File name: Pandora103s1_Downsview_20180413_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T233352.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v3d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180413_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180413 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180413T104431.0Z 6677.447581 364 1 40.00 2 89.75 77.58 81.10 108.93 0.00 1 0.00 1 0 26 3.200e-01 2.018e-01 2.866e-01 2.449e-01 2.793576e+04 1.947019e+04 1.813168e+03 -6.000000e+00 1.623032e+04 277.14 -2.00 20.00 -2.00 505.15 0.00e+00 -4.880152e-03 6.634955e-03 3.449666e-04 -6.000000e+00 8.638269e-03 277.14 -2.00 20.00 -2.00 499.50 0.00e+00 -3.414916e+00 4.960331e+00 1.224956e-01 -6.000000e+00 6.171082e+00 227.99 -2.00 3.57 -2.00 501.19 0.00e+00 20.266 0.162 489.00 513.00 1 1.1468e+01 3.8034e-01 3.8803e-02 -6.0000e+00 4.7031e-01 2.6156e-01 9.9517e-02 3.7712e-03 -6.0000e+00 1.2510e-01 1.4969e-06 1.7043e-02 1.5525e-02 2.0476e-04 -6.0000e+00 2.4930e-02 9.1414e-02 -9.2105e-04 12 8 8 10 0 0 82.19 15.00 16.97 0.09141 0.20963 10 1 1 4 0 4000.000 22.09 15.00 19.18 900000 31268 -8878 -4685 15759 2397 -8501 -3985 7014 38914 10238 -9386 -19602 19700 -9993 4388 48254 17132 49441 54345 10732 143 -17496 -1630 4017 12051 -7003 657 -10586 -14211 -14229 8549 -11154 7959 10147 -22983 11914 -197 2458 39402 -14545 31263 -21995 6854 7631 -2287 -14095 35600 -13646 38702 -7186 25619 -26791 -119 -5351 4594 -22152 89398 -9393 35237 29590 706 6624 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-19411 -19639 -7634 6236 9874 -16415 -2061 -40476 21833 16476 -5798 19317 14996 1598 -26377 60178 16048 -17294 4334 28521 -30059 10740 6599 -290 23329 -4029 -11466 11491 32976 19316 15078 -30065 4832 18720 -3830 11061 4743 18999 24671 5481 -43181 11456 25881 -23640 11186 -24025 15324 -13128 2596 6907 -5317 6600 14388 -5917 -27707 2536 14198 7507 24279 6043 -4897 29584 27363 -2912 -31978 -16035 5918 -9308 19685 -2064 12418 29006 14343 SO 20180413T104902.0Z 6677.450718 368 1 40.00 2 88.95 78.35 80.34 109.73 0.00 1 0.00 1 0 22 2.176e-01 1.779e-01 1.674e-01 1.512e-01 7.026955e+03 9.168488e+03 2.004834e+02 -6.000000e+00 1.104163e+04 277.14 -2.00 20.00 -2.00 505.01 0.00e+00 1.555014e-03 3.919948e-03 2.834440e-04 -6.000000e+00 5.872339e-03 277.14 -2.00 20.00 -2.00 499.71 0.00e+00 -3.361664e+00 3.007159e+00 1.035157e-01 -6.000000e+00 4.183447e+00 227.99 -2.00 3.57 -2.00 501.34 0.00e+00 18.647 0.126 489.00 513.00 1 1.1135e+01 2.2842e-01 3.3093e-02 -6.0000e+00 3.1904e-01 2.6987e-01 6.2309e-02 2.4211e-03 -6.0000e+00 8.4493e-02 2.5039e-06 8.2002e-03 1.1128e-02 6.2864e-05 -6.0000e+00 1.6909e-02 -2.0735e-03 -1.1613e-04 12 8 8 10 0 0 7.10 15.00 12.48 -0.00207 0.05481 10 1 1 4 0 4000.000 22.19 15.00 19.20 900000 12942 35239 8989 -8071 7811 -6504 28951 11920 7625 23649 3737 -16302 16031 -20757 11083 -18474 2927 -15909 2036 696 15740 -9002 19204 19305 8760 8463 -626 27345 -21875 3602 -6991 1461 -8878 -4774 -5902 29062 -10837 2209 -19100 23478 23285 18660 -15942 17726 10367 12766 -2047 21806 -6231 6410 -13749 -18831 19255 -2777 7503 -20419 16011 12972 -6060 -19666 9390 -4613 32528 42888 19002 12037 22114 -14481 -4565 -33647 16845 -18385 6361 -20511 7797 40551 -13585 15844 1703 65280 -12636 7130 -13973 22757 -14765 -3603 24097 17783 29111 -12753 23235 -17630 28892 -17081 32401 2880 -7159 -28500 4412 -5982 48711 5562 7798 -9712 50143 -23782 2745 7898 7385 -15169 12610 36218 -15754 13914 3267 3762 6547 43303 -10158 -6866 20613 -1179 -3143 1896 44822 53089 7549 25575 -23594 34819 -8877 7851 17408 8525 2548 14626 20407 -20664 25656 -13821 46002 -33260 24571 -10624 15448 6114 90754 -1746 40828 -2153 900000 12084 27464 9374 -10141 8555 -8337 26636 12874 8434 21939 4141 -21514 15196 -27734 10878 -24325 3213 -21601 2351 809 15808 -11433 18592 18788 9431 9072 -727 23646 -28976 3627 -7806 1529 -10703 -5747 -7212 24977 -13452 2382 -24989 20368 20363 17247 -20814 16924 10651 12736 -2321 19334 -7057 6205 -15676 -22165 15802 -2906 7393 -26991 15018 12487 -6951 -25675 9342 -5279 26027 30828 16871 11199 18420 -16995 -4793 -46094 14243 -22059 6120 -25943 7454 27604 -15192 13228 1620 33901 -13969 6553 -15828 18393 -17281 -3785 19297 15035 22062 -14508 18993 -21781 22856 -20552 23550 2697 -7166 -34158 3763 -5581 27342 4898 7096 -10821 31497 -29880 2612 7037 6656 -17294 11154 25750 -18495 12259 3188 3688 6298 29057 -11137 -7114 15997 -1112 -3045 1761 27494 30040 6551 18514 -27434 22910 -8623 6350 12690 6712 2156 11311 15125 -22876 18389 -14497 27196 -42118 17870 -10794 12102 5112 32785 -1480 22895 -1841 SO 20180413T105324.0Z 6677.453750 372 1 40.00 2 88.18 79.11 79.61 110.50 0.00 1 0.00 1 0 58 9.258e-02 8.855e-02 8.695e-02 8.428e-02 4.583468e+03 5.243824e+03 6.969290e+01 -6.000000e+00 4.696100e+03 277.14 -2.00 20.00 -2.00 505.23 0.00e+00 6.197088e-03 2.235088e-03 3.042831e-04 -6.000000e+00 2.501997e-03 277.14 -2.00 20.00 -2.00 499.86 0.00e+00 2.707971e+00 1.696379e+00 9.807332e-02 -6.000000e+00 1.791620e+00 227.99 -2.00 3.57 -2.00 501.51 0.00e+00 16.600 0.089 489.00 513.00 1 1.0327e+01 1.2971e-01 2.8360e-02 -6.0000e+00 1.3647e-01 1.1164e-01 3.3669e-02 2.0874e-03 -6.0000e+00 3.6423e-02 4.6445e-06 1.8179e-03 6.3109e-03 8.6060e-05 -6.0000e+00 7.2220e-03 4.6381e-02 -1.5183e-04 12 8 8 10 0 0 -5.07 14.99 3.63 0.04638 0.05899 10 1 1 4 0 4000.000 22.19 14.99 19.21 9261 2173 -8183 -21584 2578 -1617 3056 -4387 2738 -11794 17423 3538 -4045 -378 6524 16106 351 -11828 -7522 -5996 -8262 -1465 172 19913 -3010 13193 6141 94 -12145 -1980 7300 15384 4639 12216 9668 -7955 4554 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