File name: Pandora103s1_Downsview_20180706_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T005029.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180706_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180706 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180706T094945.0Z 6761.409549 247 1 32.01 2 89.78 57.99 47.95 146.90 0.00 1 0.00 1 0 15 2.111e-02 2.100e-02 2.030e-02 2.020e-02 9.566382e+03 1.334616e+03 6.012891e+02 -6.000000e+00 1.109295e+03 285.97 -2.00 20.00 -2.00 505.40 0.00e+00 2.468573e-03 5.475145e-04 1.225811e-04 -6.000000e+00 5.821580e-04 285.97 -2.00 20.00 -2.00 500.63 0.00e+00 1.779661e+00 3.868907e-01 7.496765e-02 -6.000000e+00 4.055068e-01 233.00 -2.00 3.57 -2.00 502.20 0.00e+00 20.020 0.156 489.00 513.00 1 8.4529e+00 2.9580e-02 3.6301e-02 -6.0000e+00 3.1022e-02 5.8491e-02 7.5963e-03 2.5684e-03 -6.0000e+00 8.1854e-03 2.1259e-05 2.4767e-03 1.4929e-03 6.5455e-05 -6.0000e+00 1.6390e-03 -1.6988e-03 4.4384e-06 12 8 8 10 0 0 26.50 15.00 2.55 -0.00170 0.01548 8 1 1 4 0 4000.000 22.09 15.00 19.18 900000 -3746 -2588 -5337 -1476 2669 1447 -622 921 981 874 -853 346 -4653 -1021 -1483 -1897 241 737 1302 -947 1400 -1119 2954 -2447 1799 946 3175 1329 1638 -2607 2001 -2344 2933 916 -832 -957 1577 227 -781 1497 -632 -58 -2157 3977 429 2052 493 -1926 -3416 1593 -79 770 -2672 1197 290 -125 -713 402 -1426 453 1316 2994 1997 -1905 4943 -1168 3561 151 -113 -2350 2740 -850 -511 -3139 1115 -172 829 -1759 -786 -1003 402 427 2714 -661 679 3272 -1990 290 824 -2245 -2603 5956 -1718 1534 371 1365 -3067 1208 -1019 422 730 2605 1938 440 1119 973 1828 -2205 738 -531 -2743 -3516 4309 -3887 864 1798 2374 779 -497 -916 -710 1910 -4412 1152 -3003 -1697 -2246 3796 617 4050 -2274 1218 -4865 3259 -1235 989 287 -1151 -453 1324 2059 3708 -407 -1856 -801 1175 -1488 -1318 -1573 -2316 900000 -3432 -2425 -5368 -1473 2606 1463 -652 953 1002 876 -860 340 -4717 -990 -1445 -1874 239 753 1349 -1001 1447 -1185 3014 -2656 1884 995 3259 1363 1604 -2575 1890 -2347 2904 967 -905 -1029 1631 235 -807 1512 -657 -61 -2337 4119 463 2173 523 -2062 -3632 1561 -77 723 -2598 1153 294 -131 -759 423 -1516 472 1370 3086 2079 -2048 4894 -1202 3447 150 -111 -2316 2571 -834 -507 -3254 1106 -169 785 -1687 -742 -948 378 404 2524 -645 661 3109 -1978 279 788 -2220 -2618 5639 -1761 1491 353 1248 -2841 1049 -884 356 622 2262 1795 433 1104 951 1738 -2145 702 -522 -2807 -3663 4187 -4093 871 1821 2428 810 -514 -933 -705 1822 -4513 1132 -3077 -1721 -2290 3630 612 3880 -2262 1148 -4828 2979 -1198 968 288 -1187 -471 1366 2118 3776 -434 -2007 -854 1208 -1526 -1315 -1567 -2355 SO 20180706T095359.6Z 6761.412495 251 1 11.18 2 89.13 58.72 47.53 148.19 0.00 1 0.00 1 0 22 9.847e-03 9.631e-03 1.408e-03 1.403e-03 1.685233e+04 9.453032e+01 1.104946e+03 -6.000000e+00 5.174367e+02 285.97 -2.00 20.00 -2.00 505.44 0.00e+00 2.906285e-03 3.829423e-05 1.687912e-04 -6.000000e+00 2.714925e-04 285.97 -2.00 20.00 -2.00 501.04 0.00e+00 1.509826e+00 2.626567e-02 1.098129e-01 -6.000000e+00 1.886903e-01 233.00 -2.00 3.57 -2.00 502.54 0.00e+00 18.829 0.130 489.00 513.00 1 4.8617e+00 2.0066e-03 3.3680e-02 -6.0000e+00 1.4446e-02 -4.7296e-02 5.1057e-04 3.2049e-03 -6.0000e+00 3.7914e-03 9.1503e-04 3.1014e-04 9.7894e-05 1.3114e-04 -6.0000e+00 7.6343e-04 4.1707e-03 -1.3147e-05 12 9 9 12 1 1 99.96 15.00 2.35 0.00417 0.00632 6 4 1 4 0 1572.910 22.19 15.00 19.19 -3290 -2836 -1718 -594 491 818 1228 1318 1538 854 568 -157 -317 -861 -959 -1143 -702 -214 550 634 1081 590 502 557 862 825 1076 776 143 -871 -1628 -1652 -1232 127 782 1186 480 352 -72 -300 -277 -43 457 441 1025 1449 1268 998 705 -207 -587 -1777 -1905 -2017 -1028 -377 778 687 1009 706 681 904 932 1434 1108 346 4 -453 -271 -1062 -1266 -1302 -877 -312 -309 169 -394 -966 -1332 -1348 -1135 -1060 -627 -482 -394 -92 -438 -145 -256 40 28 362 1250 942 1329 874 404 -120 -987 -1567 -1729 -2074 -1102 -374 639 195 -70 -761 -830 -1036 -299 40 792 662 753 1490 1680 1775 1186 711 159 -21 -37 33 656 865 776 423 585 704 634 88 -418 -927 -1203 -743 -232 151 366 641 419 429 273 616 846 357 60 -1072 -1539 -1678 -1746 -2880 -2503 -1554 -529 448 761 1167 1276 1494 828 543 -149 -299 -804 -889 -1061 -656 -205 542 609 1034 568 485 540 844 815 1060 766 140 -826 -1580 -1604 -1154 122 787 1213 490 355 -72 -299 -276 -43 464 436 1024 1456 1277 999 698 -203 -587 -1743 -1837 -1947 -1013 -368 778 699 1024 716 690 923 962 1479 1144 355 4 -454 -268 -1049 -1234 -1270 -863 -310 -314 171 -393 -944 -1290 -1297 -1089 -1025 -610 -471 -392 -92 -445 -146 -256 39 28 365 1278 971 1329 842 375 -113 -923 -1449 -1582 -1931 -1062 -366 629 198 -71 -767 -824 -1039 -305 42 822 690 785 1546 1772 1842 1254 747 164 -22 -38 35 688 911 789 434 596 721 652 88 -434 -967 -1261 -756 -243 161 395 703 449 465 299 676 927 392 65 -1154 -1628 -1771 -1871 SO 20180706T095825.5Z 6761.415573 255 1 33.00 2 88.44 59.48 47.12 149.55 0.00 1 0.00 1 0 22 7.938e-03 7.782e-03 1.324e-03 1.318e-03 1.326042e+04 8.773249e+01 8.720487e+02 -6.000000e+00 4.171598e+02 285.97 -2.00 20.00 -2.00 505.44 0.00e+00 2.451644e-03 3.561804e-05 1.425512e-04 -6.000000e+00 2.188547e-04 285.97 -2.00 20.00 -2.00 500.96 0.00e+00 1.439450e+00 2.459611e-02 8.981293e-02 -6.000000e+00 1.520647e-01 233.00 -2.00 3.57 -2.00 502.48 0.00e+00 17.137 0.098 489.00 513.00 1 5.8838e+00 1.8762e-03 2.8925e-02 -6.0000e+00 1.1642e-02 -2.2984e-02 4.7861e-04 2.6383e-03 -6.0000e+00 3.0543e-03 4.2371e-04 -2.8148e-04 9.4468e-05 1.0076e-04 -6.0000e+00 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