00 4.4953e-02 3.9121e-06 1.0901e-03 7.3418e-03 3.2638e-05 -6.0000e+00 9.0406e-03 -1.5163e-02 9.4268e-05 12 8 8 10 0 0 5.17 15.00 7.51 -0.01516 -0.00760 9 1 1 4 0 4000.000 21.98 15.00 19.04 900000 4083 36263 -4470 351 -1989 5671 -9615 4057 6855 -9218 -10539 11692 2325 13 4172 -8390 20704 -3299 11591 -2089 -10161 -4066 21074 -5161 6868 -12817 5696 -1202 12119 -1780 4335 7969 -18445 -11471 10085 -136 978 15825 -3390 -3344 -8557 10849 -528 11494 -10145 12833 2563 9280 -6387 -4467 -98 6686 -1442 10042 9767 -1478 21263 -5177 -15572 -16122 -5845 12921 9604 -2181 6851 3937 5501 -4089 19858 -5332 5180 -8814 12905 -6797 559 2876 489 -7943 13687 9478 2027 -2175 11725 -5383 -16949 31103 -15663 22043 -4772 13809 -9741 -333 14748 14595 -24530 13662 2300 -1898 19774 2712 14081 -1728 22499 -6609 14333 -2270 9231 -9734 22443 699 -4793 -4629 8822 -16098 9916 -12046 -403 3579 14934 -10252 -6090 -1230 765 -10195 5848 15222 -2206 -609 -13890 12098 -20559 41154 -10870 8626 1424 18906 2248 17038 -4703 10467 2056 -6521 326 2265 8863 -10363 12831 -9321 23609 -5332 900000 3922 26312 -5011 387 -2277 6156 -12282 4546 7384 -11357 -12972 11429 2441 14 4237 -9695 18452 -3833 11895 -2441 -12819 -4823 19581 -6221 7392 -16597 6130 -1357 11515 -1865 4266 7667 -23771 -14441 10452 -154 1074 14845 -3776 -3708 -10024 10640 -585 11468 -12542 12649 2752 9184 -7199 -4774 -97 6072 -1412 9023 9159 -1590 18573 -5830 -19229 -19916 -6574 12192 9350 -2365 6698 3878 5247 -4238 16089 -5413 4744 -9326 11236 -7287 557 2738 465 -8074 11221 8091 1878 -2112 9987 -5478 -19519 22544 -17771 17287 -4845 11747 -10523 -336 12972 12692 -30458 11462 2094 -1750 14405 2293 10755 -1583 17140 -6925 12299 -2251 8009 -9948 16830 658 -4844 -4730 7980 -18577 8902 -13462 -406 3441 12617 -10821 -6047 -1149 706 -10564 5177 12291 -2099 -567 -14723 9959 -22684 24447 -10503 6835 1220 14082 2007 13323 -4583 8852 1885 -6517 307 2093 7647 -10558 10106 -8812 16077 -4851 SO 20180131T124339.0Z 6605.530313 3 1 36.00 2 89.54 114.82 91.98 295.01 0.00 1 0.00 1 0 40 7.148e-02 6.879e-02 7.037e-02 6.921e-02 3.604502e+03 4.048299e+03 2.426405e+02 -6.000000e+00 3.548946e+03 271.77 -2.00 20.00 -2.00 505.24 0.00e+00 1.536604e-03 1.809802e-03 1.740899e-04 -6.000000e+00 1.906266e-03 271.77 -2.00 20.00 -2.00 500.16 0.00e+00 1.942720e+00 1.356490e+00 6.650103e-02 -6.000000e+00 1.377614e+00 224.04 -2.00 3.57 -2.00 501.79 0.00e+00 20.038 0.157 489.00 513.00 1 9.8145e+00 1.0345e-01 3.6064e-02 -6.0000e+00 1.0484e-01 1.0901e-01 2.7091e-02 2.2882e-03 -6.0000e+00 2.7909e-02 5.5519e-06 7.9698e-03 5.2108e-03 5.1943e-05 -6.0000e+00 5.5736e-03 -1.4792e-02 4.0501e-04 12 8 8 10 0 0 6.78 14.99 3.63 -0.01479 0.04049 9 1 1 4 0 4000.000 21.98 14.99 19.06 7282 3138 2755 -1282 10762 4401 8912 -2466 6448 7351 256 -3112 -2862 -789 7395 -4290 -1350 3943 631 -9043 -5576 2382 198 -3353 -2863 17891 3332 5428 -10994 -2094 7469 884 -10704 -11708 4466 3771 -1175 3766 2737 2224 -3652 -1579 -5729 4940 3420 -5033 -2333 -2030 1527 912 11749 -6891 976 1678 -127 14 -4124 -4557 5402 1375 2515 9441 7519 -6644 -4217 -1591 -4018 12707 -5131 -953 -8579 10918 -3146 9950 -4960 10542 4902 2162 -12801 1152 -8387 -927 -2413 1612 6306 -11084 -7134 4239 -7948 -3027 -1080 -3332 3218 -10214 -5999 -1667 5133 9518 -2179 -2935 3217 -822 14637 343 -876 2177 8699 5419 10460 524 1856 3206 -7768 -1752 -9353 40 511 9815 2463 -36 -4855 5234 751 16366 2692 8556 -13534 1885 -3873 -2723 -2740 -3249 6602 -4712 19474 -18675 4196 8956 19399 2754 2316 11203 4790 7879 -3002 3884 22418 -14823 6103 -11721 900000 6336 2918 2681 -1345 10231 4545 8977 -2791 6641 7357 270 -3355 -3023 -806 6947 -4546 -1416 4063 690 -10877 -6467 2560 217 -3831 -3275 16686 3563 5619 -12847 -2153 6933 884 -12361 -14325 4776 4027 -1296 3903 2826 2292 -4007 -1712 -6554 5163 3658 -5831 -2604 -2224 1585 923 10332 -7090 923 1609 -129 15 -4566 -5067 5418 1425 2587 9151 7435 -7499 -4583 -1652 -4192 11148 -5282 -925 -8910 9466 -3169 8991 -5198 9311 4450 1983 -13493 1058 -8516 -883 -2337 1517 5744 -11990 -7401 3917 -8250 -3002 -1060 -3415 3140 -11263 -6208 -1617 4535 7839 -1958 -2606 2701 -737 11841 334 -870 2074 7622 4804 8809 495 1764 3052 -8317 -1777 -10231 41 517 9054 2402 -35 -4888 4704 708 13450 2530 7596 -14879 1773 -3861 -2693 -2663 -3098 5642 -4452 14650 -20928 3861 7968 15796 2657 2247 10016 4589 7354 -3109 3707 17353 -15952 5292 -12196 900000 SO 20180131T124533.0Z 6605.531632 5 1 36.01 2 89.23 115.15 92.28 295.33 0.00 1 0.00 1 0 15 2.496e-02 2.476e-02 2.102e-02 2.087e-02 6.130027e+03 1.213198e+03 2.814603e+02 -6.000000e+00 1.238766e+03 271.77 -2.00 20.00 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