File name: Pandora103s1_Downsview_20180617_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T004159.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v4d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180617_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180617 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180617T094227.0Z 6742.404479 311 1 40.00 2 89.77 56.93 119.15 14.00 0.00 1 0.00 1 0 22 2.699e-02 2.715e-02 2.498e-02 2.481e-02 1.291451e+04 1.708378e+03 7.813939e+02 -6.000000e+00 1.409050e+03 284.23 -2.00 20.00 -2.00 505.39 0.00e+00 3.115386e-03 6.672871e-04 1.626873e-04 -6.000000e+00 7.409186e-04 284.23 -2.00 20.00 -2.00 500.47 0.00e+00 2.224505e+00 4.787020e-01 9.933428e-02 -6.000000e+00 5.176345e-01 232.90 -2.00 3.57 -2.00 502.06 0.00e+00 20.053 0.157 489.00 513.00 1 8.6319e+00 3.6567e-02 3.6827e-02 -6.0000e+00 3.9603e-02 5.7333e-02 9.3414e-03 2.9543e-03 -6.0000e+00 1.0398e-02 1.6886e-05 8.2950e-04 1.7958e-03 8.5215e-05 -6.0000e+00 2.0926e-03 1.0497e-02 -4.3780e-05 12 8 8 10 0 0 7.08 15.00 3.04 0.01050 0.01625 10 1 1 4 0 4000.000 22.40 15.00 19.50 375 -2719 -282 -538 -1856 3011 4889 4500 -6559 164 -1056 2235 -3334 1735 -2387 -4113 -3380 2336 -1192 2431 1552 3400 -2740 3734 -1894 -1103 620 -1000 1366 1172 -1690 1950 -1232 833 3219 -1667 4051 -1489 1065 -3357 2795 1821 2252 -4126 2795 -3866 1538 -678 2786 746 3866 -5530 -428 -3448 -2884 4339 496 4859 -673 -982 -544 334 774 951 -2243 2147 -927 332 -379 3308 277 -830 -1365 3121 684 710 -1036 -5567 4607 826 -3315 -2003 2350 -5703 -809 -2677 4005 -4811 4497 478 1438 1060 3674 3240 -2471 1331 -1696 -2626 -565 335 2438 1131 -3073 4689 -4162 1219 -1337 4447 -3996 -1492 -5633 -1268 676 2824 -693 1234 -849 2367 4804 -202 2905 2117 1466 1462 -642 -685 -1257 -2522 506 2258 1377 -5243 1650 -2633 2919 -2062 1738 -990 -958 2739 42 910 -402 4247 -386 483 1294 1995 -930 -1110 -7544 331 -2498 -262 -523 -1885 2971 4850 4551 -7406 171 -1095 2218 -3444 1677 -2378 -4163 -3429 2295 -1255 2521 1621 3487 -2983 3826 -2069 -1204 663 -1083 1421 1169 -1675 1864 -1233 850 3357 -1851 4205 -1606 1107 -3601 2820 1871 2334 -4616 2966 -4409 1660 -739 2892 774 3762 -5712 -412 -3420 -2922 4272 522 4965 -725 -1054 -579 355 825 1012 -2449 2211 -964 335 -381 3167 269 -812 -1354 3009 687 712 -1030 -5633 4165 768 -3202 -1924 2177 -5739 -787 -2686 3765 -4894 4133 454 1356 1017 3511 3125 -2458 1229 -1555 -2351 -484 279 1958 930 -2734 4111 -4185 1182 -1319 4074 -3908 -1431 -5751 -1262 666 2737 -695 1216 -867 2390 4759 -208 2823 2020 1383 1389 -632 -677 -1253 -2548 493 2175 1337 -5306 1529 -2530 2650 -1997 1673 -997 -975 2734 44 940 -423 4293 -408 505 1321 1968 -921 -1095 -8026 SO 20180617T094714.0Z 6742.407801 315 1 40.00 2 89.04 57.75 118.95 15.23 0.00 1 0.00 1 0 22 1.429e-02 1.398e-02 7.383e-03 7.326e-03 1.860288e+04 5.163118e+02 1.218848e+03 -6.000000e+00 7.459475e+02 284.23 -2.00 20.00 -2.00 505.53 0.00e+00 4.452120e-03 1.982018e-04 2.378748e-04 -6.000000e+00 3.922678e-04 284.23 -2.00 20.00 -2.00 501.08 0.00e+00 1.634914e+00 1.376316e-01 1.242448e-01 -6.000000e+00 2.740676e-01 232.90 -2.00 3.57 -2.00 502.58 0.00e+00 18.673 0.127 489.00 513.00 1 7.5723e+00 1.0508e-02 3.3812e-02 -6.0000e+00 2.0968e-02 -2.4936e-02 2.6430e-03 3.4956e-03 -6.0000e+00 5.5060e-03 6.0170e-05 1.1353e-03 5.1039e-04 1.3104e-04 -6.0000e+00 1.1077e-03 -6.6577e-03 5.3330e-05 12 8 8 10 0 0 60.49 15.00 3.14 -0.00666 0.00122 10 1 1 4 0 4000.000 22.40 15.00 19.50 -4668 -3199 -3309 -870 -494 191 1036 915 651 -361 1276 -601 -734 -13 -292 -531 -647 -1460 1087 -398 -163 -1835 249 562 986 1639 1926 -241 -752 -14 -1006 -1793 -167 430 2530 1858 691 624 1405 161 -759 -81 1052 1575 958 1637 1076 951 761 695 -548 -1930 -2521 -3162 -1847 -456 993 1917 1261 -882 1941 2025 2504 1009 2739 635 -261 -787 -537 -1944 -879 -291 -859 -1963 -919 -905 644 -1040 -1649 -599 -895 -1828 -1150 -381 -427 1152 -575 -12 -286 152 -179 1991 1743 1974 2197 1366 1167 -821 -242 -3108 -3202 -2144 -1923 -325 1327 1193 433 -1432 -1846 -1824 -56 51 1102 290 2042 1511 2584 2328 1920 766 80 -1250 -1971 1694 526 79 632 -328 -608 712 -439 -492 78 646 -1819 -795 -1023 122 370 1840 631 -102 172 266 1208 406 -347 -477 -799 -3660 -2180 -3941 -2695 -2888 -775 -453 178 978 879 628 -348 1189 -563 -680 -12 -263 -479 -591 -1375 1034 -392 -160 -1831 244 551 974 1623 1899 -242 -747 -13 -931 -1671 -155 414 2504 1880 700 624 1380 158 -755 -81 1056 1599 994 1703 1126 985 780 700 -542 -1878 -2424 -3064 -1817 -462 1022 1983 1313 -933 1996 2098 2606 1067 2838 662 -269 -804 -543 -1966 -867 -285 -855 -2004 -946 -931 638 -1021 -1606 -573 -856 -1776 -1117 -370 -421 1135 -575 -12 -279 147 -174 1924 1727 1959 2113 1269 1041 -721 -208 -2692 -2737 -1836 -1713 -305 1295 1193 435 -1442 -1842 -1832 -56 52 1131 300 2078 1549 2669 2475 2071 825 85 -1305 -2031 1697 542 83 658 -345 -639 743 -463 -508 78 646 -1864 -821 -1092 131 401 2001 704 -115 196 303 1363 459 -391 -525 -865 -4057 -2416 SO 20180617T095155.0Z 6742.411053 319 1 40.00 2 88.32 58.55 118.74 16.42 0.00 1 0.00 1 0 22 9.081e-03 8.789e-03 4.294e-03 4.269e-03 1.828098e+04 3.022486e+02 1.197496e+03 -6.000000e+00 4.740716e+02 284.23 -2.00 20.00 -2.00 505.49 0.00e+00 4.084516e-03 1.154434e-04 2.233951e-04 -6.000000e+00 2.492725e-04 284.23 -2.00 20.00 -2.00 500.91 0.00e+00 1.586305e+00 8.083336e-02 1.199317e-01 -6.000000e+00 1.741197e-01 232.90 -2.00 3.57 -2.00 502.44 0.00e+00 16.855 0.093 489.00 513.00 1 7.2507e+00 6.1740e-03 2.9315e-02 -6.0000e+00 1.3322e-02 -1.7666e-02 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