File name: Pandora103s1_Downsview_20180523_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T235510.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v3d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180523_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180523 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180523T095144.0Z 6717.410926 279 1 40.00 2 89.75 61.10 117.47 313.33 0.00 1 0.00 1 0 15 2.250e-02 2.270e-02 2.168e-02 2.155e-02 9.842305e+03 1.424183e+03 6.678880e+02 -6.000000e+00 1.162399e+03 281.65 -2.00 20.00 -2.00 505.39 0.00e+00 2.221009e-03 5.781486e-04 1.070862e-04 -6.000000e+00 6.148543e-04 281.65 -2.00 20.00 -2.00 500.48 0.00e+00 2.540840e+00 4.184907e-01 6.720975e-02 -6.000000e+00 4.363865e-01 231.40 -2.00 3.57 -2.00 502.08 0.00e+00 20.122 0.159 489.00 513.00 1 8.4771e+00 3.1916e-02 3.6477e-02 -6.0000e+00 3.3279e-02 4.5934e-02 8.2506e-03 2.5477e-03 -6.0000e+00 8.8817e-03 1.9391e-05 3.3415e-03 1.5836e-03 7.4956e-05 -6.0000e+00 1.7552e-03 1.9271e-02 -2.7166e-05 12 8 8 10 0 0 1.70 15.00 2.66 0.01927 0.04245 10 1 1 4 0 4000.000 22.09 15.00 19.13 -106 -702 -2543 -1432 2228 -5428 3042 -1574 543 -2287 540 -2552 -2263 -6530 -676 2413 658 1528 689 4457 506 1744 -1391 1743 -5423 690 310 3745 -3175 -1831 326 -1913 -1716 1793 277 2626 -1008 -1507 -37 -791 1031 1405 3190 4754 3908 963 -248 1474 1179 862 -237 -1749 27 1877 -3166 -641 1551 -581 1301 -2162 533 -1064 3367 -69 -1875 2852 540 2549 -2504 87 330 1849 -3080 4908 -953 511 1686 -1840 -273 2589 435 -885 -1754 -1054 1025 850 580 -1878 4424 -2403 2121 -2727 1880 577 3056 5 -423 -537 1763 -1103 351 758 3111 -806 1149 701 1293 1884 271 -2025 1891 -602 -114 -2296 1377 -227 -771 -143 986 -235 -3248 3271 -4012 -891 -3192 1183 2156 -3103 1393 1634 2198 -4830 3880 -2849 377 -4205 -3248 3650 -1202 -3413 2741 1100 2026 550 -757 1711 3110 -983 -1363 -4608 900000 -93 -628 -2408 -1400 2159 -5777 3052 -1673 566 -2414 544 -2624 -2285 -6766 -657 2280 641 1517 713 4514 531 1811 -1489 1817 -6121 737 331 3847 -3408 -1854 315 -1896 -1731 1828 298 2783 -1091 -1617 -39 -823 1056 1446 3268 4866 4087 1040 -270 1556 1229 880 -236 -1717 25 1760 -3222 -662 1609 -620 1361 -2321 557 -1138 3469 -73 -2015 2875 545 2488 -2544 85 316 1751 -3092 4637 -967 507 1611 -1777 -257 2353 404 -841 -1689 -1014 981 823 563 -1853 4073 -2358 2001 -2741 1844 573 2887 5 -387 -478 1498 -943 293 642 2686 -767 1117 688 1247 1771 255 -1971 1812 -600 -114 -2360 1367 -230 -797 -149 1014 -241 -3347 3091 -4027 -879 -3255 1158 2098 -3172 1358 1600 2130 -4887 3548 -2765 354 -4218 -3329 3558 -1244 -3665 2797 1147 2106 583 -814 1784 3140 -1003 -1365 -4761 900000 SO 20180523T095616.1Z 6717.414075 283 1 22.23 2 89.03 61.88 118.05 314.36 0.00 1 0.00 1 0 22 1.653e-02 1.606e-02 1.323e-03 1.308e-03 1.315393e+04 8.560748e+01 8.618196e+02 -6.000000e+00 8.541148e+02 281.65 -2.00 20.00 -2.00 505.56 0.00e+00 3.759834e-03 3.538823e-05 1.918619e-04 -6.000000e+00 4.517641e-04 281.65 -2.00 20.00 -2.00 501.31 0.00e+00 1.680381e+00 2.437358e-02 1.036481e-01 -6.000000e+00 3.206407e-01 231.40 -2.00 3.57 -2.00 502.78 0.00e+00 18.728 0.128 489.00 513.00 1 4.8135e+00 1.8486e-03 3.3297e-02 -6.0000e+00 2.4452e-02 -6.7611e-02 4.7670e-04 2.9659e-03 -6.0000e+00 6.5257e-03 9.5842e-04 1.8764e-03 9.5108e-05 1.1461e-04 -6.0000e+00 1.2894e-03 -7.6980e-03 1.3303e-04 12 9 9 12 1 1 42.11 15.00 6.85 -0.00770 0.00532 16 1 1 4 0 1307.460 22.09 15.00 19.15 -5831 -5235 -3452 -1317 -178 586 1513 1949 2013 937 450 -513 -827 -1801 -1909 -2123 -1434 -358 799 1150 1303 1179 1051 1192 1614 1747 1540 1372 409 -1643 -3003 -2477 -1693 276 1546 1730 1113 384 314 -37 -38 378 949 1640 2246 2413 2156 1455 984 -185 -1282 -2449 -3164 -3077 -1667 82 1402 1528 1354 1188 1420 1631 1863 1978 1512 1085 155 -315 -889 -1526 -1712 -1435 -1176 -325 221 62 -902 -1765 -2288 -2001 -1825 -1490 -1021 -1126 -634 -313 -118 -461 -347 -409 -240 787 1761 2319 1919 1369 750 -189 -1673 -2799 -3400 -2689 -1857 131 1112 622 -268 -1365 -1789 -1331 -309 298 1252 2047 2048 2581 2870 2634 1892 866 278 -366 -294 535 1003 1036 790 413 442 740 305 -404 -1318 -2089 -2356 -1794 -681 -76 571 772 731 227 569 609 1154 742 -296 -1984 -3025 -3091 900000 -4989 -4532 -3054 -1196 -152 509 1336 1743 1806 840 398 -454 -724 -1571 -1655 -1850 -1259 -320 732 1071 1211 1099 984 1122 1535 1671 1476 1315 388 -1524 -2746 -2263 -1566 262 1522 1724 1103 379 307 -36 -37 373 948 1656 2294 2484 2223 1496 1003 -187 -1270 -2386 -3056 -2985 -1652 84 1454 1604 1424 1247 1489 1604 1846 1966 1504 1068 151 -305 -859 -1465 -1750 -1362 -1128 -316 217 61 -873 -1685 -2174 -1887 -1720 -1415 -973 -1083 -618 -308 -116 -452 -337 -397 -235 775 1761 2315 1876 1299 691 -170 -1502 -2493 -3017 -2410 -1726 128 1129 644 -278 -1409 -1832 -1374 -325 317 1334 2178 2185 2755 3115 2932 2133 973 307 -398 -315 576 1093 1135 874 459 491 826 319 -446 -1441 -2297 -2429 -1879 -730 -82 625 860 825 260 655 704 1331 856 -340 -2259 -3408 -3486 900000 SO 20180523T100052.5Z 6717.417274 287 1 39.02 2 88.30 62.67 118.63 315.42 0.00 1 0.00 1 0 29 1.312e-02 1.274e-02 9.507e-04 9.394e-04 1.185466e+04 5.938233e+01 7.988802e+02 -6.000000e+00 6.781893e+02 281.65 -2.00 20.00 -2.00 505.52 0.00e+00 3.281419e-03 2.542108e-05 1.712241e-04 -6.000000e+00 3.579019e-04 281.65 -2.00 20.00 -2.00 501.42 0.00e+00 1.661643e+00 1.731357e-02 9.019026e-02 -6.000000e+00 2.514493e-01 231.40 -2.00 3.57 -2.00 502.84 0.00e+00 16.840 0.093 489.00 513.00 1 4.4029e+00 1.3249e-03 2.8334e-02 -6.0000e+00 1.9223e-02 -6.6619e-02 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