File name: Pandora103s1_Downsview_20180720_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010740.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180720_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180720 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180720T100110.0Z 6775.417477 339 1 32.01 2 89.77 61.05 138.67 320.70 0.00 1 0.00 1 0 15 2.233e-02 2.223e-02 1.938e-02 1.928e-02 9.098746e+03 1.272937e+03 5.367680e+02 -6.000000e+00 1.177760e+03 286.93 -2.00 20.00 -2.00 505.39 0.00e+00 2.670317e-03 5.221704e-04 1.581270e-04 -6.000000e+00 6.172134e-04 286.93 -2.00 20.00 -2.00 500.54 0.00e+00 2.679432e+00 3.691391e-01 7.888859e-02 -6.000000e+00 4.275799e-01 232.89 -2.00 3.57 -2.00 502.13 0.00e+00 19.987 0.156 489.00 513.00 1 8.3392e+00 2.8239e-02 3.6317e-02 -6.0000e+00 3.2748e-02 4.4623e-02 7.2180e-03 2.5615e-03 -6.0000e+00 8.5909e-03 2.2278e-05 6.3244e-04 1.4184e-03 6.2399e-05 -6.0000e+00 1.7313e-03 -1.1595e-03 2.7508e-05 12 8 8 10 0 0 2.26 14.99 4.00 -0.00116 0.00323 8 1 1 4 0 4000.000 22.09 14.99 19.21 -2854 -4903 466 -2994 2267 2092 787 -1059 -359 3258 -1770 -665 -1721 486 -336 2160 -1031 672 -630 2450 -2388 1117 -2548 926 1175 5675 2386 5916 -1920 -1435 -2520 -4386 -317 -2970 -4 1423 847 1355 4319 1579 -209 -1176 140 -2330 -315 321 4416 -1137 -57 -269 -99 -1636 947 -3001 -639 987 -52 2106 506 2214 -210 1113 -3530 3453 -658 2774 -1963 867 1442 -3411 -1508 -913 2153 1182 -502 469 -1374 -2339 153 850 -848 -2034 1883 -1805 747 -1877 406 -1797 44 -1454 -2318 -3612 3481 1937 1589 -3877 2330 -121 -554 -428 -3924 -1859 -140 3827 1197 139 -1174 1304 -3662 -1146 -2092 4843 -1218 5233 -1190 969 1009 2850 1244 2342 1680 -276 154 911 377 513 270 -738 1766 -1561 -862 -3994 3978 1728 -479 -2718 4556 -2625 1739 -1941 -1084 -261 1778 649 4114 490 1507 -773 -2389 -592 -6206 -2570 -4552 425 -2948 2188 2062 803 -1119 -378 3277 -1833 -674 -1737 472 -325 2043 -1015 666 -655 2525 -2576 1166 -2754 969 1240 5766 2496 5961 -2053 -1463 -2509 -4439 -313 -3126 -4 1526 903 1417 4333 1607 -216 -1237 147 -2545 -343 349 4608 -1237 -60 -280 -100 -1617 895 -2943 -629 996 -54 2193 535 2285 -221 1164 -3889 3558 -702 2817 -2044 864 1416 -3460 -1476 -887 2050 1153 -506 468 -1363 -2281 143 788 -797 -1950 1749 -1744 714 -1863 394 -1773 42 -1413 -2276 -3638 3346 1904 1538 -3835 2105 -108 -488 -368 -3435 -1611 -124 3436 1155 137 -1161 1235 -3579 -1098 -2066 4558 -1230 4997 -1212 969 1021 2879 1279 2345 1658 -272 149 880 371 506 267 -739 1717 -1575 -865 -4042 3651 1608 -454 -2667 4297 -2709 1742 -2046 -1145 -274 1846 685 4210 518 1552 -791 -2420 -585 -6567 SO 20180720T100512.8Z 6775.420287 343 1 13.64 2 89.13 61.75 139.11 321.99 0.00 1 0.00 1 0 29 1.555e-02 1.531e-02 9.648e-04 9.588e-04 1.807129e+04 6.500938e+01 1.187380e+03 -6.000000e+00 8.202537e+02 286.93 -2.00 20.00 -2.00 505.50 0.00e+00 4.187640e-03 2.639472e-05 2.267204e-04 -6.000000e+00 4.299954e-04 286.93 -2.00 20.00 -2.00 501.23 0.00e+00 1.629132e+00 1.790446e-02 1.182835e-01 -6.000000e+00 2.987781e-01 232.89 -2.00 3.57 -2.00 502.71 0.00e+00 18.819 0.130 489.00 513.00 1 4.3305e+00 1.3677e-03 3.4076e-02 -6.0000e+00 2.2863e-02 -7.9245e-02 3.4748e-04 3.3701e-03 -6.0000e+00 6.0353e-03 1.5188e-03 2.5907e-03 6.6458e-05 1.3984e-04 -6.0000e+00 1.2083e-03 3.1124e-02 -2.3982e-04 12 9 9 12 1 1 41.60 15.00 5.84 0.03112 0.04909 16 8 1 4 0 784.790 22.19 15.00 19.21 900000 -4965 -3268 -1414 -183 766 1387 1923 1685 1038 115 -233 -1194 -1711 -2269 -2195 -1633 -437 801 1176 1011 1156 1036 1204 1601 1620 1592 1486 219 -1747 -2754 -2630 -1931 -63 1478 1875 1228 476 80 -309 -390 247 882 1344 2106 2402 2189 1479 1021 59 -1378 -2572 -3162 -2970 -1569 84 1147 1437 1398 1031 1233 1629 1845 1985 1594 839 -34 -374 -611 -1347 -1932 -1859 -1319 -403 57 -55 -1013 -1704 -2090 -2206 -1868 -1266 -1058 -999 -548 -292 -203 -556 -577 -95 -125 600 1709 2210 1954 1469 967 -126 -1258 -2931 -3395 -2817 -1781 290 929 772 30 -1032 -1568 -1284 -421 -161 885 1366 1747 2345 2555 2710 1965 856 95 -409 -322 540 1218 999 1232 743 406 778 574 -333 -1090 -1723 -2025 -1552 -605 235 809 948 892 510 531 992 1428 1136 378 -1341 -2671 -3006 -2418 900000 -4336 -2916 -1300 -163 689 1272 1786 1576 967 106 -214 -1092 -1551 -2053 -1989 -1491 -405 761 1138 981 1121 1010 1179 1500 1531 1506 1406 207 -1700 -2623 -2508 -1863 -59 1436 1845 1205 465 78 -299 -379 242 873 1349 2137 2457 2245 1513 1037 60 -1364 -2503 -3044 -2862 -1541 85 1127 1430 1393 1028 1228 1634 1868 2016 1621 848 -34 -370 -603 -1322 -1881 -1812 -1294 -399 57 -56 -1007 -1665 -2025 -2128 -1793 -1218 -1025 -975 -543 -293 -204 -557 -572 -93 -123 597 1726 2232 1922 1391 929 -118 -1174 -2736 -3145 -2636 -1726 281 949 771 30 -1033 -1557 -1283 -429 -167 915 1412 1801 2413 2679 2921 2160 941 103 -433 -335 560 1280 1061 1314 800 437 842 623 -357 -1155 -1837 -2172 -1614 -645 253 879 1050 1006 557 586 1094 1570 1250 414 -1460 -3019 -3255 -2646 SO 20180720T100927.8Z 6775.423239 347 1 33.70 2 88.45 62.47 139.57 323.37 0.00 1 0.00 1 0 22 1.148e-02 1.126e-02 2.831e-04 2.815e-04 1.791030e+04 1.918243e+01 1.179441e+03 -6.000000e+00 6.056512e+02 286.93 -2.00 20.00 -2.00 505.48 0.00e+00 3.802784e-03 7.727665e-06 2.155005e-04 -6.000000e+00 3.174771e-04 286.93 -2.00 20.00 -2.00 501.19 0.00e+00 1.534555e+00 5.268989e-03 1.151730e-01 -6.000000e+00 2.204458e-01 232.89 -2.00 3.57 -2.00 502.67 0.00e+00 17.156 0.098 489.00 513.00 1 3.0510e+00 4.0278e-04 2.9884e-02 -6.0000e+00 1.6871e-02 -7.3743e-02 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