File name: Pandora103s1_Downsview_20180305_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T231655.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180305_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180305 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180305T114745.0Z 6638.491493 318 1 36.01 2 90.83 97.48 69.39 236.98 0.00 1 0.00 1 0 8 4.309e-02 4.269e-02 3.747e-02 3.707e-02 -9.604661e+02 1.962007e+03 2.436070e+02 -6.000000e+00 2.151722e+03 273.15 -2.00 20.00 -2.00 505.31 0.00e+00 3.495983e-03 9.747814e-04 1.633326e-04 -6.000000e+00 1.153051e-03 273.15 -2.00 20.00 -2.00 500.18 0.00e+00 4.944768e+00 7.266540e-01 4.090948e-02 -6.000000e+00 8.321443e-01 225.36 -2.00 3.57 -2.00 501.83 0.00e+00 20.889 0.178 489.00 513.00 1 8.7977e+00 5.5608e-02 3.8613e-02 -6.0000e+00 6.3336e-02 5.9305e-02 1.4471e-02 2.1622e-03 -6.0000e+00 1.6883e-02 1.0705e-05 2.3383e-03 2.8424e-03 5.1834e-05 -6.0000e+00 3.3605e-03 2.8231e-02 5.5471e-05 12 8 8 10 0 0 13.83 15.01 3.49 0.02823 0.04445 9 1 1 4 0 4000.000 22.09 15.01 19.12 -1432 1935 -9049 -731 -7544 -1556 1077 4271 -3596 3880 -2302 -290 8431 -2336 5540 -6072 583 -837 1443 -614 4134 -5142 2276 -4996 3929 2254 6161 1327 -1043 -3496 -2362 -2969 -1218 1893 2201 -1360 2686 -472 -1421 2928 -5049 183 -5262 6118 -4782 11499 -2492 5590 -3347 7167 7353 2245 816 2978 5495 577 7266 740 3047 -3526 2722 -868 -77 -2804 2141 -32 6410 2061 -2407 -2929 -5202 143 -6328 3306 -217 -8855 2017 1977 26 -241 -3007 -5177 -5367 8723 816 3803 87 -532 1109 91 -9645 2076 -1420 102 1065 7302 -3337 3604 -6588 1548 -3506 1197 5926 4664 -3359 479 2051 3227 8048 3866 -6257 4830 -1784 1376 2670 -900 9859 580 2607 2613 -5420 2826 -129 -8214 5181 7045 -4308 -5314 -640 2373 -5239 7339 -3181 -1267 -5301 8970 1094 3083 963 -2374 -4169 2877 -1316 -1935 2539 -7943 4084 -5977 -1201 4205 900000 -1332 1776 -9612 -748 -8443 -1674 1156 4489 -4072 4016 -2483 -303 7970 -2415 5266 -6480 591 -886 1542 -676 4332 -5906 2431 -5755 4192 2449 6421 1441 -1128 -3694 -2413 -3067 -1263 1995 2398 -1538 2874 -513 -1539 3011 -5625 196 -6010 6343 -5581 11482 -2832 5783 -3713 6992 6906 2153 782 2815 5241 600 7234 789 3164 -3869 2808 -934 -83 -3075 2213 -33 6098 2015 -2430 -2915 -5215 136 -6492 3137 -215 -9452 1882 1805 24 -221 -2849 -5058 -5258 7469 764 3472 82 -503 1028 85 -9989 1952 -1414 101 1032 6572 -3277 3218 -6300 1331 -3134 1035 5053 4198 -3322 450 1857 2826 6663 3379 -6182 4379 -1760 1335 2576 -903 8966 577 2508 2468 -5457 2592 -122 -8528 4756 6351 -4350 -5401 -621 2257 -5333 6463 -3047 -1175 -5087 7643 1039 2928 946 -2432 -4355 2809 -1349 -2015 2541 -8740 3897 -6073 -1138 3785 900000 SO 20180305T115146.0Z 6638.494282 322 1 36.00 2 90.11 98.17 69.99 237.79 0.00 1 0.00 1 0 15 1.573e-02 1.576e-02 1.516e-02 1.509e-02 3.383973e+03 8.652505e+02 2.472623e+02 -6.000000e+00 7.853031e+02 273.15 -2.00 20.00 -2.00 505.34 0.00e+00 2.534008e-03 3.948777e-04 1.385242e-04 -6.000000e+00 4.211335e-04 273.15 -2.00 20.00 -2.00 500.43 0.00e+00 3.187787e+00 2.917903e-01 3.592502e-02 -6.000000e+00 3.041379e-01 225.36 -2.00 3.57 -2.00 502.03 0.00e+00 20.815 0.176 489.00 513.00 1 8.0166e+00 2.2184e-02 3.8312e-02 -6.0000e+00 2.3143e-02 5.7689e-02 5.8167e-03 2.2039e-03 -6.0000e+00 6.1785e-03 2.7094e-05 6.0798e-04 1.1434e-03 4.7266e-05 -6.0000e+00 1.2270e-03 1.9857e-02 1.8424e-05 12 8 8 10 0 0 7.05 15.00 2.45 0.01986 0.02407 9 1 1 4 0 4000.000 22.09 15.00 19.13 -3067 281 -2703 -1993 1436 1408 1086 318 430 2346 -1367 -659 134 -724 1916 -1798 -113 -598 1061 -572 321 -1250 213 -275 2370 -1652 -869 -715 1834 -2085 -1032 -591 -1589 1333 1872 2676 2817 448 383 496 -1713 2406 -2885 1917 1327 2572 784 -2217 -863 612 579 -1004 -1123 -3568 -1640 -905 -1105 -239 1535 1195 821 -934 1177 -3928 1864 -1212 1324 224 126 -944 1309 -54 1084 -2109 898 2814 -2006 847 -297 3378 -1544 535 -703 358 1967 1368 -769 3962 792 -549 1238 1091 -2000 374 -1712 -955 378 1579 -1448 1442 -1182 -1823 398 -918 662 -1016 261 -2607 -2272 -175 699 -637 1936 -12 40 3438 140 -443 -175 -639 -1094 -120 -721 1397 -674 -1424 2065 994 1341 8 -513 397 -153 -184 92 -826 3348 -589 -2899 -1467 -797 -308 2131 1871 395 2158 1514 -3764 -593 -2030 900000 -2801 252 -2585 -1978 1417 1416 1121 335 453 2397 -1421 -672 134 -717 1833 -1784 -112 -609 1100 -613 340 -1346 226 -294 2494 -1814 -944 -772 1894 -2138 -1017 -581 -1604 1364 1988 2848 2954 474 400 511 -1806 2457 -3139 2020 1425 2742 847 -2432 -920 629 575 -982 -1080 -3523 -1638 -934 -1173 -254 1600 1240 853 -994 1234 -4321 1925 -1267 1323 222 124 -926 1236 -52 1037 -2113 887 2714 -1976 792 -278 3033 -1455 499 -667 337 1847 1305 -748 3665 752 -528 1174 1051 -2031 374 -1722 -933 356 1432 -1316 1243 -1032 -1620 358 -879 645 -1005 251 -2525 -2162 -164 666 -628 1888 -12 40 3369 143 -459 -180 -647 -1093 -116 -699 1345 -670 -1426 2003 973 1303 8 -510 383 -146 -173 85 -790 3176 -592 -3018 -1526 -828 -320 2173 1927 414 2215 1534 -3885 -579 -2001 900000 SO 20180305T115532.4Z 6638.496902 326 1 10.70 2 89.43 98.82 70.56 238.54 0.00 1 0.00 1 0 22 9.360e-03 9.162e-03 1.895e-03 1.887e-03 5.984527e+03 1.085162e+02 4.142928e+02 -6.000000e+00 4.674423e+02 273.15 -2.00 20.00 -2.00 505.41 0.00e+00 4.194378e-03 4.997094e-05 2.226748e-04 -6.000000e+00 2.505817e-04 273.15 -2.00 20.00 -2.00 501.01 0.00e+00 2.287780e+00 3.550904e-02 6.186895e-02 -6.000000e+00 1.808389e-01 225.36 -2.00 3.57 -2.00 502.52 0.00e+00 19.814 0.152 489.00 513.00 1 5.1325e+00 2.6990e-03 3.5646e-02 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