File name: Pandora103s1_Downsview_20180502_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T235505.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v3d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180502_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180502 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180502T101507.0Z 6696.427164 249 1 40.00 2 89.74 68.65 75.19 225.15 0.00 1 0.00 1 0 15 5.242e-02 5.102e-02 4.423e-02 4.378e-02 8.672884e+03 2.851317e+03 5.814696e+02 -6.000000e+00 2.683294e+03 279.32 -2.00 20.00 -2.00 505.41 0.00e+00 3.408452e-03 1.171495e-03 1.655758e-04 -6.000000e+00 1.421219e-03 279.32 -2.00 20.00 -2.00 500.45 0.00e+00 4.183341e+00 8.489710e-01 6.840570e-02 -6.000000e+00 1.003554e+00 229.68 -2.00 3.57 -2.00 502.06 0.00e+00 20.182 0.160 489.00 513.00 1 9.0661e+00 6.4930e-02 3.6796e-02 -6.0000e+00 7.6665e-02 2.5673e-02 1.6447e-02 2.5235e-03 -6.0000e+00 2.0138e-02 9.2698e-06 9.1377e-05 3.2229e-03 6.4252e-05 -6.0000e+00 4.0615e-03 4.2868e-02 -2.0930e-04 12 8 8 10 0 0 -5.40 14.99 3.38 0.04287 0.04350 10 1 1 4 0 4000.000 22.40 14.99 19.57 -8276 -5442 -4940 5273 -1592 -7129 -644 5693 5055 -1787 245 -3263 -1732 2473 -1435 -8963 3581 -6168 7040 -5911 11192 -2268 1730 2388 -4774 -1317 11694 -1110 -3292 -8663 -3049 1841 240 -5154 -1086 16717 6381 5508 -6524 19657 -5400 10352 -3091 2819 1140 984 4004 2923 -9636 1440 608 959 -3438 4785 2579 1049 1078 -1887 8290 -1478 2145 -4215 2406 305 7728 -3522 -539 -3912 4508 -1012 3920 781 -4084 8570 -4342 -971 -2953 7268 -991 -3605 -1145 692 1070 2065 2406 1209 -932 1374 3903 7254 774 364 -4452 3926 262 -949 2475 658 -4702 -5848 -632 -1716 4054 6968 3948 1556 7506 -3323 943 -6257 -3763 1567 1117 -3333 -764 318 -539 -2350 1177 731 3127 -3056 -12383 14880 -4859 3647 -5059 3784 -3981 13128 8590 5988 -2849 -1800 -8213 -1176 4176 -4320 3349 1727 1830 -427 -1759 -3668 -1147 4940 5789 3912 -4732 -7946 -6720 -7931 -5139 -4804 4856 -1616 -7790 -677 5707 5114 -1910 252 -3427 -1768 2383 -1423 -9564 3416 -6631 6887 -6693 10711 -2476 1817 2499 -5414 -1453 11330 -1215 -3616 -9599 -3093 1778 239 -5635 -1194 15670 6535 5604 -7372 17013 -5964 9884 -3412 2979 1242 1081 4261 3104 -11385 1495 615 937 -3437 4414 2497 1074 1135 -2070 8223 -1600 2232 -4699 2530 327 7662 -3832 -558 -4111 4319 -1008 3653 749 -4143 7795 -4552 -982 -2969 6438 -939 -3476 -1075 643 995 1908 2244 1153 -906 1298 3564 6383 727 348 -4558 3732 253 -900 2201 577 -4239 -5205 -526 -1457 3369 5950 3631 1479 6663 -3217 862 -6170 -3704 1493 1083 -3399 -762 315 -545 -2458 1192 732 2998 -3044 -13326 12398 -4981 3453 -5233 3595 -4063 11411 7815 5466 -2779 -1726 -8353 -1133 3945 -4527 3297 1755 1877 -450 -1891 -4043 -1237 5007 5727 3832 -4913 -8468 -7180 SO 20180502T101949.0Z 6696.430428 253 1 40.00 2 88.95 69.46 75.78 226.09 0.00 1 0.00 1 0 36 1.613e-02 1.566e-02 9.043e-03 8.977e-03 1.272508e+04 5.874251e+02 8.928139e+02 -6.000000e+00 8.256272e+02 279.32 -2.00 20.00 -2.00 505.50 0.00e+00 4.933659e-03 2.409701e-04 2.419844e-04 -6.000000e+00 4.383062e-04 279.32 -2.00 20.00 -2.00 501.07 0.00e+00 1.927165e+00 1.693223e-01 9.058782e-02 -6.000000e+00 3.125400e-01 229.68 -2.00 3.57 -2.00 502.57 0.00e+00 18.584 0.125 489.00 513.00 1 7.7941e+00 1.2893e-02 3.2892e-02 -6.0000e+00 2.3819e-02 -2.6780e-02 3.2993e-03 2.7798e-03 -6.0000e+00 6.3574e-03 4.7774e-05 3.7162e-03 6.5483e-04 1.2193e-04 -6.0000e+00 1.2581e-03 1.2331e-02 3.2161e-05 12 8 8 10 0 0 28.56 14.99 4.20 0.01233 0.03811 10 1 1 4 0 4000.000 22.40 14.99 19.57 -4582 -3496 -2049 -1368 407 -313 1427 647 1829 -1576 -708 -1387 129 -1876 -3503 -1026 -1428 -805 1742 955 508 80 2933 2240 2465 1602 1011 739 -2321 -1152 -2643 -2493 -710 537 864 157 1721 217 -49 75 -96 808 145 1939 2874 2226 2238 1461 -146 129 612 -2244 -1447 -2682 -2545 -1398 331 1498 807 -36 2183 2421 3118 1330 1545 833 159 1469 -450 -2034 -2295 452 -1439 772 -741 449 -1829 -2101 -1806 -2121 -1322 -1582 -487 -396 -526 -768 743 -1095 918 -173 1876 3227 1445 2847 2049 1958 494 -1771 1021 -3666 -2123 -3528 -1557 103 1208 423 1109 -2154 -985 -1045 -286 -477 -90 1748 1903 2401 2096 1985 62 -338 -655 674 -916 1419 2135 -99 453 1733 -1538 647 -181 -5 -805 -2667 -2223 -282 -167 279 -703 -734 417 398 164 -1 1067 -611 385 -1037 -1929 -1343 900000 -3847 -2960 -1779 -1234 371 -293 1343 621 1736 -1522 -666 -1299 117 -1714 -3230 -926 -1311 -755 1649 923 491 78 2782 2153 2393 1577 999 730 -2305 -1082 -2460 -2330 -666 521 870 160 1708 216 -48 73 -94 799 146 1961 2926 2295 2301 1496 -150 129 591 -2167 -1368 -2589 -2540 -1437 343 1552 841 -37 2235 2499 3218 1397 1608 859 161 1459 -451 -2040 -2277 439 -1438 769 -759 451 -1831 -2063 -1754 -2052 -1270 -1538 -471 -385 -520 -768 730 -1087 885 -168 1798 3111 1449 2817 1989 1837 454 -1617 889 -3269 -1848 -3166 -1433 99 1199 426 1099 -2165 -970 -1044 -290 -495 -93 1801 1961 2478 2211 2134 68 -365 -695 690 -942 1448 2192 -105 478 1803 -1647 684 -192 -5 -825 -2772 -2304 -294 -178 302 -776 -825 468 449 187 -1 1210 -699 428 -1139 -2098 -1455 900000 SO 20180502T102422.0Z 6696.433588 257 1 40.00 2 88.17 70.24 76.37 226.99 0.00 1 0.00 1 0 22 9.805e-03 9.510e-03 2.736e-03 2.711e-03 1.472505e+04 1.836785e+02 9.835192e+02 -6.000000e+00 5.019332e+02 279.32 -2.00 20.00 -2.00 505.54 0.00e+00 4.385073e-03 7.278618e-05 2.350547e-04 -6.000000e+00 2.664593e-04 279.32 -2.00 20.00 -2.00 501.00 0.00e+00 1.772967e+00 5.153098e-02 1.087103e-01 -6.000000e+00 1.899877e-01 229.68 -2.00 3.57 -2.00 502.53 0.00e+00 16.557 0.088 489.00 513.00 1 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