File name: Pandora103s1_Downsview_20180201_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T231337.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180201_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180201 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180201T122834.0Z 6606.519838 2 1 36.00 2 91.86 112.01 82.09 280.63 0.00 1 0.00 1 0 57 5.341e-01 3.418e-01 5.279e-01 3.815e-01 -1.906647e+04 2.057353e+04 9.630963e+02 -6.000000e+00 2.811517e+04 271.77 -2.00 20.00 -2.00 505.38 0.00e+00 6.678757e-03 1.078827e-02 3.973176e-04 -6.000000e+00 1.432996e-02 271.77 -2.00 20.00 -2.00 499.97 0.00e+00 5.870068e+00 8.042069e+00 4.170140e-01 -6.000000e+00 1.041369e+01 224.08 -2.00 3.57 -2.00 501.69 0.00e+00 18.875 0.131 489.00 513.00 1 1.1316e+01 6.2950e-01 4.5090e-02 -6.0000e+00 7.9301e-01 8.2750e-02 1.5085e-01 6.1518e-03 -6.0000e+00 2.0879e-01 8.6683e-07 4.3252e-02 2.6999e-02 2.2764e-04 -6.0000e+00 4.1918e-02 -2.0061e-01 2.5803e-03 12 8 8 10 0 0 -3.61 15.00 34.18 -0.20061 0.09940 9 1 1 4 0 4000.000 21.98 15.00 19.00 -22892 -1310 42612 -2716 19284 12444 -16667 54199 -28494 46697 126 -3498 -36849 9141 -21312 38077 43531 98271 6165 -4305 34932 11078 66289 7106 187654 -35504 35312 -3584 92499 43742 101883 -15845 -4680 87905 -29330 78573 38817 -19081 -5953 -5076 19017 51645 1679 438 38047 73486 10363 63876 19826 14233 87686 43310 -14045 9511 -17932 18959 107594 -3871 113657 -33868 -6905 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26790 17746 -3448 11288 13871 45478 25922 32787 24071 40185 38873 -34845 40249 5699 48687 -93515 43141 23098 19033 -19783 17760 44562 900000 -25531 41504 -21445 42528 37389 39143 30127 23074 35765 6359 37108 8535 44021 -39670 900000 28911 35248 -11487 13769 12984 34664 -41459 1821 -63776 42334 27830 15490 -22 13066 40929 42424 35550 806 25840 32091 8210 23733 41438 -42058 21986 -53234 26239 -24867 10175 -2199 -41981 -22300 -20723 19493 13889 35324 15076 34947 900000 900000 SO 20180201T123251.0Z 6606.522812 9 1 36.00 2 91.14 112.74 82.83 281.31 0.00 1 0.00 1 0 88 2.845e-01 2.256e-01 2.413e-01 2.118e-01 -8.479816e+03 1.130009e+04 1.858733e+03 -6.000000e+00 1.464771e+04 271.77 -2.00 20.00 -2.00 505.34 0.00e+00 3.503253e-03 5.517539e-03 8.295673e-05 -6.000000e+00 7.591506e-03 271.77 -2.00 20.00 -2.00 499.91 0.00e+00 7.546906e+00 4.138887e+00 4.793260e-02 -6.000000e+00 5.503344e+00 224.08 -2.00 3.57 -2.00 501.62 0.00e+00 20.518 0.168 489.00 513.00 1 1.0444e+01 3.1424e-01 3.7080e-02 -6.0000e+00 4.1846e-01 3.1979e-02 8.1538e-02 2.2524e-03 -6.0000e+00 1.1130e-01 1.6878e-06 1.8211e-02 1.5848e-02 2.5639e-04 -6.0000e+00 2.2192e-02 -3.3355e-02 4.5388e-04 12 8 8 10 0 0 10.96 15.00 19.22 -0.03336 0.09296 9 1 1 4 0 4000.000 21.98 15.00 19.02 4720 9076 -13292 5267 23147 49880 -7966 -15985 22577 -10928 -15842 -38062 25932 -23327 -8696 -20594 14757 2289 19156 -9668 7934 35044 6230 7309 50763 9417 5911 20056 11493 29445 -7667 1615 -16387 16044 4083 2736 -9892 75112 -12918 54525 10911 37371 -23210 62820 -12453 2862 21253 14317 53853 -606 4975 -15064 -1160 -3185 16467 -9768 7460 -28195 47303 9291 24018 -19209 20934 11031 14845 1244 25837 69695 19154 6827 6108 24254 -4579 9199 -3553 54945 -5475 9267 -33272 58172 -40600 6682 -23286 -1278 -13806 29368 46120 31901 65253 -16782 25778 26336 19907 21102 19209 -19146 68983 -11002 1600 2336 900000 2214 52162 -16668 -15485 -21260 60639 -20102 18389 10394 13947 17583 25657 -5690 47986 18856 -14391 40911 13880 26498 3691 15817 -10371 33384 -24835 40318 -5628 20029 -44049 17917 10493 12924 -14456 2022 73264 60396 3457 -6068 -11801 -7780 -2210 23506 29245 -15339 69814 -9870 53281 -14609 50348 -28424 900000 4477 8564 -16215 5526 20864 35625 -10013 -21704 20874 -13656 -20508 -60154 21853 -31227 -10131 -27249 14279 2579 18615 -12350 8559 29223 6867 8056 37054 10165 6564 18995 11291 23742 -8831 1733 -21833 16296 4671 3123 -12566 41825 -16464 36521 11175 30052 -33810 40685 -16599 3269 20067 14191 35731 -651 4920 -17724 -1199 -3464 15379 -12004 7820 -41353 33435 9403 21235 -25758 19052 10901 13867 1295 20922 36755 16007 6308 5678 19131 -4822 8593 -3709 31951 -5528 8046 -43236 31717 -57301 5997 -27807 -1246 -15234 21416 28603 22658 33914 -19107 19840 20672 16883 17750 16489 -23667 35977 -11865 1483 2122 900000 2069 31225 -19309 -17293 -24400 31205 -22071 14155 8841 11785 14782 20416 -6179 31404 16252 -16859 27731 11955 20095 3461 13283 -11378 24286 -31476 27510 -5939 16581 -68038 15233 9404 11082 -15797 1870 34993 33656 3393 -6608 -13674 -8668 -2332 19585 23363 -18916 38061 -11195 31891 -16258 30205 -36907 900000 SO 20180201T123712.0Z 6606.525833 16 1 36.01 2 90.42 113.49 83.57 282.00 0.00 1 0.00 1 0 60 1.330e-01 1.172e-01 1.283e-01 1.226e-01 -2.089928e+04 6.120891e+03 1.371277e+03 -6.000000e+00 6.598506e+03 271.77 -2.00 20.00 -2.00 505.15 0.00e+00 1.097089e-02 3.180790e-03 4.955845e-04 -6.000000e+00 3.540289e-03 271.77 -2.00 20.00 -2.00 499.88 0.00e+00 6.156406e+00 2.415451e+00 1.027150e-01 -6.000000e+00 2.542597e+00 224.08 -2.00 3.57 -2.00 501.54 0.00e+00 21.057 0.182 489.00 513.00 1 9.8614e+00 1.8490e-01 4.0940e-02 -6.0000e+00 1.9380e-01 1.2856e-01 4.7937e-02 2.1925e-03 -6.0000e+00 5.1044e-02 3.0529e-06 3.3328e-02 7.6133e-03 2.2491e-04 -6.0000e+00 1.0304e-02 5.7191e-02 -4.0555e-04 12 8 8 10 0 0 77.97 15.00 7.09 0.05719 0.28837 9 1 1 4 0 4000.000 21.98 15.00 19.03 -7953 14709 -6989 1210 -6708 -6024 9490 -4539 4675 4416 26352 11438 -5752 -8528 14733 4647 17267 3910 4574 -10426 13540 -2285 1765 -1044 847 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