File name: Pandora103s1_Downsview_20180317_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T233313.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180317_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180317 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180317T112625.0Z 6650.476678 404 1 36.00 2 90.85 90.94 94.62 93.09 0.00 1 0.00 1 0 22 4.247e-02 4.355e-02 3.691e-02 3.655e-02 2.914381e+03 2.120000e+03 2.043493e+02 -6.000000e+00 2.127670e+03 274.08 -2.00 20.00 -2.00 505.31 0.00e+00 2.658354e-03 9.564672e-04 9.099673e-05 -6.000000e+00 1.139167e-03 274.08 -2.00 20.00 -2.00 500.17 0.00e+00 3.062441e+00 7.161376e-01 2.866914e-02 -6.000000e+00 8.208977e-01 225.89 -2.00 3.57 -2.00 501.81 0.00e+00 20.848 0.177 489.00 513.00 1 8.9234e+00 5.4513e-02 3.8332e-02 -6.0000e+00 6.2483e-02 9.3949e-02 1.4269e-02 2.1756e-03 -6.0000e+00 1.6675e-02 1.0933e-05 2.9566e-03 2.7759e-03 3.6512e-05 -6.0000e+00 3.3120e-03 1.9061e-02 3.7635e-05 12 8 8 10 0 0 97.46 15.00 3.86 0.01906 0.03957 9 1 1 4 0 4000.000 21.79 15.00 18.65 -24397 -7377 248 -262 1081 -2092 7108 -3188 7709 2548 2673 2802 672 -4863 3431 2487 1879 2303 2540 -1250 -1401 2876 -1271 2789 -561 -216 -4420 2336 -1856 4046 -894 923 5519 -482 -3543 3420 -3451 -427 3313 901 2450 -2205 1111 -1087 214 5801 1298 1308 1774 -6093 -2162 -2092 4178 -3137 2596 -1011 -347 4857 1129 8279 -2930 3416 -3174 -847 -3175 2773 -3422 4390 -6447 6598 -265 -776 -959 -876 2678 8235 -1308 2831 94 -4908 8095 -182 9109 -3261 5814 -3888 4404 -2189 5467 449 6895 -3353 6196 1464 550 -7960 4472 3116 878 6098 -2053 -1175 2715 897 -4839 429 -4733 -425 1337 -2310 -592 1318 -7817 7690 -1332 3926 -1951 6374 -752 1101 3911 177 -182 819 -5021 -5587 -2712 -1080 -3391 348 -2734 1815 -1954 -3103 -2950 -3047 4815 -584 3102 524 5469 -791 7017 533 -2729 2035 -1997 -979 -8020 -4045 900000 -28563 -7447 241 -268 1116 -2271 7211 -3616 7852 2686 2759 2857 689 -5169 3337 2447 1883 2363 2687 -1389 -1552 3060 -1406 2978 -625 -241 -5097 2508 -2024 3974 -899 915 5337 -517 -4067 3684 -3914 -463 3419 942 2527 -2399 1186 -1201 236 6087 1414 1404 1864 -6739 -2221 -2085 3853 -3127 2529 -1061 -370 4959 1191 8076 -3182 3516 -3498 -911 -3456 2795 -3587 4203 -6788 6009 -255 -751 -938 -871 2603 7508 -1273 2585 87 -4759 6934 -171 7821 -3172 5244 -3882 4048 -2133 4921 425 6150 -3358 5780 1437 536 -8242 4008 2751 771 4957 -1789 -1030 2375 839 -4911 411 -4685 -395 1206 -2183 -563 1252 -8241 7037 -1335 3757 -1995 6041 -756 1067 3623 167 -171 775 -5073 -5675 -2683 -1048 -3356 334 -2690 1669 -1829 -2905 -2745 -2894 4366 -568 2948 516 5157 -794 6574 535 -2837 2006 -2000 -939 -8036 -3899 900000 SO 20180317T113026.0Z 6650.479468 408 1 36.00 2 90.12 91.63 93.91 93.75 0.00 1 0.00 1 0 15 1.541e-02 1.526e-02 1.556e-02 1.549e-02 2.820277e+03 8.722213e+02 2.429619e+02 -6.000000e+00 7.722145e+02 274.08 -2.00 20.00 -2.00 505.35 0.00e+00 2.132347e-03 4.074498e-04 1.067274e-04 -6.000000e+00 4.134669e-04 274.08 -2.00 20.00 -2.00 500.50 0.00e+00 2.936379e+00 2.979360e-01 2.519586e-02 -6.000000e+00 2.980288e-01 225.89 -2.00 3.57 -2.00 502.10 0.00e+00 20.805 0.175 489.00 513.00 1 8.0615e+00 2.2668e-02 3.8209e-02 -6.0000e+00 2.2682e-02 5.4412e-02 5.9509e-03 2.1488e-03 -6.0000e+00 6.0570e-03 2.6543e-05 -3.6257e-04 1.1808e-03 4.0650e-05 -6.0000e+00 1.2017e-03 1.5881e-02 1.8650e-05 12 8 8 10 0 0 -13.20 15.00 2.47 0.01588 0.01337 9 1 1 4 0 4000.000 21.79 15.00 18.66 415 -3020 -1046 -2204 2213 -928 2867 -2170 2148 -917 619 -52 -2841 -2213 985 -521 -698 755 -1715 2623 -1013 587 -1267 703 156 1878 565 2225 1100 -337 -1726 2717 -1328 -325 606 384 751 -757 495 1070 1416 -248 -214 -1282 -748 -2161 1641 -106 2244 925 657 -2401 148 -3734 897 -177 529 3148 -1479 -257 327 164 336 502 -945 -940 1023 705 -1434 1950 -756 1843 517 927 -1460 740 -2189 1413 -250 623 400 459 -807 274 -1295 -2591 3260 -1929 -819 -757 2479 -1797 1400 -1351 3092 1531 2240 709 -1167 -832 -4278 -1435 190 2620 1027 424 -416 -1546 -631 -464 942 1255 -2220 -480 -1567 1508 -1118 3716 947 279 919 402 -1865 2256 -1464 -988 563 -288 1871 631 862 -915 581 -2463 -22 -1608 1748 -1835 1176 -1201 1495 -2017 2565 829 541 -115 -1146 -1191 -641 -967 900000 363 -2761 -971 -2160 2141 -943 2875 -2319 2207 -959 626 -52 -2897 -2206 943 -506 -686 751 -1808 2704 -1080 616 -1354 738 166 1979 601 2321 1139 -339 -1703 2567 -1326 -335 646 416 799 -806 514 1092 1438 -258 -225 -1382 -813 -2395 1747 -113 2309 943 650 -2370 140 -3664 865 -179 548 3219 -1579 -269 340 171 354 526 -999 -977 1023 696 -1432 1856 -726 1727 496 898 -1472 729 -2164 1315 -234 574 370 429 -768 259 -1257 -2574 3064 -1898 -794 -734 2336 -1789 1382 -1384 2998 1476 2100 657 -1072 -742 -3891 -1282 172 2441 1006 419 -408 -1499 -597 -441 902 1222 -2272 -489 -1619 1519 -1165 3727 970 283 910 393 -1845 2171 -1478 -993 558 -288 1824 627 854 -903 554 -2390 -21 -1559 1693 -1880 1186 -1255 1532 -2143 2624 870 571 -122 -1204 -1213 -632 -951 900000 SO 20180317T113426.0Z 6650.482245 412 1 36.01 2 89.40 92.32 93.20 94.41 0.00 1 0.00 1 0 15 1.030e-02 1.017e-02 7.966e-03 7.937e-03 4.246554e+03 4.591908e+02 2.661604e+02 -6.000000e+00 5.162602e+02 274.08 -2.00 20.00 -2.00 505.36 0.00e+00 2.269325e-03 2.088526e-04 1.179124e-04 -6.000000e+00 2.764265e-04 274.08 -2.00 20.00 -2.00 500.59 0.00e+00 2.636831e+00 1.520728e-01 4.716360e-02 -6.000000e+00 1.992130e-01 225.89 -2.00 3.57 -2.00 502.17 0.00e+00 19.723 0.149 489.00 513.00 1 7.5290e+00 1.1572e-02 3.4935e-02 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