File name: Pandora103s1_Downsview_20180714_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010631.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180714_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180714 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180714T095549.0Z 6769.413762 331 1 32.01 2 89.77 59.52 104.74 47.47 0.00 1 0.00 1 0 61 2.310e-01 1.854e-01 1.999e-01 1.808e-01 2.120237e+04 1.430087e+04 9.019789e+02 -6.000000e+00 1.217499e+04 286.70 -2.00 20.00 -2.00 505.52 0.00e+00 3.362329e-04 4.758218e-03 1.820966e-04 -6.000000e+00 6.381377e-03 286.70 -2.00 20.00 -2.00 500.14 0.00e+00 4.289550e+00 3.577158e+00 2.342514e-01 -6.000000e+00 4.423003e+00 233.04 -2.00 3.57 -2.00 501.85 0.00e+00 19.994 0.156 489.00 513.00 1 1.0511e+01 2.6940e-01 4.0098e-02 -6.0000e+00 3.3875e-01 1.7531e-02 6.9678e-02 4.8291e-03 -6.0000e+00 8.8812e-02 2.1608e-06 6.5524e-03 1.1838e-02 6.6970e-05 -6.0000e+00 1.7901e-02 -5.7201e-02 4.0268e-04 12 8 8 10 0 0 -5.59 15.00 12.85 -0.05720 -0.01175 8 1 1 4 0 4000.000 22.40 15.00 19.52 390 17042 -9140 -24843 1916 22733 -9208 3934 38161 -6129 15219 -9618 859 20813 7226 5364 10050 698 -10752 -25031 -6404 5054 12653 -6615 9549 5552 762 -12861 -18222 -3108 -20480 25538 18536 -4611 7159 6965 19836 -4074 -946 66907 27665 29465 -28555 -682 10038 40229 10054 33333 504 53260 -4998 -8934 9758 4593 2297 -18071 -8152 4738 -732 -6240 12008 -2555 6442 -10426 7428 -2810 7300 -33265 27214 -23746 8293 -4592 37888 10777 33639 30764 39367 78583 16291 33159 45171 1149 -11200 48116 20753 9194 -5975 36353 -13611 39344 -13556 47 -6253 23013 -24642 10598 8792 -4771 828 28927 23409 16335 26061 -7864 20566 21673 -30799 -6871 16091 -5191 40973 -20858 33170 -13956 72738 10664 35406 -9148 3847 -8979 4986 -4404 9378 -10007 -7263 -5102 -4258 -4473 -24988 15103 -15138 11308 7551 -7451 29536 -26943 -25685 11898 -15891 27946 -7240 21631 37218 -5731 11578 -7158 -3983 52509 41568 -10915 66326 360 13670 -9771 -32226 1971 19561 -11013 4202 29433 -7121 14183 -11265 897 17700 6954 5274 9585 750 -13355 -36174 -7725 5473 12735 -8041 10032 6067 868 -16623 -24200 -3415 -25984 20964 16613 -5395 7771 7609 18887 -4807 -1069 39182 23534 24800 -42394 -785 10532 31704 10500 27467 558 34816 -5495 -9902 8896 4429 2340 -23242 -9753 5039 -817 -7275 11731 -2891 6714 -12748 7580 -3102 7165 -47472 21547 -30089 7627 -4793 26641 9974 25355 23556 26996 36284 13394 23002 27896 1087 -11984 29543 16831 8406 -6294 25302 -15044 26080 -14939 46 -6608 18109 -29228 8531 6871 -4115 667 17536 14895 11407 17557 -7878 16539 17525 -40863 -7105 13194 -5272 27333 -25321 23987 -15756 35831 9513 25583 -10382 3870 -10037 4742 -4441 8170 -10612 -7599 -5246 -4368 -4594 -31118 12911 -17133 9672 6626 -7568 21236 -34175 -33149 10842 -19185 22662 -8338 19091 28498 -6619 11306 -8315 -4421 33288 28807 -12516 37034 SO 20180714T100010.0Z 6769.416782 335 1 32.01 2 89.09 60.27 104.19 48.32 0.00 1 0.00 1 0 22 1.186e-01 1.114e-01 1.058e-01 1.018e-01 1.980185e+04 7.985013e+03 1.072642e+03 -6.000000e+00 6.247866e+03 286.70 -2.00 20.00 -2.00 505.31 0.00e+00 6.036916e-04 2.828102e-03 8.897486e-05 -6.000000e+00 3.282044e-03 286.70 -2.00 20.00 -2.00 499.85 0.00e+00 2.795773e+00 2.074654e+00 1.387789e-01 -6.000000e+00 2.296804e+00 233.04 -2.00 3.57 -2.00 501.53 0.00e+00 18.742 0.128 489.00 513.00 1 1.0224e+01 1.5925e-01 3.3883e-02 -6.0000e+00 1.7549e-01 8.7113e-02 4.0637e-02 3.4676e-03 -6.0000e+00 4.6720e-02 3.9707e-06 2.8887e-03 6.9749e-03 8.3035e-05 -6.0000e+00 9.2542e-03 -3.3871e-02 3.7437e-04 12 8 8 10 0 0 11.04 15.01 4.73 -0.03387 -0.01383 8 1 1 4 0 4000.000 22.40 15.01 19.53 1166 -5909 -6691 2828 18889 -3690 19954 1042 -9090 -13684 15081 1534 64 -9070 -6330 1148 5043 13568 356 -149 -16573 15020 24243 -3239 -14831 4584 3833 2034 -2891 8447 -8637 10497 -21464 16873 -2353 6167 17999 26547 -4639 -16631 18320 2204 -2429 -7520 -4430 4052 2791 183 5032 3708 -13441 -10597 11440 -1552 30556 -6279 -6080 19778 33782 1150 3205 761 19610 -6280 37799 -4235 4398 11147 -8639 12545 3742 6242 -13872 11607 -20903 2871 -333 -9342 22950 -1408 -12797 -3330 -6355 9543 -165 7940 2139 6945 -4274 -20384 -931 -1026 12387 -708 -3099 -3753 18652 -950 -3827 2706 16810 3858 -11806 7018 15419 6141 28516 -2668 4758 -9260 15619 11279 15715 -8453 9751 14934 -6845 -667 623 -7410 -9260 8725 -14424 3675 9698 8397 -11701 -2465 -11295 -2079 -13649 13114 -6728 5621 18685 -17844 -626 1444 7797 -11510 16801 -6660 -7222 8089 -4677 9195 20619 -11805 8894 11868 900000 1108 -6111 -7226 2905 17036 -4217 18562 1179 -11343 -17596 14414 1654 69 -10494 -7074 1195 5122 13057 402 -172 -22328 14923 22005 -3844 -19849 5088 4264 2290 -3330 8333 -9791 9924 -28171 15972 -2788 6762 17342 23202 -5402 -21489 16876 2386 -2779 -9149 -5288 4465 3093 205 5284 3844 -15856 -11793 10111 -1562 23303 -7094 -7022 17904 26600 1229 3349 820 17683 -7255 28274 -4662 4357 10187 -9458 11004 3521 5746 -15664 10415 -26018 2809 -327 -9737 17296 -1328 -13437 -3214 -6346 8246 -159 7162 2034 6239 -4219 -23336 -886 -992 10672 -683 -2932 -3399 13001 -774 -3152 2054 11077 2945 -11054 5889 12559 5554 20635 -2554 4177 -9392 12701 9649 12864 -8697 8368 12229 -7071 -665 615 -7767 -9601 7368 -14973 3234 8148 7155 -12151 -2338 -11594 -1964 -14293 10314 -6319 4687 13798 -19207 -587 1343 6911 -12533 14100 -7065 -7745 7483 -4877 8328 16460 -12568 7619 9884 900000 SO 20180714T100422.0Z 6769.419699 339 1 32.01 2 88.43 60.99 103.65 49.13 0.00 1 0.00 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