File name: Pandora103s1_Downsview_20180322_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T233431.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180322_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180322 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180322T111723.0Z 6655.470405 396 1 36.01 2 90.85 88.20 115.95 29.30 0.00 1 0.00 1 0 22 5.403e-02 5.285e-02 4.869e-02 4.820e-02 1.298578e+03 2.614453e+03 8.001613e+01 -6.000000e+00 2.715196e+03 274.65 -2.00 20.00 -2.00 505.33 0.00e+00 1.980692e-03 1.272942e-03 8.504720e-05 -6.000000e+00 1.451334e-03 274.65 -2.00 20.00 -2.00 500.36 0.00e+00 4.306640e+00 9.335216e-01 4.895805e-02 -6.000000e+00 1.043741e+00 226.28 -2.00 3.57 -2.00 501.98 0.00e+00 20.834 0.176 489.00 513.00 1 9.1231e+00 7.1286e-02 3.8403e-02 -6.0000e+00 7.9477e-02 4.6599e-02 1.8625e-02 2.2227e-03 -6.0000e+00 2.1173e-02 8.2593e-06 -4.5612e-03 3.6621e-03 2.5105e-05 -6.0000e+00 4.2143e-03 -1.6862e-02 3.4724e-04 12 8 8 10 0 0 2.88 15.00 6.18 -0.01686 -0.04850 9 1 1 4 0 4000.000 22.09 15.00 19.06 -5627 -4421 -3407 -6587 -1036 -5705 3447 -45 7093 -1683 2300 -4583 7848 -6265 -1600 8426 6414 -371 1621 2499 2979 -2130 -171 -805 -5241 1021 2621 11560 -631 3329 -9078 2822 -8870 541 -1738 -4340 8277 1851 -1002 3328 5076 1510 1171 8255 2739 -1498 -2310 -4621 -378 -2871 2738 -8675 -124 -3901 14348 -4855 153 2935 4509 1840 -4475 8104 5804 4762 1068 7640 360 -1275 -6328 -7407 -2998 5024 -6177 5162 4965 10749 -10569 -1058 -5496 6937 -4673 8854 -8343 -4430 9460 5831 -6570 923 7808 4213 -748 -1983 9126 -4153 7476 -5562 -4939 -6115 7821 -3786 5141 4070 -3654 2286 -3496 1988 -1284 8466 -293 2006 -10237 -2991 -7204 10702 2774 2808 -5666 4023 4601 565 -6741 6260 1552 -1929 8939 2827 -1981 1999 841 -1093 7214 841 4442 -3780 -198 -10988 7450 -5809 6556 -134 3835 -4988 4939 -5958 7655 -6555 532 -154 -244 -5732 900000 -5320 -4169 -3284 -6848 -1054 -6190 3502 -48 7102 -1818 2344 -4934 7391 -6656 -1607 7668 6007 -380 1687 2638 3128 -2351 -186 -879 -6025 1111 2798 11276 -683 3321 -9853 2720 -9712 561 -1929 -5027 8384 1965 -1080 3393 5072 1571 1238 8246 2927 -1679 -2602 -5257 -407 -3094 2701 -9249 -119 -3874 12222 -5191 161 3033 4584 1904 -4900 7893 5816 4819 1113 7350 364 -1287 -6640 -7736 -2944 4552 -6294 4775 4682 9572 -11310 -1004 -5376 5974 -4504 7554 -8464 -4334 8174 5275 -6712 873 6880 3842 -718 -1949 8234 -4320 6884 -5709 -4945 -6036 6551 -3456 4231 3408 -3393 2099 -3520 1900 -1246 7314 -271 1820 -10682 -2970 -7587 9593 2704 2748 -6067 3947 4464 561 -7058 5682 1462 -1900 8026 2696 -1984 1925 816 -1087 6632 807 4032 -3670 -184 -11482 6715 -6107 6197 -137 3797 -5392 4877 -6602 7475 -7339 546 -154 -237 -5844 900000 SO 20180322T112124.0Z 6655.473195 400 1 36.01 2 90.12 88.90 115.60 30.25 0.00 1 0.00 1 0 15 1.589e-02 1.576e-02 1.424e-02 1.418e-02 3.882095e+03 8.120396e+02 2.785805e+02 -6.000000e+00 7.978217e+02 274.65 -2.00 20.00 -2.00 505.41 0.00e+00 3.323258e-03 3.747473e-04 1.662623e-04 -6.000000e+00 4.268081e-04 274.65 -2.00 20.00 -2.00 500.77 0.00e+00 3.058910e+00 2.696951e-01 4.317112e-02 -6.000000e+00 3.073236e-01 226.28 -2.00 3.57 -2.00 502.32 0.00e+00 20.790 0.175 489.00 513.00 1 7.9391e+00 2.0527e-02 3.8422e-02 -6.0000e+00 2.3392e-02 1.8631e-02 5.3374e-03 2.2456e-03 -6.0000e+00 6.2479e-03 2.9211e-05 2.7355e-03 1.0792e-03 5.5911e-05 -6.0000e+00 1.2395e-03 1.1379e-01 -5.7909e-04 12 8 8 10 0 0 -1.86 14.99 3.87 0.11379 0.13277 9 1 1 4 0 4000.000 22.09 14.99 19.07 -2564 -1511 -878 709 1304 459 -180 -1120 1349 -828 2335 -896 3020 -2127 -1818 1184 -1583 -246 1049 1236 468 870 -1584 223 -2443 3929 -421 4404 53 -1028 -1099 1730 -54 -1179 1781 -2082 -952 1173 -1468 -1082 1254 1862 99 2178 -475 -294 2336 -1535 1482 -462 -2870 -1488 -1754 -4962 951 -1088 734 3007 593 -1343 489 1949 232 1103 123 1017 790 1651 1957 -2021 709 810 702 20 -1915 -416 -877 1688 -1174 -594 -3284 -1169 -2079 3020 -2150 -1777 -1985 -2092 139 -171 132 -622 1996 -805 1487 -15 1772 -135 813 -2529 -2310 -1672 -1484 -1198 1731 1890 -1221 656 -921 -206 813 1133 349 1623 -1155 1867 2218 927 -936 2193 -205 -423 2230 3116 -231 867 771 1268 -1235 755 279 -1945 -1132 -670 -939 -1770 -573 -1059 77 1280 772 -2234 1616 -513 1473 59 1586 -1435 -1934 -8 900000 -2215 -1318 -792 657 1233 447 -180 -1144 1345 -830 2230 -873 2793 -2037 -1724 1095 -1524 -241 1047 1247 474 880 -1641 228 -2595 3936 -439 4360 53 -1000 -1046 1611 -52 -1208 1842 -2245 -1002 1193 -1513 -1101 1253 1869 102 2245 -508 -315 2435 -1639 1513 -470 -2887 -1436 -1673 -4924 922 -1119 761 3071 618 -1416 507 2010 244 1152 128 1035 790 1616 1893 -1998 673 771 677 19 -1953 -414 -854 1570 -1113 -558 -3174 -1118 -2014 2799 -2123 -1763 -1970 -2068 134 -166 128 -618 1979 -824 1466 -15 1666 -126 732 -2295 -2072 -1512 -1389 -1176 1701 1849 -1211 627 -883 -199 795 1126 355 1649 -1211 1911 2289 977 -996 2226 -210 -425 2176 3060 -237 880 786 1285 -1279 773 286 -1991 -1130 -659 -924 -1791 -591 -1118 81 1357 827 -2470 1734 -567 1600 64 1677 -1513 -2002 -9 900000 SO 20180322T112519.0Z 6655.475914 404 1 36.01 2 89.41 89.58 115.25 31.16 0.00 1 0.00 1 0 22 9.072e-03 8.852e-03 2.297e-03 2.283e-03 5.219021e+03 1.292334e+02 3.685592e+02 -6.000000e+00 4.556066e+02 274.65 -2.00 20.00 -2.00 505.41 0.00e+00 3.570612e-03 6.053962e-05 1.835142e-04 -6.000000e+00 2.437137e-04 274.65 -2.00 20.00 -2.00 501.12 0.00e+00 2.172715e+00 4.250758e-02 5.258866e-02 -6.000000e+00 1.754114e-01 226.28 -2.00 3.57 -2.00 502.60 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