File name: Pandora103s1_Downsview_20180428_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T235418.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v3d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180428_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180428 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180428T102048.0Z 6692.431111 255 1 40.00 2 89.74 70.40 95.32 270.06 0.00 1 0.00 1 0 58 2.560e-01 2.058e-01 2.241e-01 1.964e-01 3.453678e+03 1.214359e+04 2.273098e+03 -6.000000e+00 1.308584e+04 278.86 -2.00 20.00 -2.00 505.16 0.00e+00 -1.191618e-03 5.199380e-03 3.221327e-05 -6.000000e+00 6.950937e-03 278.86 -2.00 20.00 -2.00 499.46 0.00e+00 1.448986e+00 4.040787e+00 5.025780e-02 -6.000000e+00 4.959849e+00 229.32 -2.00 3.57 -2.00 501.14 0.00e+00 20.196 0.160 489.00 513.00 1 1.0869e+01 3.0909e-01 3.6205e-02 -6.0000e+00 3.7799e-01 1.9228e-01 8.3223e-02 2.3103e-03 -6.0000e+00 1.0082e-01 1.9042e-06 -2.7790e-02 1.4058e-02 1.9047e-04 -6.0000e+00 1.9962e-02 -1.0158e-01 7.4111e-04 12 8 8 10 0 0 78.72 15.00 11.97 -0.10158 -0.29435 10 1 1 4 0 4000.000 22.29 15.00 19.36 10305 -5573 -18287 4356 3528 32629 14319 18415 1788 7579 6653 -4310 -1794 9501 -5138 38535 21847 9199 -11053 -8977 -7605 -20021 -1068 -17457 -3141 18429 -17617 -13714 6766 -1702 -2305 3031 34191 19364 22263 -9763 20044 14556 39776 15164 -10601 -10219 59309 -1066 4665 6699 20242 11215 1788 20554 -4739 -18252 -7556 -24027 -16875 40917 29858 9974 876 29137 -4968 10117 -5663 4041 13168 16489 -23643 41250 8391 4498 -49872 -12417 1914 38916 9274 -19845 25272 4324 54514 49474 -5950 -36744 44347 -1872 -4406 26846 4868 -25983 29019 7881 59208 11522 -19141 16870 24489 25465 24308 43702 4919 3173 27485 54634 -17376 -31028 -30100 12379 -22834 19077 12452 17958 -5416 15364 -20142 -1011 88309 36356 -6274 43605 5117 29147 -13350 29918 7250 -14895 38063 -1755 -3064 -6581 3207 -5212 -1189 793 -1445 -9571 92612 14122 5327 -4025 61238 4115 5285 58533 39954 40781 12529 14922 -45470 18045 -5649 37100 900000 10278 -6194 -22731 4437 3749 27289 14575 18346 2131 8629 7629 -5404 -2157 10131 -6196 30139 19848 9450 -13972 -11457 -9887 -29643 -1313 -25082 -3920 18743 -25451 -19024 7663 -2073 -2742 3273 26852 17573 20024 -12471 19932 15238 32209 15289 -13464 -12755 38129 -1222 5104 7261 19445 11738 2027 19160 -5522 -23544 -8477 -30644 -19717 27780 23271 9730 953 24263 -5684 9927 -6446 4215 12624 15279 -31798 29273 7973 4377 -80833 -13797 1831 26278 8386 -24132 20225 4168 31746 29546 -5954 -49155 27520 -1820 -4404 20079 4555 -32888 21719 7180 33071 10115 -22607 14336 19675 20204 19077 27865 4417 2814 18847 28363 -17783 -36907 -36991 10669 -28236 15700 10708 14312 -5317 12483 -23345 -988 37422 25223 -6525 28291 4823 21934 -14875 21631 6367 -15838 24331 -1656 -2938 -6501 2881 -5037 -1101 725 -1333 -9301 33698 10635 4349 -3671 30984 3628 4658 31482 25663 26043 10524 12302 -66790 14308 -5472 23163 900000 SO 20180428T102543.0Z 6692.434525 259 1 40.00 2 88.90 71.24 96.19 270.87 0.00 1 0.00 1 0 57 1.542e-01 1.370e-01 1.373e-01 1.296e-01 1.305628e+04 9.112661e+03 1.124228e+03 -6.000000e+00 7.880123e+03 278.86 -2.00 20.00 -2.00 505.20 0.00e+00 7.312537e-03 3.416382e-03 2.207074e-04 -6.000000e+00 4.177716e-03 278.86 -2.00 20.00 -2.00 499.73 0.00e+00 1.275466e+00 2.567407e+00 8.120703e-02 -6.000000e+00 2.954348e+00 229.32 -2.00 3.57 -2.00 501.37 0.00e+00 18.480 0.123 489.00 513.00 1 1.0566e+01 1.9480e-01 3.2389e-02 -6.0000e+00 2.2564e-01 1.6231e-01 5.0214e-02 2.6913e-03 -6.0000e+00 5.9325e-02 2.9822e-06 2.8767e-02 9.3248e-03 1.1945e-04 -6.0000e+00 1.1956e-02 3.8024e-02 -2.3414e-04 12 8 8 10 0 0 6.68 14.99 8.69 0.03802 0.23757 10 1 1 4 0 4000.000 22.29 14.99 19.36 -3706 -3063 25314 -7128 20136 -15103 7640 -4495 1157 -9414 -4506 11309 -11261 14865 12344 11846 -11173 -6100 17794 -57 -12662 -3591 -7249 25290 3126 15237 19189 15894 30148 -10271 -14811 16423 15948 24137 -8524 -1477 -1474 -152 5628 8062 -5177 -4906 3739 -6401 43893 -19330 42792 -19472 -12477 -8534 1055 -24258 537 -20419 39755 5021 -1031 -4338 12988 14635 -14591 9293 3772 17513 13717 1975 10808 16630 -240 -4800 -1224 10571 3812 10361 -16275 9719 14882 7490 18285 -9878 14370 -137 -6012 -4340 6724 -4210 -11758 6849 -2775 -10125 -6580 3393 7280 9828 -5296 -15232 -1877 24240 -2749 32947 -9980 22150 -5396 25893 -15550 -9961 6638 21120 -11273 20584 -15388 -13563 -16450 23334 21937 10821 -6913 51125 12466 -8947 4270 3179 3480 3368 15083 6591 36350 -404 8631 -17696 -15534 -2972 10562 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10493 SO 20180428T103036.0Z 6692.437917 263 1 40.00 2 88.06 72.08 97.05 271.68 0.00 1 0.00 1 0 22 9.191e-02 8.632e-02 8.707e-02 8.466e-02 1.406275e+04 6.057954e+03 1.072453e+03 -6.000000e+00 4.695792e+03 278.86 -2.00 20.00 -2.00 505.30 0.00e+00 9.649025e-04 2.253133e-03 4.573984e-05 -6.000000e+00 2.494735e-03 278.86 -2.00 20.00 -2.00 499.91 0.00e+00 6.603777e-01 1.697287e+00 5.467733e-02 -6.000000e+00 1.780317e+00 229.32 -2.00 3.57 -2.00 501.58 0.00e+00 16.261 0.084 489.00 513.00 1 1.0578e+01 1.2925e-01 2.6165e-02 -6.0000e+00 1.3567e-01 1.1787e-01 3.3581e-02 2.2447e-03 -6.0000e+00 3.6205e-02 4.6721e-06 5.0273e-03 5.9140e-03 9.5847e-05 -6.0000e+00 7.1691e-03 1.0323e-02 5.7764e-05 12 8 8 10 0 0 -5.13 14.99 8.79 0.01032 0.04519 10 1 1 4 0 4000.000 22.29 14.99 19.36 -2517 -3104 -13241 3500 2892 7100 -2712 478 -5891 -10016 3103 3515 -1237 2911 897 -2413 -13420 -944 6195 646 -3842 -2084 8781 3500 14761 5271 6870 -3905 -8519 -7362 -1533 -12894 9096 -7602 353 21595 7847 -5785 1975 1554 1802 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