File name: Pandora103s1_Downsview_20180603_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T001830.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v3d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180603_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180603 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180603T094454.0Z 6728.406181 229 1 40.00 2 89.76 58.52 64.04 191.15 0.00 1 0.00 1 0 22 1.273e-01 1.172e-01 1.154e-01 1.111e-01 1.716409e+04 7.918270e+03 1.075748e+03 -6.000000e+00 6.606448e+03 282.79 -2.00 20.00 -2.00 505.35 0.00e+00 1.428192e-03 2.969627e-03 6.293111e-05 -6.000000e+00 3.482157e-03 282.79 -2.00 20.00 -2.00 500.19 0.00e+00 2.511600e+00 2.160180e+00 1.058608e-01 -6.000000e+00 2.448755e+00 232.11 -2.00 3.57 -2.00 501.80 0.00e+00 20.092 0.158 489.00 513.00 1 1.0155e+01 1.6462e-01 3.6946e-02 -6.0000e+00 1.8709e-01 7.6707e-02 4.2690e-02 3.2674e-03 -6.0000e+00 4.9453e-02 3.5765e-06 1.6329e-03 7.9127e-03 8.9375e-05 -6.0000e+00 9.8864e-03 3.2982e-02 -2.6344e-04 12 8 8 10 0 0 -2.56 14.99 13.01 0.03298 0.04431 10 1 1 4 0 4000.000 22.19 14.99 19.33 900000 -2994 7360 -1026 -737 27799 -13373 2450 -4882 -1720 -832 15736 -1030 -4642 -14812 -4811 2947 8638 -3444 14330 17188 19792 -13588 -11096 -2801 892 6328 12869 4155 15751 26687 -11988 -5688 -3485 11790 -11436 23560 -1737 -2306 -3791 2663 -5120 -2317 7195 25066 -3865 4695 -15555 -11183 -115 7961 -19785 3390 9371 -859 -318 -2703 12040 -5885 18357 -6851 10641 -15299 24172 8510 8025 -6317 3162 11053 1040 -3366 7544 -5234 1674 29606 2130 -5253 6106 -3156 -5679 -8142 -4911 17290 -10712 20908 -24981 -16417 22 -812 31920 15754 4239 10415 11921 6614 13577 -7126 -5158 -10259 6332 -9442 5284 4063 25709 -7545 1363 -9128 11614 -13959 -371 -6413 2949 -7375 18349 -5978 -11696 -810 10158 1942 6191 29887 13192 11911 -8635 -2462 4442 27214 -8621 -90 -22750 8047 -42 2216 17301 21968 -18187 690 14351 -5321 2240 27855 -5779 3174 6760 -4732 11180 -18370 19035 -20157 40378 2507 900000 -2893 6642 -1049 -775 22594 -16559 2645 -5676 -1920 -903 14380 -1091 -5011 -17458 -5143 2949 8377 -3888 13916 16220 18219 -17267 -13779 -3237 999 6700 12743 4403 14297 21044 -13703 -6204 -3863 11800 -14563 21126 -1959 -2582 -4248 2795 -5828 -2596 7443 22108 -4537 5059 -20129 -13650 -123 7645 -24042 3223 8386 -869 -333 -2988 11680 -6782 16594 -7865 10374 -19298 20813 8476 7901 -6993 3138 10065 1029 -3412 6868 -5437 1650 22672 2124 -5489 5558 -3093 -5648 -8253 -4856 13885 -11332 16545 -31239 -18905 21 -788 22402 12926 3932 9274 10480 5935 10892 -6678 -4572 -9350 4825 -8257 4058 3289 18038 -7741 1313 -9707 9936 -15007 -350 -6549 2793 -7748 15020 -6167 -12744 -807 9324 1949 5891 22079 11112 9931 -8806 -2400 4068 20068 -9001 -86 -27137 7133 -40 1986 13359 16213 -20097 655 12168 -5515 2196 21638 -6261 3175 6550 -5119 10324 -22280 15702 -23721 26322 2379 SO 20180603T094939.0Z 6728.409479 233 1 40.00 2 89.03 59.34 64.20 192.36 0.00 1 0.00 1 0 36 2.747e-02 2.693e-02 2.537e-02 2.518e-02 2.039878e+04 1.827406e+03 1.334920e+03 -6.000000e+00 1.426074e+03 282.79 -2.00 20.00 -2.00 505.47 0.00e+00 2.238666e-03 6.782025e-04 1.415172e-04 -6.000000e+00 7.513606e-04 282.79 -2.00 20.00 -2.00 500.77 0.00e+00 1.399799e+00 4.795403e-01 1.298582e-01 -6.000000e+00 5.265928e-01 232.11 -2.00 3.57 -2.00 502.32 0.00e+00 18.678 0.127 489.00 513.00 1 8.9026e+00 3.6626e-02 3.3672e-02 -6.0000e+00 4.0271e-02 1.4059e-02 9.2358e-03 3.6960e-03 -6.0000e+00 1.0573e-02 1.6587e-05 -5.0370e-04 1.7188e-03 1.2867e-04 -6.0000e+00 2.1290e-03 -1.3788e-03 5.0852e-05 12 8 8 10 0 0 91.36 14.99 3.03 -0.00138 -0.00487 10 1 1 4 0 4000.000 22.29 14.99 19.33 -8335 -2878 -2866 1607 -4288 6659 113 7203 -2235 -254 -384 1178 1137 -862 810 -628 -1262 -3078 -1525 -3023 4962 -3205 1151 -1142 4434 1610 975 406 -1226 -3540 2531 -466 440 320 -603 1826 3067 3102 -1806 728 1745 689 1956 1891 33 -332 -2082 -541 -1365 -16 -407 3965 -629 -3548 -522 4041 3501 1775 -17 -1466 2432 9 2231 3238 -3718 951 3477 -2332 -64 -1961 1565 165 -1557 1768 -5238 -2722 -427 -5185 -1299 1067 981 4621 -3172 3201 -2727 1042 -4517 808 -4622 5091 -3760 -413 -1826 2363 -220 3564 3663 -3425 3176 -2336 -5348 952 -6300 -1369 3396 1756 2498 -1061 304 7 1262 -577 3856 -358 -1224 -543 554 -130 1853 1973 735 667 4138 2176 3224 3636 369 -2722 2350 4065 770 -915 -580 -58 -6959 3704 -1038 -1830 -1479 625 2294 -1027 129 246 -1216 -491 2342 -3823 1289 -6552 2085 -7626 -2522 -2594 1457 -4252 6054 112 6789 -2320 -257 -380 1136 1083 -824 754 -593 -1210 -3074 -1554 -3199 4859 -3401 1171 -1191 4423 1662 1011 422 -1275 -3612 2349 -445 422 320 -637 1918 3150 3138 -1894 736 1746 702 1994 1956 36 -359 -2289 -580 -1453 -17 -408 3688 -600 -3475 -509 3937 3538 1850 -18 -1567 2496 9 2330 3355 -4105 989 3457 -2413 -64 -1979 1501 161 -1554 1735 -5607 -2844 -426 -5275 -1254 997 913 4182 -3120 2980 -2735 1024 -4691 790 -4706 4670 -3765 -406 -1858 2312 -213 3176 3111 -3000 2559 -1952 -4540 770 -5715 -1270 3209 1735 2452 -1061 295 7 1244 -589 3780 -365 -1254 -553 568 -138 1956 2059 757 666 3899 2095 3123 3528 371 -2833 2314 3950 774 -911 -564 -56 -7207 3518 -1067 -1927 -1569 663 2431 -1135 142 271 -1357 -542 2482 -4208 1321 -7209 2135 SO 20180603T095353.0Z 6728.412419 237 1 8.00 2 88.37 60.06 64.36 193.43 0.00 1 0.00 1 0 22 9.097e-03 9.016e-03 3.638e-03 3.628e-03 2.140589e+04 2.554045e+02 1.421628e+03 -6.000000e+00 4.721897e+02 282.79 -2.00 20.00 -2.00 505.42 0.00e+00 3.369774e-03 9.791441e-05 1.982937e-04 -6.000000e+00 2.488654e-04 282.79 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