File name: Pandora103s1_Downsview_20180206_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T231339.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180206_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180206 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180206T122841.0Z 6611.519919 349 1 36.00 2 90.85 110.90 59.48 215.69 0.00 1 0.00 1 0 21 1.176e+00 6.918e-01 7.482e-01 5.320e-01 -4.454622e+04 2.891677e+04 3.210244e+03 -6.000000e+00 6.311488e+04 271.77 -2.00 20.00 -2.00 505.29 0.00e+00 -2.369563e-02 1.440018e-02 1.974920e-03 -6.000000e+00 3.260848e-02 271.77 -2.00 20.00 -2.00 499.84 0.00e+00 1.729671e+01 1.093991e+01 6.424040e-01 -6.000000e+00 2.364297e+01 224.28 -2.00 3.57 -2.00 501.55 0.00e+00 20.897 0.178 489.00 513.00 1 1.1064e+01 8.3068e-01 7.6195e-02 -6.0000e+00 1.8062e+00 -1.2326e-01 2.1918e-01 1.3369e-02 -6.0000e+00 4.7467e-01 5.1052e-07 2.0948e-02 2.8386e-02 5.0407e-04 -6.0000e+00 9.4034e-02 2.0288e-01 -1.7918e-03 12 8 8 10 0 0 -7.42 15.00 33.09 0.20288 0.34818 9 1 1 4 0 4000.000 21.98 15.00 18.93 900000 42302 -57116 128872 80572 7386 -38829 -37808 73320 438533 43099 32709 -28433 27061 98751 146431 58381 -31941 7883 -7947 215602 86592 92700 84366 121423 -17748 102153 -20525 98446 -32986 53225 26383 83494 -21668 -28177 455316 28237 50163 -6133 56661 -14775 900000 10768 205257 98727 195888 -25287 61839 -28601 -66182 62168 900000 -7534 39728 15720 66546 -11613 6483 267663 -41909 78564 -27481 151653 -21649 900000 -10950 199473 -60760 293353 41843 565655 2716 900000 22646 166831 73225 343529 12385 21722 179359 -36932 48156 -30890 900000 15978 83557 66709 12081 -22073 75926 24146 27782 140705 61160 32003 96438 25422 900000 197011 50873 -36432 -21610 43215 -3118 216543 -16814 29098 28774 44288 -52602 900000 -65762 178786 -13843 85572 -330 900000 -5218 8281 66727 77594 70726 -22742 -122 28392 267157 -60869 104374 39343 -26677 80457 900000 -31795 900000 43749 900000 6996 45415 16665 63257 24432 79255 55969 197314 90458 29045 26917 -56462 -14991 5266 73423 900000 29095 -103333 67067 42452 7903 -66137 -65111 45073 228217 35130 29393 -44860 25191 51391 76204 42778 -57322 10131 -12058 112202 54997 55280 54165 63190 -28982 53947 -33901 51971 -57522 41044 26357 50332 -36589 -51867 236951 29929 42505 -8576 42898 -21384 900000 11949 106818 51379 101942 -37439 39605 -41579 -131975 35566 900000 -7756 26458 13461 36438 -13308 6229 139295 -61170 40885 -34567 78922 -25406 900000 -11188 103808 -95680 152664 24417 294372 2274 900000 16338 86820 38107 178776 9314 14929 93340 -45346 27323 -36840 900000 12606 43484 34716 10525 -27524 39512 19867 22145 73224 37392 26955 50187 25401 900000 102527 36699 -60189 -31583 34863 -3868 112691 -21075 22632 21732 28289 -82562 900000 -122178 93042 -17108 44533 -364 900000 -5441 7292 34725 40381 36807 -28756 -126 22178 139031 -108007 54317 27553 -35048 41871 900000 -42684 900000 27519 900000 6699 31955 15639 38454 21166 41354 37290 102684 47075 26512 24357 -106976 -18670 5422 40822 SO 20180206T123249.0Z 6611.522789 353 1 36.01 2 90.16 111.61 59.92 216.73 0.00 1 0.00 1 0 22 5.484e-01 3.269e-01 4.592e-01 3.210e-01 -1.258626e+04 1.791244e+04 4.947164e+02 -6.000000e+00 2.723474e+04 271.77 -2.00 20.00 -2.00 505.33 0.00e+00 6.156724e-03 8.592909e-03 1.135141e-04 -6.000000e+00 1.462173e-02 271.77 -2.00 20.00 -2.00 499.79 0.00e+00 1.453935e+01 6.633773e+00 2.154103e-01 -6.000000e+00 1.055598e+01 224.28 -2.00 3.57 -2.00 501.47 0.00e+00 20.900 0.178 489.00 513.00 1 1.0225e+01 5.1151e-01 4.1717e-02 -6.0000e+00 8.0359e-01 -1.1249e-01 1.2875e-01 4.6210e-03 -6.0000e+00 2.1346e-01 1.0432e-06 1.8521e-02 2.2265e-02 8.4695e-05 -6.0000e+00 4.2737e-02 -7.6033e-02 9.0053e-04 12 8 8 10 0 0 -0.43 14.99 8.85 -0.07603 0.05244 9 1 1 4 0 4000.000 21.98 14.99 18.95 9929 -12430 -5418 -7263 70380 132326 -3580 111592 -11813 32660 54042 20971 -10263 55161 6157 72416 -14912 66695 -24355 103447 -5706 1772 -3511 13304 36532 -3983 8633 25960 19826 14938 10396 59443 -3106 33299 9201 -15931 -12526 -26530 -46859 9539 14591 18107 37431 -7053 -10241 -13901 43586 -18300 33409 22178 -19649 102909 -16787 -9422 6207 103071 43375 76158 249 151014 -18678 50503 -36063 -12097 25927 20329 14656 56625 -3670 66617 -1471 79380 27987 25710 59190 20263 37113 -14977 97949 -50396 81556 -49140 135633 54060 -26316 14456 97180 -47087 16532 76539 37525 11321 15140 42111 25959 11995 39239 22336 -14802 34351 -25419 102904 -16882 70837 8135 133306 17357 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10788 7433 -66292 51568 28175 39947 25260 34064 35049 78 -38014 16621 -5054 49233 40969 -27347 20825 44110 -52536 45176 36749 30048 47331 23642 46819 -52129 14102 -24759 31509 17381 42708 900000 SO 20180206T123653.0Z 6611.525613 357 1 36.00 2 89.48 112.32 60.37 217.74 0.00 1 0.00 1 0 92 2.312e-01 1.925e-01 2.134e-01 1.935e-01 1.730057e+03 1.073025e+04 3.579479e+02 -6.000000e+00 1.147051e+04 271.77 -2.00 20.00 -2.00 505.22 0.00e+00 3.274908e-03 4.934893e-03 3.374865e-04 -6.000000e+00 6.163406e-03 271.77 -2.00 20.00 -2.00 499.87 0.00e+00 4.464734e+00 3.855322e+00 1.648860e-01 -6.000000e+00 4.462970e+00 224.28 -2.00 3.57 -2.00 501.50 0.00e+00 19.927 0.154 489.00 513.00 1 1.0659e+01 2.9109e-01 3.7839e-02 -6.0000e+00 3.3950e-01 9.7365e-02 7.7201e-02 3.0292e-03 -6.0000e+00 9.0647e-02 1.8781e-06 -1.0454e-02 1.4392e-02 7.8355e-05 -6.0000e+00 1.8030e-02 1.2237e-01 -1.2930e-03 12 8 8 10 0 0 88.76 15.00 10.02 0.12237 0.04985 9 1 1 4 0 4000.000 21.98 15.00 18.95 900000 -2855 15254 3678 -155 13637 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