File name: Pandora103s1_Downsview_20180717_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010742.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180717_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180717 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180717T095824.0Z 6772.415556 335 1 32.01 2 89.77 60.25 130.43 11.61 0.00 1 0.00 1 0 22 7.620e-02 7.401e-02 7.139e-02 7.024e-02 9.813900e+03 4.667563e+03 9.059158e+02 -6.000000e+00 4.019499e+03 286.87 -2.00 20.00 -2.00 505.32 0.00e+00 3.003415e-03 1.904894e-03 2.289381e-04 -6.000000e+00 2.106832e-03 286.87 -2.00 20.00 -2.00 500.43 0.00e+00 1.339701e+00 1.364905e+00 3.505226e-02 -6.000000e+00 1.464629e+00 233.00 -2.00 3.57 -2.00 502.01 0.00e+00 19.992 0.156 489.00 513.00 1 9.7591e+00 1.0447e-01 3.6085e-02 -6.0000e+00 1.1207e-01 9.1537e-02 2.7141e-02 2.1826e-03 -6.0000e+00 2.9580e-02 5.8664e-06 -1.5296e-03 5.1676e-03 1.0840e-04 -6.0000e+00 5.9213e-03 -7.0852e-02 3.8261e-04 12 8 8 10 0 0 6.93 15.00 4.23 -0.07085 -0.08146 8 1 1 4 0 4000.000 22.19 15.00 19.30 900000 2744 -9713 4404 3103 10575 4750 6831 -105 11698 -6244 -10864 5725 7074 5516 681 120 989 -853 -2482 8710 -3070 -3558 -3509 10665 -13020 944 -6665 2502 -598 9398 6550 723 -6535 634 -2024 -705 -2413 4028 5710 -110 8076 -333 -5128 -5436 3589 -4663 5671 -5271 13503 420 718 -12153 6036 -7484 416 1193 -2970 3369 -7761 12308 -741 8681 -16955 15568 -14295 10778 -5612 20894 164 10481 -5983 3114 -1712 -1595 4578 42 -11779 1445 17263 -426 2942 -1631 42 7775 -2929 -5275 3117 6418 -11 -9954 1757 -4987 13360 -2209 10559 -4696 -97 -2366 -4976 7566 -1086 -2670 -2419 2991 -3907 11503 -6257 27077 -8311 6939 -7175 9720 -8295 -1148 -3132 -328 -2894 -7615 -13535 10593 11231 -4923 982 484 9454 5370 3209 -7721 13712 5145 359 -7363 2378 -8015 -5334 7244 3423 20015 13574 462 2346 258 6599 -694 5992 -16657 2732 631 569 -808 900000 2427 -9955 4109 3038 9823 4771 6849 -113 11172 -6957 -12470 5525 6617 5171 666 118 988 -897 -2721 8589 -3388 -3943 -3888 10375 -16072 1016 -7691 2612 -620 8475 6012 710 -7093 673 -2263 -773 -2646 4096 5639 -115 7801 -354 -5776 -6234 3807 -5360 5840 -5945 12467 428 704 -13189 5451 -7849 421 1239 -3269 3495 -8909 11561 -794 8555 -21479 14336 -17356 10057 -6025 17170 163 9245 -6155 2954 -1724 -1634 4441 42 -12773 1356 13787 -402 2705 -1580 40 6972 -2956 -5464 2962 5857 -10 -10587 1685 -5216 11854 -2248 9205 -4597 -88 -2138 -4507 5955 -932 -2394 -2280 2820 -4019 10129 -6433 19765 -8528 6260 -7572 8815 -9022 -1168 -3250 -334 -3075 -8523 -15845 9608 9888 -4965 937 471 8467 5008 3062 -8140 11755 4812 345 -7445 2164 -8019 -5236 6476 3251 16362 11975 468 2344 264 6389 -723 5830 -19928 2636 604 538 -781 SO 20180717T100237.8Z 6772.418493 339 1 7.56 2 89.11 60.97 130.29 12.91 0.00 1 0.00 1 0 29 1.592e-02 1.550e-02 2.131e-03 2.119e-03 1.979976e+04 1.464355e+02 1.294620e+03 -6.000000e+00 8.391193e+02 286.87 -2.00 20.00 -2.00 505.49 0.00e+00 3.583618e-03 5.816942e-05 1.936016e-04 -6.000000e+00 4.398597e-04 286.87 -2.00 20.00 -2.00 501.14 0.00e+00 1.731905e+00 3.958139e-02 1.233764e-01 -6.000000e+00 3.052681e-01 233.00 -2.00 3.57 -2.00 502.64 0.00e+00 18.774 0.129 489.00 513.00 1 5.1384e+00 3.0260e-03 3.3985e-02 -6.0000e+00 2.3373e-02 -7.7602e-02 7.6456e-04 3.5250e-03 -6.0000e+00 6.1434e-03 6.7792e-04 2.3182e-03 1.4396e-04 1.4668e-04 -6.0000e+00 1.2350e-03 9.0753e-02 -6.3926e-04 12 9 9 12 1 1 82.56 15.00 5.42 0.09075 0.10683 3 4 1 4 0 1846.840 22.19 15.00 19.30 -5650 -4468 -3177 -1067 -53 1212 1592 2003 1936 1227 189 -579 -1277 -1851 -1983 -2172 -1067 83 911 1178 1085 1098 897 1227 1603 1554 1517 1211 263 -1954 -2838 -2988 -1680 145 1811 1984 1480 79 191 -574 -541 456 1327 1515 1881 2227 1919 1505 900 206 -1137 -2115 -3336 -2887 -1421 96 779 1702 1152 1408 1389 1584 2063 1849 1859 707 266 -348 -803 -1412 -1961 -1886 -1281 -590 149 -126 -751 -1266 -2157 -2074 -1492 -840 -622 -1080 -510 -515 -586 -486 48 -255 130 762 1741 2274 1990 1332 1034 217 -1427 -2383 -3577 -2890 -1658 -142 724 789 315 -900 -1395 -996 -785 301 771 1103 1308 1732 2853 2537 1880 848 230 -613 -361 534 1367 1485 1323 875 660 492 -40 -58 -850 -1879 -2071 -1723 -906 -29 748 974 538 636 455 1045 1292 648 446 -1073 -2762 -2702 -2639 -4859 -3859 -2814 -971 -50 1140 1456 1857 1805 1141 174 -533 -1170 -1682 -1791 -1969 -970 77 866 1142 1054 1068 877 1203 1588 1552 1444 1155 261 -1906 -2707 -2862 -1618 143 1763 1961 1457 78 186 -560 -529 447 1311 1522 1916 2285 1975 1542 916 208 -1124 -2049 -3215 -2777 -1391 97 770 1694 1155 1402 1384 1592 2087 1884 1888 717 265 -345 -795 -1388 -1912 -1839 -1257 -586 150 -127 -745 -1232 -2091 -2091 -1493 -842 -600 -1054 -504 -518 -592 -486 47 -250 128 756 1752 2284 1943 1310 976 199 -1310 -2174 -3263 -2659 -1579 -136 737 789 316 -903 -1388 -995 -803 310 798 1141 1350 1785 2969 2732 1982 894 249 -649 -374 551 1428 1562 1404 938 707 509 -42 -62 -895 -1999 -2217 -1796 -970 -31 814 1080 586 700 507 1162 1434 722 493 -1178 -3022 -2946 -2920 SO 20180717T100655.0Z 6772.421470 343 1 33.95 2 88.43 61.71 130.13 14.23 0.00 1 0.00 1 0 36 1.412e-02 1.383e-02 5.468e-04 5.436e-04 1.795871e+04 3.696396e+01 1.180908e+03 -6.000000e+00 7.445692e+02 286.87 -2.00 20.00 -2.00 505.50 0.00e+00 3.231979e-03 1.488002e-05 1.804585e-04 -6.000000e+00 3.903213e-04 286.87 -2.00 20.00 -2.00 501.20 0.00e+00 1.574048e+00 1.008790e-02 1.157961e-01 -6.000000e+00 2.711400e-01 233.00 -2.00 3.57 -2.00 502.68 0.00e+00 17.101 0.097 489.00 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