File name: Pandora103s1_Downsview_20180712_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T005651.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180712_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180712 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180712T095409.0Z 6767.412604 327 1 32.01 2 89.78 59.08 84.57 67.30 0.00 1 0.00 1 0 8 6.801e-02 6.628e-02 6.091e-02 6.003e-02 9.891158e+02 3.450833e+03 1.892109e+02 -6.000000e+00 3.581404e+03 286.52 -2.00 20.00 -2.00 505.35 0.00e+00 5.445085e-03 1.625936e-03 2.466439e-04 -6.000000e+00 1.878298e-03 286.52 -2.00 20.00 -2.00 500.28 0.00e+00 4.702931e+00 1.170076e+00 4.277983e-02 -6.000000e+00 1.306414e+00 233.03 -2.00 3.57 -2.00 501.90 0.00e+00 20.005 0.156 489.00 513.00 1 9.3288e+00 8.9259e-02 3.6258e-02 -6.0000e+00 9.9962e-02 5.5842e-02 2.3386e-02 2.0216e-03 -6.0000e+00 2.6374e-02 6.9026e-06 -9.0541e-04 4.5695e-03 6.6648e-05 -6.0000e+00 5.2820e-03 -2.7657e-02 1.5375e-04 12 8 8 10 0 0 1.56 14.99 6.05 -0.02766 -0.03394 8 1 1 4 0 4000.000 22.19 14.99 19.27 900000 -10067 -2445 3109 -2962 -537 -627 -1394 9046 2812 -5990 4261 -6812 7169 -6481 15125 -3690 849 4567 6597 -806 15389 -5211 -2738 2878 -4132 3715 2706 -5557 1758 -505 -11938 -684 1108 8979 484 3494 -3892 17362 -4903 12971 -229 8425 -11274 2066 4245 -11491 -4524 -6085 -1424 -6164 6168 -7709 -5403 3090 6935 -7540 3510 589 5882 1144 5512 -192 5147 5479 6709 5034 19195 -1288 6828 416 -12494 -5510 -3371 -2363 7381 2974 -11783 10999 -6526 7209 -755 8657 -9872 12048 8126 4846 -4725 3102 -7125 -18 -2959 2029 -494 3982 894 2002 9639 1236 9230 -6653 -3020 -398 2567 -13004 10358 -6755 -2892 -7227 895 -4955 -1169 5782 6898 1121 3238 -2291 12907 4730 721 4420 5235 898 -4976 5374 -1072 16007 -4577 2014 -9153 1301 -12041 -9979 -576 -2123 -10662 8119 -6518 1361 -1017 -4938 -5545 -1886 14111 -2632 4835 -882 10466 -1559 8589 5321 900000 -10266 -2387 3006 -3144 -568 -678 -1545 9095 2973 -6752 4283 -7525 6791 -6926 13061 -3851 865 4633 6717 -881 14356 -5937 -3050 3066 -4754 3955 2900 -6367 1801 -508 -13324 -692 1139 8969 536 3722 -4382 15699 -5436 12065 -244 8372 -13767 2251 4567 -14404 -5240 -7044 -1545 -6786 5824 -8150 -5556 2987 6723 -8682 3684 636 5989 1213 5627 -208 5310 5600 6673 4980 16234 -1314 6342 403 -13635 -5653 -3427 -2416 6876 2827 -12565 9261 -6465 6230 -710 7465 -10181 10112 7152 4401 -4682 2829 -7157 -17 -2889 1933 -491 3776 859 1873 8172 1104 7406 -6092 -2669 -350 2286 -13944 8869 -6708 -2708 -6938 796 -4772 -1112 5250 6303 1094 3111 -2339 11442 4519 704 4094 4737 839 -4970 4928 -1049 13305 -4652 1914 -9745 1256 -13016 -10335 -536 -1986 -10905 7119 -6760 1325 -1025 -5210 -5886 -1939 12528 -2765 4722 -897 9230 -1497 7385 4782 SO 20180712T095829.1Z 6767.415614 331 1 32.15 2 89.10 59.83 83.87 67.98 0.00 1 0.00 1 0 15 3.209e-02 3.131e-02 2.766e-02 2.747e-02 6.956330e+03 1.764574e+03 3.670677e+02 -6.000000e+00 1.689739e+03 286.52 -2.00 20.00 -2.00 505.38 0.00e+00 2.686155e-03 7.452432e-04 1.300227e-04 -6.000000e+00 8.861524e-04 286.52 -2.00 20.00 -2.00 500.49 0.00e+00 2.677480e+00 5.304610e-01 7.030074e-02 -6.000000e+00 6.161695e-01 233.03 -2.00 3.57 -2.00 502.09 0.00e+00 18.768 0.129 489.00 513.00 1 8.8787e+00 4.0569e-02 3.2590e-02 -6.0000e+00 4.7149e-02 5.0558e-02 1.0460e-02 2.2363e-03 -6.0000e+00 1.2436e-02 1.5460e-05 -3.1421e-04 2.0437e-03 4.7234e-05 -6.0000e+00 2.4914e-03 -2.6187e-02 1.6226e-04 12 8 8 10 0 0 -13.64 15.00 3.08 -0.02619 -0.02837 8 1 1 4 0 4000.000 22.29 15.00 19.27 900000 -932 -5961 1792 -3600 -3329 777 -1092 1797 -4955 4348 -4157 -3211 -3701 -361 -3896 536 1427 -5278 6 5776 270 3912 1686 1049 -1152 -312 175 -3007 4347 695 301 -2798 1102 -899 344 78 4745 -3283 3490 2545 8855 368 5122 -834 -154 153 -1233 1817 1086 1358 -5045 -494 -2943 3944 547 -2081 -534 829 1797 4716 -648 4568 -1864 3724 -3030 -549 -2943 1606 2862 -1827 2960 -552 5825 -1427 957 -3294 -838 -3471 1140 -349 -1090 2934 3927 546 2455 1308 10309 -2304 -1212 2352 -2187 -1875 3556 -18 2830 -1928 -7438 5702 -3176 7610 -2245 3473 -3253 1221 3952 -590 -3348 -1291 -582 -65 -1212 2216 -535 3278 1792 2538 472 -4611 -1016 -781 1250 -4892 3713 -1254 4778 -2245 -1652 -1846 5750 -607 2509 -1542 4529 -4579 -2166 -6483 1032 -789 -1642 682 3161 -86 -3816 1281 -2965 7712 -4739 833 -5009 1196 900000 -844 -5843 1703 -3725 -3501 804 -1170 1880 -5481 4307 -4414 -3337 -3795 -355 -3951 525 1416 -5784 6 5822 287 4012 1768 1118 -1263 -338 188 -3286 4245 677 293 -2844 1117 -974 375 85 4834 -3570 3509 2575 8481 387 5222 -913 -169 167 -1349 1901 1121 1355 -5181 -475 -2887 3702 553 -2226 -571 875 1865 4732 -689 4651 -2022 3807 -3258 -565 -3043 1573 2731 -1792 2763 -537 5406 -1447 949 -3327 -804 -3371 1050 -326 -1033 2691 3577 520 2325 1254 9014 -2261 -1173 2202 -2164 -1891 3442 -18 2644 -1836 -7256 4770 -2828 5997 -1960 2957 -3116 1172 3737 -577 -3298 -1224 -549 -62 -1198 2148 -538 3183 1770 2514 483 -4968 -1041 -783 1203 -4922 3460 -1244 4482 -2259 -1654 -1841 5350 -603 2368 -1480 4057 -4453 -2080 -6694 1014 -799 -1699 697 3163 -89 -4136 1326 -3191 7367 -4966 804 -5068 1153 SO 20180712T100228.8Z 6767.418389 335 1 19.66 2 88.48 60.51 83.23 68.61 0.00 1 0.00 1 0 29 1.381e-02 1.354e-02 9.374e-04 9.327e-04 1.518446e+04 6.209282e+01 9.950421e+02 -6.000000e+00 7.271500e+02 286.52 -2.00 20.00 -2.00 505.45 0.00e+00 2.965921e-03 2.535768e-05 1.621540e-04 -6.000000e+00 3.813208e-04 286.52 -2.00 20.00 -2.00 501.15 0.00e+00 1.545942e+00 1.738408e-02 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