File name: Pandora103s1_Downsview_20180227_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T231453.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180227_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180227 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180227T115747.0Z 6632.498461 345 1 36.00 2 90.85 100.64 104.30 312.26 0.00 1 0.00 1 0 15 6.392e-02 6.117e-02 6.047e-02 5.960e-02 2.514518e+03 3.392696e+03 9.114925e+01 -6.000000e+00 3.185363e+03 272.71 -2.00 20.00 -2.00 505.29 0.00e+00 5.243720e-03 1.570640e-03 2.398805e-04 -6.000000e+00 1.709364e-03 272.71 -2.00 20.00 -2.00 500.19 0.00e+00 3.970746e+00 1.171445e+00 5.656666e-02 -6.000000e+00 1.236455e+00 225.12 -2.00 3.57 -2.00 501.81 0.00e+00 20.881 0.177 489.00 513.00 1 9.3292e+00 8.9411e-02 3.8935e-02 -6.0000e+00 9.4058e-02 7.5623e-02 2.3327e-02 2.2815e-03 -6.0000e+00 2.5140e-02 6.5461e-06 1.5135e-03 4.5149e-03 6.2314e-05 -6.0000e+00 4.9846e-03 4.4197e-02 -1.9546e-04 12 8 8 10 0 0 0.63 15.00 3.14 0.04420 0.05470 9 1 1 4 0 4000.000 22.09 15.00 19.18 -10193 -10381 4645 -4497 -1104 381 9846 -1307 3442 -4967 2285 -3506 8046 3962 2070 4356 -464 1018 -2151 10345 -3497 -5932 10535 8883 -860 10773 -3274 1533 -2648 -2023 3889 -4847 -6442 13103 5339 5980 1797 -6529 -242 -732 -7801 -15914 -1145 11758 2291 1029 2961 122 -5572 -6965 1027 4468 4299 -4511 10293 -2618 4451 -599 -2783 -7329 6352 19817 -2335 -507 5373 -6552 7578 -42 -1877 -1033 -2136 8082 -380 -3200 -3922 4560 -9492 12406 -7360 -4044 8213 -9366 4500 7311 23 5874 4873 -4894 -2441 -641 -2870 -2177 -7972 -4215 26589 -3121 -6860 -1731 5533 -5467 5013 8218 -1769 -8250 624 -2177 7698 -1621 12891 -4980 -4087 4078 -3350 11546 2962 4775 -8075 2435 -2691 -1371 6431 339 4077 1172 -6450 10809 1508 14600 -6463 -1426 5243 870 3776 -3940 2719 -293 -3123 -7787 6552 -2272 1504 -4742 -99 1786 2580 -7789 401 852 2056 628 900000 -10364 -10731 4302 -4759 -1162 403 9709 -1454 3655 -5637 2364 -3790 7654 3854 2031 4180 -471 1044 -2351 10165 -3916 -6802 10289 8847 -953 10710 -3720 1655 -2913 -2112 3718 -5048 -6928 12150 5571 6261 1932 -7495 -258 -777 -8878 -19790 -1252 11513 2494 1141 3210 135 -6375 -7895 1041 4247 4020 -4607 9378 -2814 4587 -654 -3099 -8464 6404 17657 -2594 -552 5481 -7372 7273 -43 -1922 -1030 -2116 7244 -372 -3272 -4097 4358 -10125 10430 -7415 -3918 7059 -9627 4053 6411 21 5311 4438 -4865 -2353 -606 -2782 -2127 -8448 -4354 20132 -3093 -6904 -1612 4665 -4987 4065 6503 -1586 -8249 589 -2104 6639 -1499 10217 -4742 -3953 3724 -3350 10129 2842 4522 -8745 2395 -2762 -1365 5828 321 3691 1107 -6638 9419 1442 12287 -6652 -1408 4844 820 3391 -3766 2419 -273 -3073 -8184 6060 -2317 1485 -4981 -100 1783 2565 -8528 398 812 1884 582 900000 SO 20180227T120148.0Z 6632.501250 349 1 36.00 2 90.14 101.34 104.82 313.04 0.00 1 0.00 1 0 22 3.355e-02 3.325e-02 3.202e-02 3.180e-02 3.849353e+02 1.640218e+03 5.052077e+01 -6.000000e+00 1.672321e+03 272.71 -2.00 20.00 -2.00 505.33 0.00e+00 1.860697e-03 8.327444e-04 1.106161e-04 -6.000000e+00 8.968583e-04 272.71 -2.00 20.00 -2.00 500.36 0.00e+00 3.492835e+00 6.118819e-01 2.301988e-02 -6.000000e+00 6.480847e-01 225.12 -2.00 3.57 -2.00 501.99 0.00e+00 20.855 0.177 489.00 513.00 1 8.7773e+00 4.6641e-02 3.8306e-02 -6.0000e+00 4.9317e-02 6.3142e-02 1.2258e-02 2.1170e-03 -6.0000e+00 1.3153e-02 1.2510e-05 6.6934e-03 2.4405e-03 2.7055e-05 -6.0000e+00 2.6166e-03 4.2037e-02 -5.3467e-05 12 8 8 10 0 0 -2.95 15.00 1.10 0.04204 0.08847 9 1 1 4 0 4000.000 22.19 15.00 19.21 1950 -3106 2448 -1246 9518 5746 2008 294 39 1319 -481 -3415 63 -10587 -5557 518 456 -287 -4435 629 -22 2401 -467 1653 -2497 -341 -1843 4813 217 2729 351 778 -766 1346 -2234 -2884 732 -4092 5410 1372 6604 -2530 -1479 -2850 3502 3130 5246 -1736 386 1080 -1095 -94 -4856 421 -1618 2386 4269 1937 1650 -1519 -1484 -170 -3389 7417 125 7285 -4515 -876 -4094 3275 -1836 90 -1070 157 -5126 3822 8103 -2757 -2775 143 1514 -6147 -3441 -3750 -3220 -3378 2473 6279 -2915 2271 5139 -4257 5950 -1846 1370 -818 7226 -1140 -358 -3533 -3824 2381 843 2614 -2803 -2762 2558 -729 1792 3401 2044 97 6418 176 -2697 -2941 1940 668 -1077 -2034 130 4220 -582 2881 -351 2608 4292 -1834 -177 -1997 223 1924 -5747 -385 -734 -1924 -1860 -306 -5316 -6747 -1025 3372 4118 -539 4816 -3586 228 2660 2289 4334 900000 1716 -2942 2289 -1256 8825 5643 2089 314 41 1361 -497 -3593 63 -11583 -5761 509 456 -299 -4953 673 -24 2523 -504 1759 -2789 -373 -2035 4940 226 2645 343 765 -786 1419 -2510 -3249 784 -4528 5384 1409 6472 -2734 -1604 -3173 3704 3322 5404 -1885 404 1089 -1087 -90 -4819 403 -1641 2412 4317 2008 1705 -1608 -1573 -179 -3699 7256 129 6906 -4709 -871 -4153 3034 -1770 85 -1043 154 -5337 3588 7094 -2633 -2634 132 1384 -6111 -3338 -3675 -3182 -3358 2317 5647 -2864 2127 4715 -4366 5636 -1887 1336 -802 6417 -1067 -324 -3218 -3487 2084 780 2483 -2840 -2758 2376 -685 1633 3101 1930 95 6020 177 -2802 -3079 1951 679 -1098 -2053 127 3895 -565 2746 -347 2502 4056 -1831 -174 -2014 218 1804 -5709 -359 -687 -1870 -1860 -306 -5661 -7355 -1059 3347 4095 -565 4801 -3839 229 2519 2137 3992 900000 SO 20180227T120550.0Z 6632.504051 353 1 36.00 2 89.42 102.03 105.33 313.82 0.00 1 0.00 1 0 15 1.395e-02 1.365e-02 6.914e-03 6.851e-03 5.357120e+03 3.990541e+02 3.462347e+02 -6.000000e+00 6.948878e+02 272.71 -2.00 20.00 -2.00 505.54 0.00e+00 6.006851e-03 1.821214e-04 3.087621e-04 -6.000000e+00 3.729064e-04 272.71 -2.00 20.00 -2.00 501.13 0.00e+00 1.983359e+00 1.289279e-01 7.184125e-02 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