File name: Pandora103s1_Downsview_20180531_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T001743.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v3d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180531_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180531 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180531T094622.0Z 6725.407199 232 1 40.00 2 89.75 59.12 77.53 223.67 0.00 1 0.00 1 0 64 2.323e-01 1.923e-01 1.824e-01 1.659e-01 2.435532e+04 1.292397e+04 6.478931e+02 -6.000000e+00 1.204389e+04 282.48 -2.00 20.00 -2.00 505.24 0.00e+00 9.126508e-03 4.444482e-03 5.634889e-04 -6.000000e+00 6.348317e-03 282.48 -2.00 20.00 -2.00 500.03 0.00e+00 -1.162123e+00 3.261816e+00 7.534596e-02 -6.000000e+00 4.452287e+00 231.91 -2.00 3.57 -2.00 501.61 0.00e+00 20.096 0.158 489.00 513.00 1 1.0699e+01 2.5034e-01 3.8545e-02 -6.0000e+00 3.4046e-01 1.8055e-01 6.1093e-02 2.3221e-03 -6.0000e+00 8.9383e-02 2.3236e-06 5.1009e-02 1.1135e-02 1.3230e-04 -6.0000e+00 1.8002e-02 8.5824e-03 -5.2479e-06 12 8 8 10 0 0 84.72 14.99 14.16 0.00858 0.36240 10 1 1 4 0 4000.000 22.29 14.99 19.43 -1970 -23572 12255 -19377 11000 27602 23637 6905 -30494 47122 13003 -6368 7282 7342 1705 50279 -6968 -14011 -11941 63104 20310 5897 14172 -6858 11957 -6172 -11256 -9963 -6328 17706 38635 -841 43575 -16364 28612 -17015 9061 5618 27514 -6657 29641 21232 48507 7789 14223 -18372 -7923 -31823 6176 14327 17377 40493 -15112 -9223 -8626 15696 4010 18592 -16435 3427 -13990 39790 -14168 33949 -12145 8409 9999 7639 -8815 43763 32948 20909 -11848 -2906 63908 9625 43839 -12604 25348 -18897 11449 -20699 -84 -20624 947 7960 9577 -22826 50119 -13326 40871 9881 26369 10593 40898 6245 -20481 8738 -30579 16629 -16985 12154 -687 31133 9287 36916 -2602 -13897 9646 1610 35063 -896 -15177 3662 -5182 -7236 13635 1868 28307 -24679 6314 -19860 58155 2364 -4452 41290 24850 -5878 27024 18336 24859 -23747 -13804 31748 61892 -1680 38456 9314 -8051 15603 -508 36595 3845 4753 -18099 -4123 -24996 -17912 2278 13285 -8211 -2177 -33090 12402 -27109 11630 24863 21813 7294 -45326 32715 12264 -7139 7123 7211 1797 34286 -8361 -17912 -14889 38367 18611 6284 14059 -8315 12043 -7276 -13328 -11210 -6840 15386 28466 -947 32610 -21490 24013 -21870 8982 5758 23162 -7907 25310 19983 35582 8436 14337 -24976 -9561 -46892 6122 12893 15167 29116 -19297 -11492 -10828 15605 4435 17843 -22298 3874 -18736 31630 -18603 27482 -15033 8456 9756 7485 -10077 30453 25726 18621 -14419 -3164 35774 8897 28936 -14153 19827 -22645 10278 -25615 -86 -25695 946 7283 8495 -27622 30644 -15294 28052 8819 19103 8474 23556 4904 -20355 6433 -32945 11840 -17792 10228 -671 22431 8118 24414 -2530 -15445 8714 1578 24932 -896 -17374 3558 -5643 -8144 12402 1849 20999 -29596 5628 -23111 32320 2247 -4527 26922 18967 -6006 19578 14078 17878 -27169 -14544 22191 32809 -1640 25965 8414 -8635 13368 -506 25387 3612 4353 -20118 -3913 -28804 -19499 2088 11244 -8664 SO 20180531T095113.0Z 6725.410567 236 1 40.00 2 89.00 59.95 78.12 224.62 0.00 1 0.00 1 0 74 1.131e-01 1.080e-01 1.110e-01 1.077e-01 8.003476e+03 6.961765e+03 3.266111e+02 -6.000000e+00 5.860166e+03 282.48 -2.00 20.00 -2.00 505.23 0.00e+00 1.347505e-03 2.838481e-03 1.642572e-04 -6.000000e+00 3.092590e-03 282.48 -2.00 20.00 -2.00 500.09 0.00e+00 1.537661e+00 2.118121e+00 8.361460e-02 -6.000000e+00 2.183460e+00 231.91 -2.00 3.57 -2.00 501.71 0.00e+00 18.627 0.126 489.00 513.00 1 1.0419e+01 1.6135e-01 3.2399e-02 -6.0000e+00 1.6669e-01 1.1315e-01 4.2329e-02 2.3283e-03 -6.0000e+00 4.4253e-02 3.6968e-06 4.8337e-03 7.8670e-03 5.5495e-05 -6.0000e+00 8.8094e-03 1.5032e-02 -3.9262e-04 12 8 8 10 0 0 -4.68 14.99 14.08 0.01503 0.04856 10 1 1 4 0 4000.000 22.29 14.99 19.43 900000 -5881 -2538 20650 -4965 -295 -3572 19981 11337 2810 -5530 -3556 9744 3642 -5526 1325 18171 339 -1954 -19969 6551 1386 4262 -6400 14809 1572 1572 -3001 -3265 -5091 7906 11068 4941 10292 -13520 -4082 -7823 -7783 4974 420 8607 16863 -6903 7465 -8367 22898 11959 16632 12714 -9899 -3555 988 5293 9618 -2327 21052 -10243 -18858 1631 -16251 25027 -12617 17395 1602 1967 -3266 -241 561 2738 8724 -28989 2564 4626 -3148 1163 7865 2509 14 -5321 10043 -871 -2848 -1736 2080 13736 -6227 -7248 17665 17084 2976 -9465 17910 -14792 284 1120 -4220 -8803 14403 4477 -15731 5032 -5180 2346 -13428 -5919 -9030 4858 7810 -11087 -11011 8490 -2234 1412 25685 27242 24335 23846 7914 -19339 13934 23976 -3299 11492 18162 1383 6865 -4189 31259 -2290 3645 -3687 -179 -9289 -8462 -7748 7862 -14300 -3032 9063 978 -5968 -3135 6918 -12761 12741 -9787 20437 -8969 13346 5290 11193 900000 -5950 -2560 17363 -5523 -320 -4079 18471 11438 3050 -6381 -3970 9436 3674 -6018 1346 15806 358 -2181 -27182 6893 1532 4574 -7614 14446 1753 1746 -3468 -3728 -5679 7476 10092 4836 9891 -17147 -4820 -9477 -9271 5165 449 8468 15381 -8011 7624 -10094 20545 11907 15634 12214 -11601 -3792 975 4894 8480 -2353 17674 -12006 -24382 1728 -20318 20860 -15211 15786 1695 2064 -3551 -250 566 2674 7934 -37290 2419 4312 -3208 1157 7353 2418 13 -5296 8549 -821 -2758 -1676 1941 11592 -6462 -7616 14519 14021 2785 -10006 14678 -16970 285 1095 -4217 -8924 11313 3769 -15729 4044 -4622 2006 -14104 -6076 -9703 4523 6932 -11581 -11470 7452 -2215 1366 19779 20694 19011 18880 7415 -23661 12173 18605 -3255 9647 14334 1301 6137 -4168 22080 -2220 3343 -3639 -168 -9263 -8279 -7475 6575 -15253 -2968 7981 944 -6223 -3192 6418 -14401 11257 -10724 16478 -9348 10882 4604 9281 SO 20180531T095548.0Z 6725.413750 240 1 40.00 2 88.28 60.74 78.69 225.51 0.00 1 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