File name: Pandora103s1_Downsview_20180711_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010709.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180711_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180711 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180711T095322.0Z 6766.412060 314 1 32.01 2 89.78 58.88 74.90 77.62 0.00 1 0.00 1 0 15 3.802e-02 3.718e-02 3.781e-02 3.750e-02 4.390429e+03 2.317956e+03 3.575920e+02 -6.000000e+00 2.001820e+03 286.43 -2.00 20.00 -2.00 505.32 0.00e+00 2.431746e-03 1.014119e-03 5.980580e-05 -6.000000e+00 1.049898e-03 286.43 -2.00 20.00 -2.00 500.28 0.00e+00 1.807655e+00 7.314006e-01 2.274241e-02 -6.000000e+00 7.312448e-01 233.03 -2.00 3.57 -2.00 501.91 0.00e+00 20.007 0.156 489.00 513.00 1 9.0992e+00 5.5962e-02 3.5700e-02 -6.0000e+00 5.5939e-02 1.0909e-01 1.4575e-02 2.0410e-03 -6.0000e+00 1.4778e-02 1.1216e-05 -8.4034e-04 2.8041e-03 4.0290e-05 -6.0000e+00 2.9545e-03 1.8816e-02 -2.0119e-04 12 8 8 10 0 0 -6.69 14.99 3.56 0.01882 0.01299 8 1 1 4 0 4000.000 22.19 14.99 19.30 900000 -3624 -6577 -5025 -5044 251 -3849 386 -104 -2120 3282 3081 -6089 -3045 -3963 -1331 1410 6820 608 -1318 -2039 7334 126 -5182 4199 496 2599 -1019 5250 -3210 -365 -396 -1243 -7 694 2984 3154 4641 -3355 -1393 3633 1932 -3444 361 2693 4613 -1140 1973 78 -2699 -1515 652 -3377 3938 -2141 5972 430 5065 2331 3961 -2691 1047 3818 5830 2551 -940 -296 431 -161 -495 1732 -3529 30 -3346 1628 -3265 -3711 -90 310 -11873 -808 4742 1550 5153 11476 1166 1393 -1733 9720 -768 3251 4420 -2553 4604 -3065 6186 1614 2744 -5320 4483 6329 -1132 -6688 -1891 -1956 4047 -5710 -667 -853 -1956 2630 1691 7294 -554 5522 -5776 1739 -344 3527 -5204 -432 -2378 3238 -659 2276 -5210 6943 -3099 8496 -2343 -4592 -1843 -806 -244 2426 -2774 -4539 -2311 -5924 -938 -2293 7920 -532 471 -3655 4281 186 -1126 -3783 -1512 -506 900000 -3483 -6693 -5258 -5459 263 -4288 420 -114 -2353 3386 3140 -6697 -3192 -4138 -1350 1402 6561 642 -1454 -2267 7433 137 -5926 4415 545 2786 -1127 5395 -3441 -365 -393 -1258 -7 747 3210 3357 4789 -3693 -1484 3668 1993 -3787 387 2866 4858 -1269 2105 84 -2911 -1564 637 -3353 3618 -2129 5714 449 5130 2427 4029 -2902 1094 3912 5864 2638 -991 -304 431 -160 -489 1640 -3499 29 -3381 1596 -3371 -3769 -85 290 -12413 -757 4239 1440 4634 9805 1116 1333 -1704 8498 -741 3024 4104 -2592 4424 -3146 5670 1511 2472 -5042 3765 5118 -987 -6315 -1786 -1934 3817 -5848 -638 -801 -1852 2426 1607 6666 -552 5217 -6102 1719 -351 3463 -5476 -425 -2340 2968 -630 2144 -5292 6265 -3083 7503 -2304 -4633 -1779 -751 -223 2140 -2589 -4431 -2264 -6085 -929 -2322 7274 -533 470 -3810 4125 184 -1094 -3655 -1409 -471 SO 20180711T095744.0Z 6766.415093 318 1 32.01 2 89.10 59.63 74.16 78.29 0.00 1 0.00 1 0 22 1.846e-02 1.820e-02 1.434e-02 1.427e-02 1.388420e+04 9.829194e+02 8.773417e+02 -6.000000e+00 9.716583e+02 286.43 -2.00 20.00 -2.00 505.45 0.00e+00 1.489442e-03 3.875365e-04 7.515850e-05 -6.000000e+00 5.096513e-04 286.43 -2.00 20.00 -2.00 500.80 0.00e+00 1.570798e+00 2.708495e-01 9.692027e-02 -6.000000e+00 3.545990e-01 233.03 -2.00 3.57 -2.00 502.35 0.00e+00 18.761 0.129 489.00 513.00 1 8.2898e+00 2.0708e-02 3.2995e-02 -6.0000e+00 2.7131e-02 2.2160e-02 5.2729e-03 2.8878e-03 -6.0000e+00 7.1595e-03 3.0507e-05 2.6764e-03 1.0211e-03 8.3228e-05 -6.0000e+00 1.4335e-03 -2.7577e-03 -4.3655e-06 12 8 8 10 0 0 47.42 15.00 2.91 -0.00276 0.01581 8 1 1 4 0 4000.000 22.19 15.00 19.30 900000 -5957 -2161 -3054 -445 -1617 -278 820 2091 1350 -1774 -1737 174 -873 -1531 -309 -175 1324 -476 1994 -2891 1952 -659 436 -792 2047 -287 2976 78 -602 -2045 -1496 1675 1769 -17 269 1932 -811 -243 -710 605 -416 637 -102 2124 2673 3448 488 -1131 549 862 -382 -1198 -1911 -865 935 192 1689 655 -491 555 2608 2760 504 1618 1786 -3653 -405 -1465 -1326 -2972 201 542 1127 1181 -757 3196 1346 152 1072 -2818 -5230 27 -3148 24 -1982 229 -1578 3348 1094 2858 992 2345 1448 830 -893 240 2916 -759 -3246 -3986 834 -347 698 762 -487 220 708 -874 1133 -4590 3559 -2186 61 1794 4067 761 1028 710 402 -894 -510 -2064 4310 750 -1033 1848 -3601 205 -779 2557 -2253 -1381 146 1115 -1661 1829 1386 134 -1245 -741 -350 2026 -744 -999 -1630 1195 -518 3 -2713 -1525 900000 -5411 -1958 -2916 -427 -1598 -278 824 2082 1340 -1781 -1725 168 -835 -1460 -291 -166 1275 -483 2016 -3061 1976 -684 449 -833 2105 -301 3014 80 -594 -1983 -1443 1593 1750 -17 287 2000 -850 -250 -726 610 -427 656 -107 2215 2790 3564 513 -1189 556 843 -367 -1137 -1829 -843 933 199 1743 683 -514 573 2662 2834 530 1672 1816 -3836 -406 -1470 -1311 -2940 193 525 1102 1175 -766 3039 1270 143 995 -2710 -5195 25 -3109 24 -1994 226 -1575 3157 1049 2704 969 2308 1440 808 -851 218 2499 -660 -2837 -3469 703 -308 655 753 -495 221 695 -857 1096 -4787 3487 -2277 63 1803 4004 786 1081 753 421 -927 -513 -2072 4100 749 -1052 1837 -3773 206 -794 2524 -2274 -1356 141 1064 -1657 1820 1411 140 -1338 -802 -379 2165 -820 -1104 -1804 1268 -545 3 -2837 -1598 SO 20180711T100139.8Z 6766.417822 322 1 11.62 2 88.49 60.30 73.48 78.90 0.00 1 0.00 1 0 22 1.067e-02 1.044e-02 9.880e-04 9.833e-04 1.573542e+04 6.584080e+01 1.023440e+03 -6.000000e+00 5.613825e+02 286.43 -2.00 20.00 -2.00 505.46 0.00e+00 2.606379e-03 2.674155e-05 1.488861e-04 -6.000000e+00 2.944123e-04 286.43 -2.00 20.00 -2.00 501.07 0.00e+00 1.618909e+00 1.832998e-02 1.044517e-01 -6.000000e+00 2.044209e-01 233.03 -2.00 3.57 -2.00 502.57 0.00e+00 17.250 0.100 489.00 513.00 1 4.5034e+00 1.3993e-03 2.9564e-02 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