File name: Pandora103s1_Downsview_20180718_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010730.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180718_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180718 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180718T095919.0Z 6773.416192 335 1 32.01 2 89.77 60.51 135.77 355.94 0.00 1 0.00 1 0 15 2.264e-02 2.279e-02 1.967e-02 1.955e-02 1.228930e+04 1.352767e+03 7.071412e+02 -6.000000e+00 1.194042e+03 286.89 -2.00 20.00 -2.00 505.39 0.00e+00 2.130680e-03 5.301178e-04 1.003461e-04 -6.000000e+00 6.259534e-04 286.89 -2.00 20.00 -2.00 500.48 0.00e+00 2.169122e+00 3.788052e-01 9.837076e-02 -6.000000e+00 4.349267e-01 232.96 -2.00 3.57 -2.00 502.08 0.00e+00 19.989 0.156 489.00 513.00 1 8.3937e+00 2.8962e-02 3.6539e-02 -6.0000e+00 3.3283e-02 6.1385e-02 7.4376e-03 2.8921e-03 -6.0000e+00 8.7825e-03 2.1962e-05 -2.2920e-03 1.4178e-03 6.6391e-05 -6.0000e+00 1.7589e-03 -1.9192e-02 8.6772e-05 12 8 8 10 0 0 -3.36 14.99 2.92 -0.01919 -0.03509 8 1 1 4 0 4000.000 22.19 14.99 19.22 900000 -2667 -2049 -4604 -345 -5973 1088 -3228 4464 -826 797 -895 1886 -1443 724 -3383 2757 -2440 -1998 2635 -1245 -589 -2142 549 1384 1659 1452 1305 -2219 1922 -2103 -1004 323 1969 326 4835 293 906 -2500 -1042 1146 2254 3581 -683 1050 1337 2656 -809 3058 -3240 531 -658 -856 -1656 -1079 -2682 474 -656 1645 764 6065 1674 3223 4283 1324 1142 402 -190 -3668 2089 1946 -202 -1868 1906 -399 2388 -8252 3240 -2263 -289 -1450 -2975 35 -863 -2600 1643 154 382 997 -222 -57 -433 3291 950 2299 -1542 3193 -483 -1356 45 4250 -2270 -2814 3018 3271 806 1546 -3867 -441 -1665 902 2014 891 -130 1935 1442 -1078 -1063 1709 3762 682 699 -1795 3371 -5123 1382 -712 -1944 40 406 -1133 -2521 -793 -1724 385 -2306 679 -1834 713 3671 2100 -2918 1155 -1612 -1054 -801 1154 -3443 129 -890 -560 900000 -2444 -1919 -4613 -344 -6408 1115 -3515 4541 -878 818 -922 1868 -1450 704 -3412 2637 -2505 -2111 2735 -1345 -632 -2332 583 1468 1769 1549 1389 -2416 1937 -2115 -991 318 1969 347 5057 318 962 -2709 -1099 1177 2302 3654 -736 1128 1445 2835 -884 3170 -3504 537 -651 -829 -1604 -1059 -2784 493 -702 1726 803 6017 1741 3328 4386 1390 1186 412 -193 -3797 2020 1852 -196 -1847 1841 -402 2352 -8828 3015 -2183 -271 -1370 -2869 33 -825 -2559 1575 150 370 951 -213 -55 -420 3145 939 2203 -1481 2826 -428 -1182 38 3376 -1930 -2481 2659 3046 787 1494 -3875 -419 -1597 860 1937 875 -129 1892 1416 -1096 -1102 1742 3717 679 680 -1748 3125 -5236 1333 -702 -1945 39 395 -1125 -2491 -752 -1636 357 -2212 652 -1847 709 3598 2118 -3111 1190 -1715 -1118 -845 1181 -3594 127 -872 -552 SO 20180718T100322.7Z 6773.419012 339 1 11.33 2 89.13 61.21 135.83 357.33 0.00 1 0.00 1 0 22 1.251e-02 1.219e-02 8.148e-04 8.103e-04 1.895621e+04 5.574699e+01 1.220836e+03 -6.000000e+00 6.598348e+02 286.89 -2.00 20.00 -2.00 505.48 0.00e+00 3.160946e-03 2.220751e-05 1.793228e-04 -6.000000e+00 3.458292e-04 286.89 -2.00 20.00 -2.00 501.11 0.00e+00 1.769717e+00 1.514250e-02 1.223864e-01 -6.000000e+00 2.396648e-01 232.96 -2.00 3.57 -2.00 502.61 0.00e+00 18.823 0.130 489.00 513.00 1 3.8777e+00 1.1576e-03 3.4020e-02 -6.0000e+00 1.8355e-02 -6.9543e-02 2.9262e-04 3.4638e-03 -6.0000e+00 4.8163e-03 2.3847e-03 7.5609e-04 5.5442e-05 1.3953e-04 -6.0000e+00 9.7014e-04 -5.3323e-03 3.9461e-05 12 9 9 12 1 1 83.67 15.00 3.99 -0.00533 -0.00009 19 11 1 4 0 558.310 22.19 15.00 19.23 -4244 -3815 -2405 -888 149 661 1250 1604 1407 1021 392 -19 -681 -1331 -1826 -1429 -1133 -246 714 1003 886 871 772 888 1195 1390 1348 1112 454 -1150 -1896 -2220 -1667 -201 1076 1373 928 396 -88 -186 -187 -39 603 1043 1538 1709 1642 1247 747 100 -995 -1895 -2469 -2195 -1371 -80 825 1064 1177 970 809 1226 1347 1409 1152 816 249 -228 -410 -1103 -1362 -1335 -832 -399 45 38 -623 -1246 -1621 -1646 -1533 -1040 -710 -845 -433 -62 -270 -446 -510 -174 -48 493 1362 1817 1629 1156 553 5 -1077 -2183 -2560 -2225 -1617 -129 779 810 -18 -691 -1299 -1071 -437 -9 654 1140 1393 1774 2073 2076 1634 764 212 -368 -281 546 871 829 910 532 539 653 363 -180 -745 -1348 -1543 -1128 -459 80 589 828 624 431 466 919 902 772 69 -1232 -2168 -2417 -2008 -3616 -3282 -2115 -808 139 627 1152 1501 1328 959 364 -18 -625 -1212 -1658 -1294 -1036 -229 683 980 868 855 761 879 1194 1335 1296 1070 434 -1122 -1803 -2119 -1609 -200 1060 1375 925 392 -86 -182 -183 -39 601 1055 1576 1767 1700 1284 763 101 -985 -1837 -2363 -2096 -1340 -81 816 1068 1181 972 811 1237 1373 1442 1179 826 250 -226 -404 -1081 -1380 -1353 -812 -395 45 38 -618 -1212 -1562 -1649 -1530 -1042 -684 -823 -428 -62 -272 -447 -506 -171 -47 490 1376 1836 1601 1142 525 4 -987 -1991 -2315 -2036 -1539 -124 793 812 -19 -694 -1294 -1072 -446 -10 678 1179 1437 1828 2173 2153 1726 806 219 -388 -290 563 912 875 967 548 553 673 376 -191 -780 -1421 -1635 -1166 -488 87 641 917 679 475 518 1022 1004 858 77 -1352 -2352 -2622 -2202 SO 20180718T100739.8Z 6773.421989 343 1 33.66 2 88.45 61.94 135.86 358.80 0.00 1 0.00 1 0 29 9.706e-03 9.538e-03 2.063e-04 2.054e-04 1.713444e+04 1.393322e+01 1.121932e+03 -6.000000e+00 5.117724e+02 286.89 -2.00 20.00 -2.00 505.46 0.00e+00 2.803792e-03 5.620880e-06 1.654432e-04 -6.000000e+00 2.682816e-04 286.89 -2.00 20.00 -2.00 501.11 0.00e+00 1.693612e+00 3.850920e-03 1.096728e-01 -6.000000e+00 1.863660e-01 232.96 -2.00 3.57 -2.00 502.60 0.00e+00 17.155 0.098 489.00 513.00 1 2.4498e+00 2.9431e-04 2.9545e-02 -6.0000e+00 1.4262e-02 -6.2714e-02 7.4920e-05 3.0958e-03 -6.0000e+00 3.7629e-03 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