File name: Pandora103s1_Downsview_20180526_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T004237.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v3d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180526_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180526 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180526T094928.0Z 6720.409352 248 1 40.00 2 89.75 60.29 105.27 275.39 0.00 1 0.00 1 0 34 1.985e-01 1.736e-01 1.607e-01 1.485e-01 2.335490e+04 1.146127e+04 1.549865e+03 -6.000000e+00 1.027291e+04 281.96 -2.00 20.00 -2.00 505.18 0.00e+00 -3.390630e-03 3.997245e-03 1.633116e-04 -6.000000e+00 5.427701e-03 281.96 -2.00 20.00 -2.00 499.85 0.00e+00 -4.112224e+00 2.992122e+00 1.162660e-01 -6.000000e+00 3.843600e+00 231.59 -2.00 3.57 -2.00 501.49 0.00e+00 20.112 0.159 489.00 513.00 1 1.0993e+01 2.2735e-01 3.7512e-02 -6.0000e+00 2.9329e-01 2.4747e-01 6.0039e-02 3.5930e-03 -6.0000e+00 7.8041e-02 2.6108e-06 -1.3861e-03 9.7529e-03 1.0784e-04 -6.0000e+00 1.5490e-02 2.1105e-04 2.6010e-04 12 8 8 10 0 0 7.21 15.00 10.75 0.00021 -0.00940 10 1 1 4 0 4000.000 22.29 15.00 19.48 4440 56914 -7045 2133 4502 18447 -5690 21325 18993 -3141 4473 -12540 -4514 -5017 -8782 -38133 7682 3474 10112 -9819 22295 25111 8713 23458 45857 20175 19116 -7182 -2808 -313 2235 3468 1260 -7820 -5964 -15482 -1160 -6422 16688 -9887 20929 27359 -5517 5698 -19800 -667 -18238 25597 10026 -12128 -14124 15258 -17351 28498 16980 -6744 14160 -894 13102 12960 7364 -10907 28096 4098 22429 -5200 4225 -26200 24989 -14102 23478 7411 60224 -8480 2896 -3052 63774 6480 23033 -23058 -36482 23858 -7760 18329 -1009 10949 17261 37312 -13337 18563 -25282 20759 -25924 48123 8743 28870 -12673 9312 21321 -6287 -13941 20251 50471 -8080 -15516 18315 20391 -5672 37034 -19121 15771 -13117 22423 -20337 5009 -14083 18989 1243 28324 -4689 6924 16627 4926 17780 -3161 36991 -13353 -1269 12160 -8468 -4365 -8847 -2323 2944 -423 20138 4005 33730 910 17110 -21847 15696 -7428 32944 26897 -5137 -7404 8410 14965 -21669 900000 4296 33717 -7936 2288 4835 17609 -7001 20503 18687 -3776 4903 -16016 -5251 -5756 -10339 -59576 7796 3770 10659 -12749 21194 23227 9399 21926 34722 19496 18513 -8903 -3263 -339 2295 3524 1329 -9375 -7314 -20979 -1350 -7737 15851 -11948 18710 23049 -6421 6009 -26957 -757 -24334 22079 9876 -14427 -16523 13034 -19882 21089 14455 -7503 13225 -974 12426 12205 7296 -12980 23126 4246 19364 -5759 4190 -34345 19869 -16099 18449 6819 33906 -9387 2925 -3246 34919 5976 17903 -27671 -49776 18408 -8189 15248 -1034 10158 15103 26771 -15370 15633 -32561 17402 -34499 31023 7838 20190 -12523 7190 14468 -5472 -12997 13973 27648 -8385 -18428 16114 17522 -6134 26067 -23094 13815 -15228 18338 -24779 4724 -15915 15938 1272 22502 -5018 6413 13499 4356 13922 -3052 24274 -14181 -1194 9948 -8442 -4146 -8492 -2056 2473 -368 14679 3501 22392 834 13666 -25684 12962 -7681 23052 19789 -5090 -7374 7024 11496 -23534 900000 SO 20180526T095423.0Z 6720.412766 252 1 40.00 2 88.98 61.14 106.13 276.23 0.00 1 0.00 1 0 36 1.030e-01 9.773e-02 8.524e-02 8.282e-02 1.380058e+04 5.818061e+03 1.054315e+03 -6.000000e+00 5.334457e+03 281.96 -2.00 20.00 -2.00 505.28 0.00e+00 -2.456761e-04 2.196761e-03 3.830719e-05 -6.000000e+00 2.816990e-03 281.96 -2.00 20.00 -2.00 500.00 0.00e+00 7.612337e-01 1.650000e+00 4.264839e-02 -6.000000e+00 1.992536e+00 231.59 -2.00 3.57 -2.00 501.66 0.00e+00 18.592 0.125 489.00 513.00 1 1.0228e+01 1.2636e-01 3.1704e-02 -6.0000e+00 1.5208e-01 1.2428e-01 3.2721e-02 2.3052e-03 -6.0000e+00 4.0398e-02 4.8354e-06 8.1284e-03 5.9587e-03 1.0906e-04 -6.0000e+00 8.0388e-03 -2.6208e-02 5.1899e-04 12 8 8 10 0 0 89.32 15.00 5.41 -0.02621 0.03017 10 1 1 4 0 4000.000 22.40 15.00 19.48 -14521 -1205 -3846 1835 -8021 9749 6336 18897 5633 12376 -11704 13463 -2682 8163 4338 16681 14205 15023 -5908 1705 -8675 -2729 -1133 -5956 -473 -12145 6875 -7357 6603 -4823 -15138 -7714 6185 -2717 6278 -16021 10410 -5411 9721 -3204 3817 22050 9987 -1252 1514 -8387 9520 14453 5116 17965 -4724 6590 -22727 8501 3240 20207 6595 3818 -4723 -2454 -5836 3215 -1919 11098 -7078 20648 7197 -5204 76 -5762 -1237 -9059 -16470 -11497 -1637 -2711 15432 -15117 -2431 -936 1137 2723 251 13097 8119 -1635 -6582 5608 8732 15380 -4619 5702 13310 1273 -750 587 -12887 25037 -5408 17643 -17533 16430 5611 -8193 -2456 19008 -16652 25086 -7984 19621 -3964 12740 -9098 7202 -2513 19214 -10631 -6516 10585 38 3448 2990 -4484 -11763 -4187 -5962 12493 -973 6180 3230 6410 -446 -3056 -10824 2432 282 -5547 -5340 -1785 3227 4576 18497 -8251 15877 2606 11547 -11585 1767 -10795 22894 900000 -16021 -1199 -4092 1913 -9368 9785 6697 17786 5985 12077 -14227 12666 -2898 7837 4306 14803 13173 14305 -7071 1899 -10663 -3168 -1293 -7165 -542 -15512 7264 -8809 6636 -5204 -17909 -8583 6216 -3123 6749 -21183 10486 -6261 9572 -3551 3966 19346 9965 -1410 1670 -10159 9579 13637 5179 15543 -4915 6000 -27296 7712 3215 17567 6637 3942 -5263 -2658 -6558 3334 -2095 10618 -7959 17386 6778 -5471 75 -5907 -1208 -9634 -19098 -12947 -1679 -2748 12762 -16525 -2331 -880 1055 2511 238 11140 7364 -1636 -6875 5156 7735 12783 -4705 5352 11669 1223 -706 524 -12645 16626 -4725 12147 -17124 11990 4837 -8564 -2486 15575 -18940 18648 -8152 15589 -4017 11036 -9734 6555 -2508 15711 -11852 -7036 9559 37 3165 2693 -4345 -12391 -4108 -5951 10428 -919 5445 2932 5517 -401 -2793 -10631 2126 259 -5511 -5348 -1754 3059 4308 15305 -8879 13512 2511 10059 -12310 1607 -10977 16946 900000 SO 20180526T095907.0Z 6720.416053 256 1 40.00 2 88.23 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