File name: Pandora103s1_Downsview_20180713_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010623.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180713_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180713 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180713T095458.0Z 6768.413171 332 1 32.01 2 89.78 59.30 94.66 57.41 0.00 1 0.00 1 0 36 2.039e-01 1.759e-01 1.814e-01 1.680e-01 -4.366241e+03 9.233655e+03 6.522356e+02 -6.000000e+00 1.074023e+04 286.61 -2.00 20.00 -2.00 505.05 0.00e+00 6.256172e-03 4.531855e-03 2.188724e-04 -6.000000e+00 5.642517e-03 286.61 -2.00 20.00 -2.00 500.00 0.00e+00 1.314110e-01 3.387623e+00 2.891738e-02 -6.000000e+00 3.950127e+00 233.04 -2.00 3.57 -2.00 501.60 0.00e+00 20.001 0.156 489.00 513.00 1 1.0714e+01 2.5902e-01 3.6018e-02 -6.0000e+00 3.0180e-01 2.0540e-01 6.9556e-02 2.0105e-03 -6.0000e+00 8.0367e-02 2.3409e-06 -4.3153e-02 1.2465e-02 9.0647e-05 -6.0000e+00 1.5911e-02 -4.1304e-02 4.0369e-04 12 8 8 10 0 0 2.69 15.00 11.68 -0.04130 -0.34063 8 1 1 4 0 4000.000 22.19 15.00 19.32 81596 3180 3391 -17226 15730 -11598 11742 -5769 54 2104 9404 -11976 -3233 -9425 -8236 5413 30088 19425 23241 -27766 68736 -18307 828 -12891 -29595 8706 9757 -426 17213 29378 19590 20063 20860 15941 -10330 1856 1083 23161 -6845 20037 1446 8170 -2811 19752 30741 25612 -546 -18101 11555 -17758 37215 -2380 20523 -26343 25963 13658 12429 -5616 9496 -2369 8794 -10390 1883 11295 14109 8650 859 15745 -5535 -8682 -23490 -5620 9788 1609 14468 -2571 -11799 -14601 21128 25931 -37069 9124 -5411 9509 -4197 -5643 -3970 12853 15697 19517 38166 -2325 -22433 -7793 4886 -3665 15612 1440 35256 -14334 17345 -14185 -10635 39800 2147 27292 24244 -15594 18624 -5824 16369 -15402 38865 -79 9641 12783 -31065 3452 -20933 8073 -4403 55059 18715 18557 12133 11621 -9126 21590 14498 26391 -12852 23086 29135 14530 -3480 41044 5491 9327 32783 -5765 2602 -18133 -14011 -7257 36419 23787 39038 -28031 -18065 -10807 900000 41795 3236 3310 -20449 13932 -13884 11659 -6905 63 2416 10106 -15675 -3803 -11530 -9812 5550 23963 16999 19644 -38807 39254 -24631 928 -16364 -44047 8960 10003 -486 16570 25060 18138 17844 17587 13856 -11612 1905 1173 20870 -8174 18178 1547 8082 -3074 17514 24857 22052 -613 -24363 11709 -23636 28822 -2646 17830 -34682 20181 11819 11047 -6161 9344 -2660 8891 -12558 2010 11041 13541 8772 936 14678 -6203 -9843 -30330 -6043 8900 1565 12507 -2644 -13489 -17265 17457 19913 -51166 8042 -5469 8387 -4254 -5792 -4023 11196 13332 15923 25953 -2325 -27302 -8306 4714 -3937 14077 1480 26101 -16821 14592 -15605 -10999 25222 1968 20255 19076 -17939 15080 -5811 12943 -16440 25176 -76 8661 11406 -42824 3435 -26391 7693 -4674 32483 15308 15001 10319 9978 -9687 17096 12256 19893 -14005 17858 21346 12065 -3345 25230 4642 7550 21636 -5637 2381 -20373 -15164 -7323 24155 17891 25545 -34808 -20078 -10824 900000 SO 20180713T095919.0Z 6768.416192 336 1 32.01 2 89.10 60.05 94.03 58.16 0.00 1 0.00 1 0 36 1.053e-01 9.899e-02 9.411e-02 9.160e-02 3.735204e+03 5.718044e+03 3.656245e+02 -6.000000e+00 5.546494e+03 286.61 -2.00 20.00 -2.00 505.25 0.00e+00 4.313894e-03 2.504213e-03 8.192729e-05 -6.000000e+00 2.913928e-03 286.61 -2.00 20.00 -2.00 500.04 0.00e+00 3.435088e+00 1.836897e+00 4.413180e-02 -6.000000e+00 2.040761e+00 233.04 -2.00 3.57 -2.00 501.68 0.00e+00 18.755 0.128 489.00 513.00 1 1.0041e+01 1.4105e-01 3.2180e-02 -6.0000e+00 1.5590e-01 8.7852e-02 3.6850e-02 2.0067e-03 -6.0000e+00 4.1546e-02 4.4436e-06 -1.6819e-02 6.9572e-03 4.2078e-05 -6.0000e+00 8.2166e-03 -1.5133e-02 2.0278e-04 12 8 8 10 0 0 -3.40 14.99 4.19 -0.01513 -0.13180 8 1 1 4 0 4000.000 22.19 14.99 19.32 17060 -18853 -2957 4445 9124 -16574 -11417 -4011 8199 15625 -8315 1316 7051 21368 657 -7522 11198 -4475 -1161 9615 -15203 9990 2553 -624 15079 1694 11491 5204 1072 -4662 914 7532 4660 -7457 2713 8451 -5621 -3931 -3234 3483 -5879 -14279 -9052 -8694 31525 399 2537 2390 -1163 7667 5865 -12624 7612 13063 -2370 16884 10984 3300 -8147 -7732 5661 6097 7565 9312 441 4646 11534 12111 -1695 7659 -12113 -13344 -6787 -4281 -972 12337 -652 13543 -683 -9632 -16129 -10754 1445 -10948 15846 -7940 18425 22643 -12504 -6796 4453 8005 10330 -5862 9247 -16 16447 -857 17499 -9400 352 -16099 -959 13597 4820 -15073 24440 5118 -3155 4712 -8054 -9323 21656 -1020 -120 5100 2658 193 -6965 5957 7043 4557 3076 18434 -5332 -12032 -3524 26638 27383 13850 -15400 -8307 3471 -8711 1044 -8193 2870 -3487 11247 -10429 9787 -6331 -7186 10295 9475 9401 2512 7519 -7988 -15222 900000 14000 -21449 -2921 4231 8665 -20766 -13868 -4634 8528 15130 -10012 1413 7070 18369 678 -8320 10311 -4844 -1245 9603 -19630 10086 2762 -696 14477 1871 11598 5565 1188 -5349 950 7102 4515 -8242 2825 8705 -6709 -4547 -3661 3646 -6661 -17525 -10672 -10337 25783 447 2801 2631 -1307 7785 5927 -14751 7087 11319 -2380 14494 10378 3452 -9626 -9064 5781 6180 7606 9251 477 4789 10926 11163 -1755 7171 -13498 -14786 -7043 -4370 -973 11039 -659 11606 -655 -9936 -17598 -11130 1339 -11477 12840 -8180 14838 17480 -13461 -6872 4030 7019 8978 -6097 8391 -16 13436 -808 13449 -9105 302 -15937 -826 10483 4240 -16608 18370 4559 -2980 4063 -7913 -9482 16670 -993 -117 4759 2548 192 -7450 5590 6423 4178 2808 14374 -5290 -12890 -3479 19701 20080 11518 -17094 -8598 3135 -8666 934 -7953 2536 -3376 9638 -11148 8708 -6618 -7581 9221 8609 8573 2438 6815 -8139 -16179 900000 SO 20180713T100334.1Z 6768.419144 340 1 32.15 2 88.43 60.77 93.40 58.89 0.00 1 0.00 1 0 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