File name: Pandora103s1_Downsview_20180705_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T005031.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180705_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180705 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180705T094906.0Z 6760.409097 175 1 32.01 2 89.78 57.84 48.91 162.53 0.00 1 0.00 1 0 15 5.646e-02 5.495e-02 5.079e-02 4.999e-02 1.832633e+04 3.671301e+03 1.444440e+03 -6.000000e+00 2.958100e+03 285.88 -2.00 20.00 -2.00 505.27 0.00e+00 2.335689e-03 1.352314e-03 5.733190e-05 -6.000000e+00 1.554723e-03 285.88 -2.00 20.00 -2.00 500.05 0.00e+00 1.162920e-01 9.889633e-01 4.761277e-02 -6.000000e+00 1.090335e+00 232.99 -2.00 3.57 -2.00 501.68 0.00e+00 20.023 0.156 489.00 513.00 1 9.4955e+00 7.5867e-02 3.5990e-02 -6.0000e+00 8.3296e-02 1.3902e-01 1.9448e-02 2.7314e-03 -6.0000e+00 2.2164e-02 8.3230e-06 1.0856e-02 3.4285e-03 1.1900e-04 -6.0000e+00 4.3923e-03 8.3064e-01 -5.7533e-03 12 9 8 11 768 0 -7.02 15.00 4.97 0.83064 0.90595 8 1 1 4 0 4000.000 22.19 15.00 19.32 2094 -5682 -3013 -2944 -5612 -3754 -3838 530 1472 10395 -1158 -2955 2386 3110 1491 3685 3490 118 -5007 9226 251 4710 -4788 3916 -1598 5391 1778 498 -10417 -3423 954 1280 -16 5362 3200 4401 -774 -7268 -2008 -867 2375 -6868 2168 221 7354 -6434 -3147 -3267 7277 -9828 13745 62 12226 9317 5042 6720 -3289 1964 -963 8127 -2019 9867 -2469 1190 1119 3035 -6067 2951 -2958 1565 2088 -228 -12889 947 -8463 -1688 -3778 2933 -367 -5723 5176 -1393 4955 -5723 4605 105 9701 -9236 11893 4092 2753 -4117 12081 -291 11303 -8502 3546 7879 5070 -9019 -10272 -4271 -1440 -4599 -3013 6719 -3041 13479 -4082 6454 3763 -4203 -8832 10430 -6353 9252 5941 -2254 2801 -4699 -6301 555 2836 -6008 10020 -2501 1407 5483 -1482 6078 6124 1490 988 4123 -276 -2424 -7106 2088 -4368 2953 934 -2562 2545 -109 5111 -3212 8111 -348 -5923 455 -9916 1939 -5816 -3130 -3172 -6325 -4237 -4421 589 1611 10224 -1253 -3215 2420 3087 1494 3629 3498 126 -5785 9337 276 4964 -5523 4174 -1810 5702 1938 545 -12283 -3603 945 1272 -16 5500 3464 4701 -856 -8441 -2185 -925 2463 -7857 2301 243 7613 -7632 -3593 -3680 7275 -11304 12135 61 10494 8303 4848 6607 -3648 2083 -1048 8030 -2200 9661 -2739 1272 1186 3101 -6636 2915 -3066 1526 1998 -224 -14465 944 -9386 -1737 -3862 2739 -350 -5694 4620 -1336 4491 -5798 4291 104 8686 -9850 10188 3753 2567 -4164 10637 -288 9635 -8390 2977 6125 3974 -7950 -9055 -3607 -1236 -4356 -2971 6150 -3045 11283 -3984 5709 3486 -4267 -9407 9191 -6564 8202 5525 -2327 2776 -4940 -6552 523 2553 -5904 8540 -2415 1310 4911 -1410 5377 5415 1344 874 3520 -245 -2230 -7046 1927 -4325 2766 905 -2585 2456 -109 4802 -3254 7262 -330 -5784 413 -10038 SO 20180705T095328.0Z 6760.412130 179 1 32.01 2 89.11 58.59 48.67 163.91 0.00 1 0.00 1 0 29 3.155e-02 3.114e-02 2.231e-02 2.220e-02 1.466223e+04 1.535034e+03 9.563231e+02 -6.000000e+00 1.657305e+03 285.88 -2.00 20.00 -2.00 505.47 0.00e+00 4.070460e-03 6.013708e-04 1.879764e-04 -6.000000e+00 8.694957e-04 285.88 -2.00 20.00 -2.00 500.81 0.00e+00 1.786570e+00 4.212893e-01 1.017387e-01 -6.000000e+00 6.042167e-01 232.99 -2.00 3.57 -2.00 502.36 0.00e+00 18.791 0.129 489.00 513.00 1 8.6888e+00 3.2221e-02 3.3432e-02 -6.0000e+00 4.6260e-02 1.4883e-02 8.1363e-03 2.9798e-03 -6.0000e+00 1.2133e-02 1.9295e-05 8.3700e-04 1.5827e-03 1.0316e-04 -6.0000e+00 2.4451e-03 1.2256e-02 -1.8573e-05 12 8 8 10 0 0 17.23 15.00 4.55 0.01226 0.01806 8 1 1 4 0 4000.000 22.19 15.00 19.32 -10600 -3468 -5876 576 -1739 -1360 371 -1729 1178 798 492 -756 -2443 -5309 -1210 -4773 -1208 -351 3588 -1886 380 342 3943 1530 6718 870 3159 1153 858 -349 -1328 -3831 -2864 -3495 -402 3687 -250 2637 1910 2015 -431 -1527 4244 4224 486 10660 1292 4453 3411 301 -2055 1059 -3601 -4048 -2816 3607 60 1141 954 296 4344 -328 4215 111 -574 -3061 2717 2105 1523 -6585 1967 -1077 1355 -703 354 403 -3454 -4222 245 -4686 -3120 2733 -2986 2901 1526 4690 -4529 2207 -1093 2421 -1050 1602 3475 3486 617 3820 2180 -350 1652 -4409 -5731 -1271 -2110 -2632 4308 930 -1534 978 -2995 -4548 -1362 -2925 8935 -457 2961 1366 6373 1980 4225 2907 -368 2148 -3093 353 -904 3297 -969 -350 -2324 3554 -1084 1374 -2294 -6633 -4410 -648 1727 1416 -2004 1352 -426 1079 2022 1161 1423 1525 -328 -6717 -1771 -5252 -1311 -9900 -3063 -5501 530 -1687 -1339 368 -1777 1180 792 480 -738 -2392 -5256 -1141 -4659 -1151 -340 3460 -1955 385 347 3861 1538 6494 897 3176 1179 865 -340 -1267 -3744 -2819 -3604 -421 3764 -262 2650 1910 1993 -437 -1581 4216 4264 517 10349 1371 4533 3458 308 -2084 1011 -3534 -3997 -2828 3549 63 1199 1004 311 4390 -349 4335 119 -616 -3310 2724 2090 1508 -6952 1881 -1061 1317 -707 359 407 -3537 -4245 233 -4639 -3034 2531 -2941 2712 1469 4430 -4676 2118 -1071 2278 -1025 1548 3372 3395 601 3475 1940 -309 1400 -3882 -5043 -1085 -1889 -2522 4061 921 -1546 946 -2965 -4606 -1369 -3040 8349 -469 2944 1383 6249 2071 4350 2988 -381 2116 -3151 351 -922 3245 -999 -359 -2419 3512 -1120 1353 -2295 -6894 -4480 -646 1735 1452 -2147 1427 -463 1163 2173 1263 1544 1645 -355 -7529 -1850 -5651 -1377 SO 20180705T095743.0Z 6760.415081 183 1 32.01 2 88.45 59.32 48.46 165.27 0.00 1 0.00 1 0 22 1.566e-02 1.543e-02 1.079e-02 1.073e-02 1.806987e+04 7.693039e+02 1.208962e+03 -6.000000e+00 8.227851e+02 285.88 -2.00 20.00 -2.00 505.49 0.00e+00 4.553827e-03 2.917717e-04 2.358477e-04 -6.000000e+00 4.318387e-04 285.88 -2.00 20.00 -2.00 500.87 0.00e+00 1.888452e+00 2.044772e-01 1.100772e-01 -6.000000e+00 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