File name: Pandora103s1_Downsview_20180610_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T002142.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v3d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180610_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180610 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180610T094247.0Z 6735.404711 287 1 40.00 2 89.76 57.48 69.61 99.95 0.00 1 0.00 1 0 15 2.937e-02 2.937e-02 2.557e-02 2.543e-02 8.117243e+03 1.629407e+03 5.651249e+02 -6.000000e+00 1.529019e+03 283.52 -2.00 20.00 -2.00 505.41 0.00e+00 1.787100e-03 6.836528e-04 8.751990e-05 -6.000000e+00 8.046743e-04 283.52 -2.00 20.00 -2.00 500.63 0.00e+00 2.803853e+00 4.862574e-01 5.768201e-02 -6.000000e+00 5.628618e-01 232.56 -2.00 3.57 -2.00 502.22 0.00e+00 20.073 0.158 489.00 513.00 1 8.6396e+00 3.7193e-02 3.6161e-02 -6.0000e+00 4.3058e-02 3.1948e-02 9.4971e-03 2.4005e-03 -6.0000e+00 1.1297e-02 1.6455e-05 -2.6309e-03 1.8894e-03 6.3750e-05 -6.0000e+00 2.2755e-03 -2.6339e-02 2.2832e-04 12 8 8 10 0 0 1.64 15.00 3.86 -0.02634 -0.04459 10 1 1 4 0 4000.000 22.19 15.00 19.30 -1060 -3287 716 -4798 895 -17 2138 -2308 1894 1442 -3266 -2427 3879 -5729 -3862 -1776 -479 -1245 1514 1450 -196 1332 -1010 -1411 745 4360 4627 3377 -2731 867 -2092 838 -3705 3939 -2653 3187 -2029 3405 -186 -1992 -779 2481 1645 3974 1942 -2063 -422 2131 6892 -3458 3080 2873 1196 -1264 1168 -3536 1785 56 2470 -2166 3130 1104 1689 3040 -7652 137 -3405 1315 1403 -4148 -1913 1485 -1282 2370 362 4472 1916 351 -1670 3419 -5933 -2042 -6345 -812 -677 -97 -3655 1292 416 1583 107 -994 5964 1461 4699 3022 -793 -3043 3789 -4009 -9 -7065 162 -2269 -1662 2962 -1767 3451 -4721 71 3653 479 -785 -2072 7373 3860 5449 455 1486 967 -4484 1280 -3495 -2763 1190 5488 2368 1454 -1522 2876 -3106 -1026 1167 -1015 -1307 -3569 1660 3676 -1322 -716 2454 -1098 595 2373 -1267 1230 2107 -612 -2810 -7828 -622 -925 -2951 637 -4708 860 -17 2119 -2434 1929 1464 -3406 -2478 3682 -5871 -3843 -1729 -465 -1242 1524 1499 -206 1380 -1071 -1504 784 4465 4712 3472 -2942 867 -2070 801 -3752 3834 -2888 3351 -2225 3486 -194 -2096 -807 2504 1694 4054 2051 -2283 -459 2238 6803 -3704 3000 2711 1122 -1208 1115 -3682 1822 59 2546 -2319 3167 1145 1756 3123 -8687 142 -3584 1299 1371 -4225 -1872 1401 -1253 2268 360 4285 1842 334 -1594 3083 -5844 -1953 -6376 -776 -655 -95 -3700 1241 400 1500 103 -978 5606 1451 4453 2827 -747 -2845 3230 -3604 -8 -6482 143 -2165 -1658 2869 -1778 3240 -4712 68 3428 473 -795 -2140 6967 3780 5312 473 1536 991 -4750 1254 -3527 -2784 1172 5200 2318 1439 -1542 2802 -3221 -1023 1113 -980 -1260 -3556 1621 3607 -1380 -755 2535 -1180 633 2499 -1387 1312 2199 -638 -2913 -8440 -632 SO 20180610T094719.0Z 6735.407859 291 1 40.00 2 89.07 58.25 68.82 100.76 0.00 1 0.00 1 0 29 1.268e-02 1.214e-02 2.949e-03 2.903e-03 1.618680e+04 2.011898e+02 1.067076e+03 -6.000000e+00 6.599153e+02 283.52 -2.00 20.00 -2.00 505.62 0.00e+00 3.613314e-03 7.843722e-05 1.948721e-04 -6.000000e+00 3.473213e-04 283.52 -2.00 20.00 -2.00 501.40 0.00e+00 1.722099e+00 5.418899e-02 1.160943e-01 -6.000000e+00 2.430242e-01 232.56 -2.00 3.57 -2.00 502.84 0.00e+00 18.764 0.129 489.00 513.00 1 6.5569e+00 4.1363e-03 3.3673e-02 -6.0000e+00 1.8590e-02 -6.2632e-02 1.0322e-03 3.3249e-03 -6.0000e+00 4.8800e-03 1.6605e-04 8.4715e-04 2.0713e-04 1.1511e-04 -6.0000e+00 9.8246e-04 4.7029e-03 1.1611e-05 12 8 8 10 0 0 99.88 15.00 3.88 0.00470 0.01058 10 1 1 4 0 4000.000 22.19 15.00 19.31 -4698 -3404 -2258 -806 -489 256 835 2063 1928 573 297 -556 -1017 -615 -1460 -1777 -1791 -667 805 683 1165 246 1045 1228 1454 1460 1370 641 -14 -718 -2031 -1620 -1848 93 409 1243 387 617 -228 -87 -516 489 631 1359 1169 1897 1333 1397 505 377 -858 -1777 -2652 -1496 -637 -133 811 797 1075 498 1141 751 1322 1422 1501 587 388 -819 -555 -1213 -1290 -1806 -803 -281 -50 169 -441 -1404 -1475 -1590 -1767 -556 -1089 -158 -367 243 -185 -576 -24 620 -392 500 1094 1779 1487 1245 706 123 -1147 -2849 -2900 -1970 -2042 -316 1192 396 477 -1264 -1118 -812 -235 71 270 467 1553 2135 2508 1701 1759 582 -145 -642 -38 371 427 1117 892 593 292 1162 -52 19 -1146 -1373 -2295 -1068 -775 351 645 583 956 462 91 948 637 768 559 -1074 -1802 -2152 -1858 -3666 -2662 -1813 -669 -419 223 740 1839 1730 516 264 -492 -894 -531 -1260 -1540 -1573 -595 734 637 1084 231 978 1152 1380 1398 1312 618 -13 -662 -1838 -1463 -1703 87 405 1241 386 607 -224 -85 -505 480 629 1368 1201 1954 1381 1432 516 378 -845 -1714 -2536 -1417 -618 -134 838 837 1127 523 1191 795 1407 1519 1597 622 404 -851 -571 -1242 -1302 -1835 -817 -290 -49 164 -455 -1426 -1481 -1589 -1768 -554 -1017 -147 -349 234 -179 -556 -23 582 -373 481 1071 1739 1419 1144 626 106 -984 -2443 -2458 -1679 -1821 -296 1169 401 480 -1276 -1112 -812 -240 74 282 490 1613 2214 2642 1856 1937 641 -157 -681 -40 387 453 1185 955 639 314 1251 -57 20 -1213 -1455 -2460 -1154 -864 394 733 677 1123 550 110 1140 714 859 666 -1269 -2100 -2510 -2040 SO 20180610T095146.0Z 6735.410949 295 1 40.00 2 88.39 59.02 68.04 101.55 0.00 1 0.00 1 0 29 9.815e-03 9.548e-03 2.298e-03 2.283e-03 1.516571e+04 1.534736e+02 1.010554e+03 -6.000000e+00 5.109399e+02 283.52 -2.00 20.00 -2.00 505.48 0.00e+00 3.503293e-03 6.152390e-05 1.959209e-04 -6.000000e+00 2.689197e-04 283.52 -2.00 20.00 -2.00 501.08 0.00e+00 1.636377e+00 4.241537e-02 1.049927e-01 -6.000000e+00 1.881734e-01 232.56 -2.00 3.57 -2.00 502.60 0.00e+00 17.038 0.096 489.00 513.00 1 6.5180e+00 3.2368e-03 2.9209e-02 -6.0000e+00 1.4394e-02 -4.8707e-02 8.2014e-04 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