File name: Pandora103s1_Downsview_20180510_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T235419.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v3d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180510_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180510 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180510T100448.0Z 6704.420000 304 1 40.00 2 89.75 65.42 68.80 127.18 0.00 1 0.00 1 0 68 8.517e-01 4.617e-01 6.318e-01 4.513e-01 -5.032276e+04 2.324207e+04 2.198524e+03 -6.000000e+00 4.390795e+04 280.24 -2.00 20.00 -2.00 505.00 0.00e+00 2.778903e-02 1.230502e-02 1.142660e-03 -6.000000e+00 2.340242e-02 280.24 -2.00 20.00 -2.00 499.60 0.00e+00 1.329908e+01 1.006906e+01 6.238334e-01 -6.000000e+00 1.674845e+01 230.41 -2.00 3.57 -2.00 501.25 0.00e+00 20.160 0.160 489.00 513.00 1 1.0509e+01 7.6162e-01 6.5993e-02 -6.0000e+00 1.2723e+00 1.1796e-01 1.9971e-01 1.1727e-02 -6.0000e+00 3.3933e-01 7.1005e-07 -1.6107e-02 1.7397e-02 5.9729e-04 -6.0000e+00 6.7121e-02 6.3526e-02 -1.0548e-03 12 8 8 10 0 0 -1.49 15.00 38.45 0.06353 -0.04820 10 1 1 4 0 4000.000 22.19 15.00 19.23 900000 74360 304098 -42647 -2203 -19278 12553 3417 29822 38869 40588 -2462 -13420 -21579 5762 14722 294661 900000 83175 41639 -29636 -47750 -8501 5970 187579 6209 75555 -16278 -5454 50611 38954 177663 34854 15657 137675 -41799 165685 900000 49552 46463 35622 2956 44664 22466 138161 64004 47730 -19541 -33093 116743 -6292 27203 37347 54523 -25172 4059 -3043 -6145 10168 25936 54141 32329 -51493 179618 71532 11392 1519 211187 8199 17533 77188 53569 -2526 -5036 -26408 -31307 20865 15866 40590 -43010 91198 -26758 -3019 900000 79378 98526 157920 57045 45017 37094 23036 16290 81304 361767 -5293 88096 2647 37185 -18374 46637 -9489 30822 25207 213598 -38732 -26569 -21123 44740 -45373 -18102 52110 36319 227281 900000 -6736 -27752 307088 -20794 40063 -11607 -10386 54824 900000 -17525 16837 48099 114557 -4963 63945 -48124 64536 104002 10343 58076 19846 15830 -28133 66583 11204 25134 3646 -31426 34767 28480 -896 212122 -23358 -4185 -34771 59125 21663 900000 43440 134377 -76003 -2788 -30007 14818 4468 30770 36804 37269 -3301 -19290 -32738 6596 15184 130207 900000 44081 33068 -47093 -90286 -10888 6620 82889 6969 44936 -23474 -7117 38544 32128 78507 27407 14739 60837 -71722 73214 900000 36417 34609 29145 3292 34092 21740 61052 44096 39220 -30741 -59159 51587 -8466 26076 31543 38186 -36975 4540 -3747 -8072 11718 25911 41223 30069 -106069 79371 46165 12902 1860 93321 8973 17199 42272 35681 -2782 -5616 -35924 -44666 18198 14313 28154 -64414 40299 -34111 -3080 900000 36557 43537 69783 30299 26393 23279 16636 12715 35927 159860 -5466 40573 2984 33127 -30070 41316 -13373 27690 22670 94386 -58176 -33604 -23247 23703 -52375 -15655 23274 19426 100433 900000 -6657 -36397 135698 -27375 28532 -12513 -10353 28706 900000 -19307 13955 30716 50621 -5240 35402 -77041 36057 45957 9814 34915 16547 12924 -33238 31506 9134 18655 3351 -39593 22723 19154 -793 93734 -26848 -4003 -42572 27835 13781 SO 20180510T100946.0Z 6704.423449 308 1 40.00 2 88.93 66.27 68.09 128.22 0.00 1 0.00 1 0 36 3.730e-01 2.413e-01 3.142e-01 2.518e-01 -1.978433e+04 1.375374e+04 1.056145e+03 -6.000000e+00 1.914867e+04 280.24 -2.00 20.00 -2.00 505.19 0.00e+00 1.412149e-03 6.807016e-03 1.698650e-04 -6.000000e+00 1.014036e-02 280.24 -2.00 20.00 -2.00 499.66 0.00e+00 4.001381e+00 5.172234e+00 2.372381e-01 -6.000000e+00 7.197694e+00 230.41 -2.00 3.57 -2.00 501.39 0.00e+00 18.512 0.124 489.00 513.00 1 1.1152e+01 3.9774e-01 3.6597e-02 -6.0000e+00 5.4905e-01 1.5424e-01 1.0385e-01 4.9262e-03 -6.0000e+00 1.4594e-01 1.4618e-06 -5.9043e-03 1.7840e-02 1.3206e-04 -6.0000e+00 2.9036e-02 1.4390e-01 -1.2150e-03 12 8 8 10 0 0 -1.88 15.00 18.02 0.14390 0.10294 10 1 1 4 0 4000.000 22.19 15.00 19.25 900000 -13090 -12766 8024 -3506 20926 29375 -22089 -32744 39989 -10062 5363 -14391 7764 2669 12321 48981 16275 9389 1639 -14387 17860 -7961 -8140 17545 -9682 32188 -1327 60293 26328 104185 -25194 -494 -13159 -11222 3251 -2257 26009 -2681 -4158 4456 91480 -2158 5419 -3588 81808 -11822 44454 -33775 27960 4948 83192 -1737 63029 -6808 13044 -2317 5235 19188 21737 -1185 21949 31522 10911 29426 -11170 13548 11067 -7721 -10112 31301 -31531 -8343 26755 73545 24843 -7860 64976 -26560 9652 48420 -1681 658 22855 953 -16403 27768 6532 -19954 7619 2449 82602 -21433 74924 -12018 105802 48708 80051 2294 -7523 -11167 42787 -4619 8297 12130 16837 -1282 15775 8191 16158 53017 -10220 25340 -13158 43635 -32501 38561 -39831 71789 6631 66985 8724 -1365 -7148 28348 30086 36678 -43639 64973 6641 -3093 18685 16313 172079 -25429 7283 -28187 108257 9731 31191 -11870 64055 1359 28137 -15716 65696 -27638 13785 -16030 -2623 20173 900000 -15628 -15460 8263 -4189 20244 26696 -33472 -55483 33731 -13445 6069 -19422 8334 2957 12346 34667 15906 10064 1952 -20164 18339 -10436 -10665 18017 -12994 28940 -1632 41012 24048 43528 -35008 -543 -16628 -14514 3799 -2786 24093 -3215 -4978 4855 43625 -2517 5929 -4328 44289 -15593 34002 -53592 24172 5185 40113 -1814 35011 -7340 12020 -2559 5503 17772 19512 -1310 19400 25569 10783 24321 -13440 12635 10344 -8501 -11262 23075 -41591 -8822 20447 36679 19889 -8515 34365 -32769 8370 29070 -1635 635 17862 915 -18715 20921 6025 -23752 7037 2402 38128 -26847 38658 -14510 42754 34503 42942 2528 -8732 -12946 29224 -4954 7957 11394 14957 -1299 13069 7097 12804 29869 -10695 19491 -15154 30196 -47165 28550 -61428 37275 6180 34506 7773 -1342 -7486 21528 22506 25601 -65330 34449 6116 -3150 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