File name: Pandora103s1_Downsview_20180601_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T004139.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v3d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180601_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180601 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180601T094550.0Z 6726.406829 227 1 40.00 2 89.76 58.91 72.46 213.31 0.00 1 0.00 1 0 22 1.111e-01 1.040e-01 9.765e-02 9.419e-02 1.186969e+04 6.463208e+03 1.157105e+03 -6.000000e+00 5.762912e+03 282.59 -2.00 20.00 -2.00 505.20 0.00e+00 2.681215e-03 2.548277e-03 1.132805e-04 -6.000000e+00 3.039879e-03 282.59 -2.00 20.00 -2.00 499.96 0.00e+00 2.568407e-01 1.899130e+00 1.969958e-02 -6.000000e+00 2.143025e+00 231.98 -2.00 3.57 -2.00 501.59 0.00e+00 20.097 0.158 489.00 513.00 1 1.0149e+01 1.4554e-01 3.5950e-02 -6.0000e+00 1.6366e-01 1.6987e-01 3.8297e-02 2.1186e-03 -6.0000e+00 4.3365e-02 4.2341e-06 -1.1505e-02 6.8281e-03 1.1358e-04 -6.0000e+00 8.6466e-03 2.3281e-03 -2.1114e-04 12 8 8 10 0 0 -8.95 15.00 5.66 0.00233 -0.07747 10 1 1 4 0 4000.000 22.29 15.00 19.38 900000 -9787 -6503 2778 9170 5206 9375 -9223 17758 8820 1656 4200 -5272 -7511 19518 12328 4857 -2672 6852 1218 26685 -17172 2923 -5839 -270 20941 10367 -10877 -15537 15746 -6549 -3991 -7013 8844 -4223 11264 10842 -6717 -10164 16372 -8338 -10572 4107 -1011 -1171 -4276 4153 3691 630 -6979 -2684 -14296 21559 3057 20109 -3789 10592 -5347 1589 5555 -1337 -19243 5774 7034 -2340 2998 14117 20459 11701 -7235 -4923 7412 -3701 -3567 -461 -14280 -5225 9537 -8417 23184 -8187 5753 -9852 10163 -5869 -11147 7727 -2361 3563 10680 10619 1343 19215 -5899 15036 -4771 4957 -8722 14110 11357 -8474 -24427 14790 -2359 1594 4464 4520 2879 16435 29394 -12057 -4390 -9802 5251 -8116 9800 -2936 -11815 -6165 2480 -22388 12129 -590 6860 5707 19430 1842 -5345 9960 -1674 14386 6144 800 -1544 26341 30354 2180 -6898 -65 -1007 -15301 -11623 8251 -6729 27982 -6500 6906 699 9007 -2967 10953 900000 -10502 -6831 2756 8913 5408 9522 -11456 17206 9324 1852 4486 -6085 -8723 17132 11467 4841 -2890 6910 1341 23364 -22954 3203 -6959 -305 19431 10690 -13719 -20408 14977 -7386 -4242 -7660 8394 -4722 11342 11102 -8036 -12384 15214 -9722 -12557 4266 -1116 -1311 -4998 4503 4003 695 -8152 -2943 -16962 17506 2909 16181 -3951 9997 -6061 1705 5717 -1459 -24888 5896 7137 -2602 3145 13079 17454 10684 -7859 -5149 6766 -3754 -3644 -463 -16704 -5584 8617 -8812 17627 -8363 5122 -10274 8783 -5944 -12046 7041 -2371 3354 9287 9185 1273 15514 -6198 12962 -4862 4433 -8587 10780 8701 -7682 -25449 10659 -2079 1433 4098 4204 2695 13240 20521 -12595 -4343 -10385 4846 -8546 8664 -2936 -13024 -6547 2428 -27425 10382 -556 5899 4986 15056 1693 -5268 8455 -1577 11638 5372 719 -1385 17913 19756 1885 -6700 -60 -949 -16772 -12407 7289 -6898 20568 -6654 6173 652 7531 -2710 8673 SO 20180601T095045.0Z 6726.410243 231 1 40.00 2 88.99 59.75 72.94 214.37 0.00 1 0.00 1 0 22 6.226e-02 6.025e-02 6.351e-02 6.225e-02 8.821003e+03 4.149662e+03 6.939610e+02 -6.000000e+00 3.229065e+03 282.59 -2.00 20.00 -2.00 505.21 0.00e+00 2.953801e-03 1.660745e-03 2.499021e-04 -6.000000e+00 1.702507e-03 282.59 -2.00 20.00 -2.00 499.96 0.00e+00 1.723780e+00 1.232836e+00 4.867376e-02 -6.000000e+00 1.197107e+00 231.98 -2.00 3.57 -2.00 501.58 0.00e+00 18.611 0.126 489.00 513.00 1 9.8277e+00 9.4247e-02 3.2222e-02 -6.0000e+00 9.1467e-02 1.3298e-01 2.4499e-02 2.0514e-03 -6.0000e+00 2.4161e-02 6.5147e-06 1.0650e-02 4.5599e-03 8.6034e-05 -6.0000e+00 4.8342e-03 -1.9929e-03 -1.1067e-05 12 8 8 10 0 0 5.96 15.00 5.24 -0.00199 0.07188 10 1 1 4 0 4000.000 22.29 15.00 19.38 900000 -4201 10722 9447 -908 -1524 2283 1974 10939 2929 -1751 2935 6709 4825 3970 -6247 3838 -12642 -7212 3980 -4236 16632 8892 -3785 -2541 1952 -1299 -619 -731 -5226 -6234 8056 -650 3191 1833 5085 -2499 956 2851 -6545 210 1703 -4967 -4888 6919 982 983 -1706 -292 -5773 -5182 -175 -4869 3867 5770 -11950 14610 -3858 6407 -2602 -2761 6233 1817 -2457 1283 34 321 -5140 -8400 -6899 2162 -5364 3721 -2164 9469 -813 2125 2562 8972 6263 -10649 -7583 -4745 10472 105 4403 -3881 -8778 3866 -12134 -3199 -9219 9321 2013 14402 -3081 776 -1770 -693 -1713 -6274 -1454 0 -5265 7704 -9355 -1547 15006 2225 -3412 7398 1069 -2891 8696 -6650 12862 -1219 -341 348 1575 -8117 5650 9247 -1945 5734 -7409 -1765 11075 6266 12327 -4654 -5703 4785 5394 -3978 3781 4447 -4034 4212 -1421 9887 174 738 13661 -129 -5249 -4229 -897 9731 1096 -8391 900000 -4340 9967 9246 -1004 -1727 2543 2222 11226 3186 -1957 3095 6700 4828 3977 -6937 3917 -15608 -8695 4330 -4969 15931 9167 -4437 -2966 2179 -1490 -699 -800 -5702 -6745 7634 -687 3404 2045 5478 -2851 1040 2999 -7480 226 1819 -5733 -5716 7290 1097 1088 -1909 -317 -6417 -5524 -172 -4970 3671 5576 -14229 13702 -4345 6494 -2856 -3038 6333 1932 -2714 1350 36 327 -5453 -9093 -7219 2047 -5492 3527 -2209 8707 -813 2007 2358 7691 5475 -11003 -7666 -4676 8963 100 4075 -3875 -9111 3520 -12890 -3133 -9757 8381 1928 11883 -2919 686 -1557 -589 -1437 -5478 -1237 0 -5142 6808 -9724 -1465 11847 1971 -3241 6458 1006 -2849 7682 -6818 10966 -1209 -338 340 1487 -8227 4894 7699 -1831 5039 -7395 -1670 9197 5440 10142 -4455 -5367 4007 4454 -3602 3253 3902 -3891 3794 -1369 8565 166 704 11525 -124 -5254 -4089 -813 7805 959 -8206 SO 20180601T095526.0Z 6726.413495 235 1 40.00 2 88.26 60.55 73.41 215.37 0.00 1 0.00 1 0 15 3.626e-02 3.600e-02 3.230e-02 3.181e-02 1.060803e+04 2.185804e+03 6.497378e+02 -6.000000e+00 1.880521e+03 282.59 -2.00 20.00 -2.00 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