File name: Pandora103s1_Downsview_20180213_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T231325.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180213_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180213 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180213T121923.0Z 6618.513461 442 1 36.01 2 90.85 107.69 79.36 130.90 0.00 1 0.00 1 0 15 4.841e-02 4.823e-02 4.896e-02 4.846e-02 4.943876e+03 2.870695e+03 2.813064e+02 -6.000000e+00 2.404074e+03 271.77 -2.00 20.00 -2.00 505.35 0.00e+00 1.505390e-03 1.266409e-03 1.017315e-04 -6.000000e+00 1.291245e-03 271.77 -2.00 20.00 -2.00 500.37 0.00e+00 3.685603e+00 9.382593e-01 5.535010e-02 -6.000000e+00 9.347169e-01 224.56 -2.00 3.57 -2.00 501.99 0.00e+00 20.901 0.178 489.00 513.00 1 9.1925e+00 7.1373e-02 3.8622e-02 -6.0000e+00 7.1118e-02 5.0856e-02 1.8583e-02 2.3808e-03 -6.0000e+00 1.8958e-02 8.0618e-06 1.1529e-03 3.6299e-03 4.5643e-05 -6.0000e+00 3.7750e-03 -7.3377e-03 2.7615e-04 12 8 8 10 0 0 4.85 15.00 3.06 -0.00734 0.00066 9 1 1 4 0 4000.000 22.09 15.00 19.07 -4323 -3964 3349 -1811 -608 -5291 2309 8696 -1889 7394 -2863 -9308 1085 352 3648 -6835 -1119 4749 -11731 2360 -316 4508 3457 4858 -2558 3627 2669 3745 -2516 -827 1250 3793 -4457 1304 977 -1931 -2015 -2182 10592 -3523 11908 5945 -6179 -4654 -1568 9064 8232 -2561 -320 -5106 7287 1431 764 -6930 5089 1175 -6275 -5036 425 -3034 192 6382 157 2870 2427 9323 -4680 1682 -7907 -8032 4870 -5807 11641 -2015 -826 5969 -307 -2261 11807 3084 796 6531 3244 -9941 141 -3204 5409 -1965 5003 -1885 -778 -1149 6888 3065 -934 1276 -4608 3130 -7563 -3384 5418 2181 -1498 2026 4141 76 -6931 4659 -527 4008 -3731 -2048 -6043 8818 -7878 6693 4735 2503 -8308 1077 3220 -3891 3052 -1111 6197 6374 3154 -4099 -1453 -8546 3835 5722 4609 -486 650 1461 1398 739 -1761 -2957 -406 -1991 -1410 4228 -3292 -1396 -5192 356 -685 3559 900000 -4024 -3740 3055 -1815 -618 -5737 2380 8534 -2056 7248 -3046 -10435 1083 348 3469 -7216 -1132 4672 -14022 2495 -342 4662 3611 5022 -2870 3839 2840 3924 -2736 -845 1221 3627 -4709 1362 1065 -2179 -2243 -2398 10140 -3828 11137 5939 -7030 -5288 -1750 9149 8325 -2836 -341 -5561 6787 1369 724 -7114 4800 1197 -7044 -5624 448 -3283 201 6338 166 2957 2488 8775 -4943 1646 -8406 -8402 4428 -5876 10042 -2019 -830 5560 -296 -2168 9774 2763 730 5727 2949 -10329 135 -3190 4945 -1920 4544 -1830 -751 -1131 6397 2960 -920 1199 -4464 2731 -7136 -2993 4362 1842 -1364 1881 3887 75 -7127 4190 -492 3618 -3710 -2038 -6332 8055 -8488 6286 4587 2501 -9156 1064 3056 -3881 2829 -1087 5706 5861 3001 -4173 -1438 -9132 3615 5173 4140 -455 601 1368 1352 733 -1813 -3123 -421 -2104 -1493 4266 -3585 -1484 -5607 353 -671 3345 900000 SO 20180213T122325.0Z 6618.516262 446 1 36.00 2 90.16 108.38 78.83 131.67 0.00 1 0.00 1 0 15 1.651e-02 1.632e-02 1.505e-02 1.499e-02 1.656209e+03 7.888432e+02 4.788294e+01 -6.000000e+00 8.197266e+02 271.77 -2.00 20.00 -2.00 505.38 0.00e+00 3.415674e-03 3.919058e-04 1.650842e-04 -6.000000e+00 4.404291e-04 271.77 -2.00 20.00 -2.00 500.79 0.00e+00 2.375977e+00 2.833590e-01 4.186726e-02 -6.000000e+00 3.189976e-01 224.56 -2.00 3.57 -2.00 502.34 0.00e+00 20.901 0.178 489.00 513.00 1 8.0623e+00 2.1542e-02 3.8658e-02 -6.0000e+00 2.4267e-02 3.6769e-02 5.6478e-03 2.1830e-03 -6.0000e+00 6.4755e-03 2.7068e-05 1.4858e-03 1.1524e-03 4.1801e-05 -6.0000e+00 1.2875e-03 2.6968e-02 1.3653e-05 12 8 8 10 0 0 16.45 15.00 1.77 0.02697 0.03727 9 1 1 4 0 4000.000 22.09 15.00 19.07 -4220 -1906 -1517 451 -1047 -790 46 676 -1516 1543 930 2127 -2576 521 -1511 90 -550 563 1152 -68 2624 1592 -128 -1646 342 2282 443 -281 -352 -56 -2315 -696 -778 -1334 432 2449 1180 -2819 -1791 1153 -872 1500 2914 397 2603 1717 -1185 1027 2014 2196 -746 -2951 -1138 -375 -440 -1350 898 377 439 2926 717 -1366 515 2733 -653 -379 -1024 2265 1417 -125 -978 -1142 -2639 664 -1577 -1732 1970 -402 -222 -3149 -4175 -1460 -111 -2453 2315 2213 4026 -1944 1817 -1021 718 676 77 2454 1555 -672 -660 -2446 -2134 1071 -2841 2249 -1556 3698 -588 -548 -2150 -959 -567 -977 -1005 905 2011 1724 -2559 2762 1620 -103 890 -941 802 1306 -668 332 1612 792 2377 703 546 444 231 -791 283 -788 725 -1008 -350 -1943 1602 435 -1010 -2083 1608 252 -1408 -441 -550 2462 -1483 -2937 900000 -3710 -1668 -1373 418 -1011 -776 46 679 -1555 1513 900 2014 -2514 486 -1426 84 -522 544 1143 -70 2595 1593 -130 -1707 352 2313 456 -290 -355 -54 -2216 -659 -751 -1355 449 2514 1210 -2963 -1841 1142 -883 1500 2915 413 2690 1799 -1271 1065 2038 2168 -732 -2878 -1073 -354 -429 -1383 924 393 457 2952 738 -1448 539 2800 -686 -390 -1041 2201 1375 -121 -942 -1106 -2621 650 -1601 -1748 1870 -382 -209 -3035 -4078 -1404 -106 -2403 2194 2117 3783 -1927 1731 -1001 697 668 78 2463 1556 -675 -650 -2389 -2023 960 -2616 1997 -1482 3511 -597 -553 -2164 -935 -545 -953 -1004 907 2030 1767 -2749 2834 1697 -111 934 -988 814 1299 -674 337 1632 809 2397 719 558 458 238 -804 280 -777 701 -1009 -359 -2063 1664 462 -1093 -2282 1711 274 -1562 -481 -589 2475 -1510 -3031 900000 SO 20180213T122717.0Z 6618.518947 450 1 36.01 2 89.50 109.05 78.32 132.42 0.00 1 0.00 1 0 15 9.189e-03 8.914e-03 2.424e-03 2.411e-03 3.891418e+03 1.313781e+02 2.769123e+02 -6.000000e+00 4.562833e+02 271.77 -2.00 20.00 -2.00 505.40 0.00e+00 4.266568e-03 6.304567e-05 2.198623e-04 -6.000000e+00 2.451114e-04 271.77 -2.00 20.00 -2.00 501.08 0.00e+00 1.777197e+00 4.476245e-02 4.869863e-02 -6.000000e+00 1.774913e-01 224.56 -2.00 3.57 -2.00 502.58 0.00e+00 19.965 0.155 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