File name: Pandora103s1_Downsview_20180320_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T233326.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180320_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180320 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180320T112100.0Z 6653.472917 399 1 36.00 2 90.85 89.30 109.61 57.02 0.00 1 0.00 1 0 22 5.568e-02 5.474e-02 5.059e-02 5.001e-02 3.868942e+02 2.622006e+03 8.915253e+01 -6.000000e+00 2.794894e+03 274.42 -2.00 20.00 -2.00 505.30 0.00e+00 2.364923e-03 1.313781e-03 1.085443e-04 -6.000000e+00 1.494797e-03 274.42 -2.00 20.00 -2.00 500.21 0.00e+00 4.669187e+00 9.731445e-01 2.571018e-02 -6.000000e+00 1.076060e+00 226.12 -2.00 3.57 -2.00 501.85 0.00e+00 20.839 0.176 489.00 513.00 1 9.1324e+00 7.4138e-02 3.8314e-02 -6.0000e+00 8.1922e-02 5.7346e-02 1.9486e-02 2.1378e-03 -6.0000e+00 2.1843e-02 7.9364e-06 8.7149e-04 3.7758e-03 3.0075e-05 -6.0000e+00 4.3425e-03 2.8605e-03 1.8189e-04 12 8 8 10 0 0 65.81 15.00 5.60 0.00286 0.00891 9 1 1 4 0 4000.000 21.98 15.00 19.01 -3010 -4431 2391 -2326 -2775 -5393 11419 2229 -1986 -265 3343 -10359 -1955 -5852 1982 3415 -308 -3009 -2765 -1551 9736 330 1843 6984 4550 10726 -3451 2223 1210 6760 -9665 1153 -1559 4436 -1016 -5076 -2318 5162 1315 -4764 4548 -2384 9086 7317 2856 2053 -1743 -3223 -925 -2670 3914 -9829 1288 -6105 -125 -8680 5845 -5498 7323 -6537 1887 11603 7119 -510 -1071 4564 -9784 432 3888 -1790 2513 6544 -1450 4894 -2102 2169 -8742 6644 374 3241 7120 -6050 1444 5497 1882 4360 -4667 7973 -6463 571 -4229 10636 7171 -5838 -799 1269 2517 -6069 11350 -5030 -2610 -5006 -2922 -3943 1672 2516 -919 -1601 295 -6735 -3964 -158 372 1324 1164 11939 3387 4471 -5171 9573 -6371 5054 -4247 7758 -4310 9236 -4100 6458 -3582 -4461 5473 -313 6724 -4693 -402 -13714 2812 -690 17198 -2568 1839 -8804 6928 -4263 6743 6463 -2247 -1488 2854 -9470 900000 -2828 -4289 2247 -2391 -2943 -5978 11001 2379 -2209 -285 3414 -11961 -2049 -6266 1950 3320 -314 -3238 -3072 -1728 9694 360 1982 7171 4828 10752 -3956 2399 1289 6515 -10633 1145 -1618 4538 -1142 -5974 -2617 5338 1393 -5292 4615 -2609 9003 7474 3085 2243 -1965 -3631 -1003 -2871 3808 -10604 1225 -6261 -125 -9789 5865 -6208 7269 -7362 1952 10997 7078 -544 -1139 4513 -10885 428 3688 -1762 2334 5852 -1415 4559 -2125 2086 -9096 5808 344 2882 6111 -5960 1326 4867 1747 3979 -4645 6984 -6492 536 -4175 9222 6578 -6127 -790 1208 2324 -5930 9093 -4601 -2305 -4578 -2704 -3858 1587 2350 -870 -1493 267 -6583 -3856 -151 361 1288 1140 10581 3287 4306 -5413 8524 -6521 4559 -4180 6893 -4349 8164 -4136 5865 -3581 -4533 5032 -298 5865 -4515 -368 -14582 2628 -682 14466 -2648 1825 -9704 6601 -4569 6524 6240 -2310 -1468 2631 -9829 900000 SO 20180320T112501.0Z 6653.475706 403 1 36.01 2 90.12 89.99 109.01 57.81 0.00 1 0.00 1 0 22 1.893e-02 1.891e-02 1.697e-02 1.690e-02 9.861859e+02 8.867745e+02 1.007613e+02 -6.000000e+00 9.498531e+02 274.42 -2.00 20.00 -2.00 505.37 0.00e+00 2.887840e-03 4.448545e-04 1.321343e-04 -6.000000e+00 5.081751e-04 274.42 -2.00 20.00 -2.00 500.62 0.00e+00 3.033042e+00 3.214369e-01 2.290482e-02 -6.000000e+00 3.659271e-01 226.12 -2.00 3.57 -2.00 502.20 0.00e+00 20.796 0.175 489.00 513.00 1 8.1366e+00 2.4487e-02 3.8233e-02 -6.0000e+00 2.7856e-02 4.2982e-02 6.4089e-03 2.1019e-03 -6.0000e+00 7.4324e-03 2.4294e-05 5.5649e-03 1.2921e-03 3.5981e-05 -6.0000e+00 1.4763e-03 3.3047e-02 -3.7939e-05 12 8 8 10 0 0 -2.70 15.00 1.40 0.03305 0.07165 9 1 1 4 0 4000.000 21.98 15.00 19.02 -2268 -3574 -2705 -1287 -1070 2499 -2816 680 882 1115 -446 -659 -2338 -2218 2587 1012 -812 333 -846 -1347 630 1750 -872 2938 1482 2071 -679 2140 685 -3628 -356 -2461 1029 1033 1369 596 -3486 -970 915 1224 1729 1355 1762 -2162 3608 451 163 2092 934 425 1785 -2792 -1074 -719 -4358 563 -581 1834 -953 -305 -1820 -648 3633 3539 3287 2073 -97 -19 -1734 -2253 -1108 97 536 1760 2071 -4171 965 -1894 -269 -267 1426 -7 623 539 712 -2360 956 -2866 -18 1890 -122 1689 1005 4284 -1971 4489 -1342 727 -3743 1121 -535 -3236 37 2365 821 1697 -761 495 -1786 1804 -2994 -3682 -486 191 361 2727 -1046 3107 919 162 0 997 1759 -2056 3764 -1199 -1755 -1584 1397 924 4 -1409 -1621 -1818 -2505 295 -278 1359 1420 860 445 2575 -2548 -248 1169 575 -590 -2271 -2659 -514 900000 -2005 -3272 -2558 -1251 -1062 2444 -2963 698 902 1117 -446 -654 -2319 -2166 2399 956 -793 332 -880 -1420 649 1789 -914 2986 1543 2145 -720 2193 692 -3650 -341 -2422 1004 1057 1444 633 -3795 -1017 930 1231 1737 1381 1813 -2346 3748 484 174 2163 961 428 1712 -2727 -1019 -689 -4484 574 -612 1895 -1007 -318 -1929 -685 3700 3598 3315 2076 -97 -19 -1728 -2216 -1065 93 516 1705 2023 -4270 915 -1810 -251 -249 1314 -7 586 511 682 -2342 917 -2841 -17 1789 -119 1647 1008 4177 -2013 4237 -1314 679 -3551 990 -478 -3018 35 2270 814 1648 -743 468 -1712 1697 -3017 -3812 -497 196 372 2760 -1107 3162 943 164 0 975 1709 -2106 3668 -1226 -1809 -1623 1392 932 4 -1408 -1596 -1772 -2454 288 -281 1378 1456 896 466 2651 -2780 -267 1243 609 -617 -2332 -2687 -511 900000 SO 20180320T112841.1Z 6653.478254 407 1 16.26 2 89.46 90.63 108.46 58.52 0.00 1 0.00 1 0 22 1.159e-02 1.135e-02 6.962e-04 6.919e-04 3.562929e+03 3.740416e+01 2.541123e+02 -6.000000e+00 5.814228e+02 274.42 -2.00 20.00 -2.00 505.42 0.00e+00 4.730960e-03 1.834964e-05 2.447247e-04 -6.000000e+00 3.111433e-04 274.42 -2.00 20.00 -2.00 501.18 0.00e+00 1.811775e+00 1.285712e-02 5.007670e-02 -6.000000e+00 2.240741e-01 226.12 -2.00 3.57 -2.00 502.65 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