File name: Pandora103s1_Downsview_20180621_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T002538.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v4d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180621_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180621 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180621T094303.0Z 6746.404896 286 1 40.00 2 89.77 56.84 126.31 312.45 0.00 1 0.00 1 0 29 5.339e-02 5.237e-02 4.950e-02 4.868e-02 3.973249e+03 3.008128e+03 2.252635e+02 -6.000000e+00 2.791131e+03 284.59 -2.00 20.00 -2.00 505.22 0.00e+00 1.829557e-03 1.302802e-03 1.036877e-04 -6.000000e+00 1.470127e-03 284.59 -2.00 20.00 -2.00 499.98 0.00e+00 3.293684e+00 9.619518e-01 4.523581e-02 -6.000000e+00 1.035905e+00 232.92 -2.00 3.57 -2.00 501.62 0.00e+00 20.042 0.157 489.00 513.00 1 9.2793e+00 7.3529e-02 3.5907e-02 -6.0000e+00 7.9076e-02 1.0197e-01 1.9268e-02 2.1535e-03 -6.0000e+00 2.1086e-02 8.4323e-06 6.7841e-03 3.6693e-03 3.7233e-05 -6.0000e+00 4.1664e-03 -7.0551e-03 1.5012e-04 12 8 8 10 0 0 -1.74 15.00 8.48 -0.00706 0.04000 10 1 1 4 0 4000.000 22.19 15.00 19.31 8504 -5916 -2304 3876 137 1428 10787 -8093 6064 -7250 10984 -698 9196 -7259 -5080 7168 9736 1729 1377 488 -4487 4345 -1863 -34 -350 1186 -9572 7210 3872 9391 -3238 -5544 -4090 1353 -3351 2916 -513 5575 -4841 3568 -1297 5391 -4810 -5849 4853 422 -3128 -3208 5314 -4480 4816 -381 1242 -952 4 1800 2517 611 -52 -1429 1147 466 -2973 -1053 -6326 1847 -2197 -8014 684 -4426 3600 10518 2537 6621 1877 2708 -7147 4711 -2291 1830 -10800 2688 390 -6014 4333 -5065 -626 1589 3805 9484 -4646 -386 1955 -6440 2173 -1126 -4279 -645 3428 -9108 13445 -4110 674 -3324 6556 -8318 -3366 -403 1614 -3737 1665 8305 -3811 -549 2928 8282 -9720 10952 -2724 8713 2750 726 -2586 8541 -6513 3045 1355 4213 -9907 6987 2381 5868 3143 8316 -2971 1049 2654 1402 3793 -1340 8022 -7202 9232 -5846 2134 71 5241 -8572 5394 -7921 900000 7411 -6056 -2367 3906 147 1536 10823 -9858 6414 -8578 10684 -752 8850 -8076 -5493 6902 9276 1835 1513 546 -5251 4669 -2124 -38 -399 1329 -11853 7523 4050 8887 -3397 -5983 -4452 1464 -3925 3210 -575 5798 -5492 3693 -1411 5533 -5522 -6868 5189 472 -3587 -3625 5428 -4895 4634 -375 1185 -937 4 1854 2627 652 -55 -1534 1201 495 -3271 -1133 -7083 1871 -2268 -8633 669 -4467 3315 9095 2397 6113 1834 2588 -7303 4196 -2165 1652 -11065 2438 362 -5984 3952 -5091 -601 1484 3461 8162 -4612 -374 1887 -6736 2046 -1069 -4083 -577 2869 -8412 9915 -3663 598 -3220 5899 -8585 -3249 -369 1437 -3552 1533 7285 -3809 -535 2765 7458 -10540 9750 -2739 7687 2522 666 -2446 7354 -6536 2780 1260 3791 -10214 6150 2170 5042 2728 6791 -2706 941 2413 1311 3508 -1317 7224 -7546 8301 -6123 2069 70 4766 -8631 4642 -7782 900000 SO 20180621T094748.0Z 6746.408194 290 1 40.00 2 89.04 57.66 126.92 313.65 0.00 1 0.00 1 0 15 3.990e-02 3.962e-02 3.524e-02 3.490e-02 6.482557e+03 2.240858e+03 2.433218e+02 -6.000000e+00 2.085781e+03 284.59 -2.00 20.00 -2.00 505.30 0.00e+00 1.571112e-03 9.385983e-04 9.022604e-05 -6.000000e+00 1.096552e-03 284.59 -2.00 20.00 -2.00 500.24 0.00e+00 2.334271e+00 6.834648e-01 8.613176e-02 -6.000000e+00 7.683416e-01 232.92 -2.00 3.57 -2.00 501.86 0.00e+00 18.677 0.127 489.00 513.00 1 9.1990e+00 5.2224e-02 3.2416e-02 -6.0000e+00 5.8732e-02 8.6458e-02 1.3526e-02 2.3312e-03 -6.0000e+00 1.5531e-02 1.1890e-05 -1.2366e-03 2.6010e-03 3.1703e-05 -6.0000e+00 3.1012e-03 9.1097e-03 -1.6907e-04 12 8 8 10 0 0 2.08 14.99 4.24 0.00911 0.00053 10 1 1 4 0 4000.000 22.19 14.99 19.32 900000 -7698 -2817 -2128 -2055 -3517 6845 2315 -449 -2104 2670 1518 -3546 -11106 2152 -4414 -1318 -3074 3758 4363 -4234 -1868 -40 5943 1762 425 -1192 3513 -2348 272 -739 4359 -866 3674 -1186 6797 -5249 4872 4439 2102 2920 2614 3668 -5209 2749 811 5665 -552 1848 581 1699 -8134 5365 3104 1092 -1786 595 898 8578 -2292 2537 -2499 -5875 3579 -6557 3203 -611 2171 -5682 10571 634 -2745 -2871 2244 3507 6971 -3116 11212 -5698 3162 -4837 184 -4720 -3294 -360 1060 -692 -3034 -2236 -2514 1682 -820 2040 -1401 5764 -5018 4369 -5242 1476 2455 483 -5926 7086 43 -5072 -2016 4218 890 -1745 1030 755 4057 -6855 1717 3352 1351 1651 7287 3264 2878 -4227 7983 -163 -944 2188 2519 3489 906 2186 -1743 5146 -1694 -1581 -310 -5139 -3699 -4009 3434 6005 -4211 1205 -2511 2317 1382 -3126 -2971 4154 -4155 -994 -6175 -3541 900000 -7704 -2761 -2163 -2161 -3825 6878 2477 -497 -2347 2789 1580 -3831 -12685 2132 -4644 -1353 -3275 3874 4592 -4858 -2091 -44 6159 1915 472 -1339 3752 -2625 285 -751 4172 -881 3687 -1310 7117 -6133 5071 4579 2187 2995 2700 3789 -5937 2939 891 5931 -607 1955 610 1712 -8706 4912 2880 1052 -1841 620 948 8415 -2480 2601 -2701 -6610 3677 -7407 3244 -630 2135 -5965 9354 606 -2696 -2843 2141 3366 6503 -3145 9564 -5636 2845 -4686 171 -4637 -3200 -344 1011 -674 -3014 -2188 -2457 1579 -796 1964 -1415 5370 -5053 3906 -4996 1282 2062 406 -5308 5741 39 -5113 -2008 3918 838 -1651 944 706 3747 -7138 1659 3198 1315 1615 6835 3196 2791 -4304 7063 -153 -896 2044 2354 3229 861 2039 -1690 4688 -1623 -1475 -282 -4865 -3473 -3883 3173 5483 -4304 1182 -2562 2265 1373 -3255 -3086 3975 -4196 -944 -6076 -3421 SO 20180621T095227.0Z 6746.411424 294 1 40.00 2 88.33 58.45 127.51 314.84 0.00 1 0.00 1 0 22 2.951e-02 2.940e-02 2.363e-02 2.348e-02 7.222974e+03 1.502453e+03 5.116822e+02 -6.000000e+00 1.542534e+03 284.60 -2.00 20.00 -2.00 505.38 0.00e+00 1.004180e-03 6.314556e-04 3.415660e-05 -6.000000e+00 8.109672e-04 284.60 -2.00 20.00 -2.00 500.47 0.00e+00 2.508014e+00 4.512501e-01 4.533948e-02 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