File name: Pandora103s1_Downsview_20180721_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010714.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180721_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180721 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180721T100207.0Z 6776.418137 338 1 32.01 2 89.77 61.33 136.15 304.23 0.00 1 0.00 1 0 22 6.220e-02 5.957e-02 5.305e-02 5.238e-02 1.131565e+04 3.589343e+03 8.685399e+02 -6.000000e+00 3.281230e+03 286.95 -2.00 20.00 -2.00 505.33 0.00e+00 2.494521e-03 1.411999e-03 1.591062e-04 -6.000000e+00 1.719935e-03 286.95 -2.00 20.00 -2.00 500.37 0.00e+00 1.576810e+00 1.017550e+00 5.567713e-02 -6.000000e+00 1.195087e+00 232.85 -2.00 3.57 -2.00 501.96 0.00e+00 19.986 0.156 489.00 513.00 1 9.4473e+00 7.7723e-02 3.6079e-02 -6.0000e+00 9.1452e-02 9.1420e-02 2.0123e-02 2.4781e-03 -6.0000e+00 2.4140e-02 7.9431e-06 -1.7385e-03 3.8147e-03 8.4992e-05 -6.0000e+00 4.8326e-03 -1.3225e-02 2.7946e-05 12 8 8 10 0 0 6.92 15.00 6.32 -0.01322 -0.02528 8 1 1 4 0 4000.000 22.29 15.00 19.42 900000 7054 -4091 -5886 231 -5536 -2744 5929 -4208 10355 3095 2493 3995 -5148 -1220 3977 7789 -5974 4541 -4349 6651 1386 -997 -1281 -1600 -481 3563 -638 13455 -1052 -926 -10543 -3501 -4036 3800 1421 -404 5440 8222 -448 -3138 5672 -8490 11901 -3262 6440 -4718 1835 -7864 -3851 -697 600 -11428 10258 6314 -226 1454 2295 3100 5197 1349 -4168 7155 -11309 6819 -3740 4887 -4185 9022 -10313 -3180 -3250 -186 -1149 1194 -2309 11451 -7375 20979 904 -2713 4500 -7038 -7617 2515 10491 -2599 4497 -4932 8672 -3475 7594 -3993 -4433 -3978 9218 1439 10358 -2589 -4775 -26 -4201 -5920 -4246 2557 3742 -328 -12034 3272 -3425 6574 -383 6787 -4759 3596 1379 -1716 2123 16324 -4140 -2934 -7069 -697 -6475 4073 -2090 10823 15868 6593 9318 -1936 2339 -11093 -1590 -4403 5096 -1944 13778 -4393 5485 -635 12857 -3218 655 -5692 -1622 -2311 -194 2623 -2913 -3080 900000 6021 -4001 -6117 234 -6054 -2985 6038 -4756 10079 3168 2531 3945 -5458 -1229 3797 7209 -6447 4572 -4901 6746 1477 -1087 -1401 -1769 -530 3765 -699 12715 -1102 -929 -11512 -3609 -4316 3949 1548 -444 5564 8083 -473 -3384 5641 -9810 11421 -3681 6670 -5448 1968 -9122 -4217 -718 590 -12333 8900 5803 -231 1508 2402 3224 5259 1409 -4613 7151 -13554 6824 -4092 4818 -4423 8296 -11310 -3193 -3248 -182 -1148 1189 -2388 10155 -7633 16208 842 -2606 4053 -7147 -7804 2362 9255 -2613 4197 -5000 7646 -3449 6837 -4108 -4635 -4072 8022 1305 8325 -2301 -4243 -21 -3658 -5402 -4028 2400 3549 -322 -13018 2989 -3333 5913 -376 6276 -4951 3453 1353 -1752 2126 14352 -4389 -3008 -7359 -668 -6563 3780 -2069 9462 13229 5979 8238 -1917 2180 -11489 -1487 -4210 4479 -1883 11725 -4508 5189 -645 11521 -3389 668 -6179 -1687 -2390 -191 2449 -2835 -3027 SO 20180721T100621.0Z 6776.421076 342 1 32.01 2 89.10 62.06 136.76 305.37 0.00 1 0.00 1 0 36 2.266e-02 2.208e-02 2.563e-03 2.531e-03 1.305140e+04 1.679847e+02 8.300201e+02 -6.000000e+00 1.195212e+03 286.95 -2.00 20.00 -2.00 505.60 0.00e+00 3.730094e-03 6.932184e-05 1.844525e-04 -6.000000e+00 6.265369e-04 286.95 -2.00 20.00 -2.00 501.45 0.00e+00 1.666437e+00 4.667631e-02 1.033474e-01 -6.000000e+00 4.351361e-01 232.85 -2.00 3.57 -2.00 502.90 0.00e+00 18.747 0.128 489.00 513.00 1 6.3384e+00 3.5515e-03 3.3336e-02 -6.0000e+00 3.3300e-02 -7.0716e-02 9.0306e-04 2.9368e-03 -6.0000e+00 8.7863e-03 2.0868e-04 4.2651e-03 1.8412e-04 9.7213e-05 -6.0000e+00 1.7600e-03 -2.1524e-03 -1.2014e-05 12 8 8 10 0 0 58.69 15.00 9.92 -0.00215 0.02743 8 1 1 4 0 4000.000 22.29 15.00 19.43 900000 -8319 -5481 -2652 -1339 190 1640 1889 1960 906 -124 -739 -2201 -2640 -3460 -3012 -2519 -1210 847 2116 1150 1545 1107 1664 1620 1864 1900 2125 432 -2254 -3589 -3844 -2597 426 2503 2888 2201 910 521 -88 198 297 1618 2522 3406 3631 3475 2316 1705 326 -1562 -3986 -3853 -3818 -1993 438 1327 2092 1583 2157 2046 2447 3027 2401 2532 1399 -467 -682 -1381 -2070 -2656 -2168 -1424 -802 264 -167 -1599 -2682 -3007 -3385 -3143 -1718 -1652 -1450 -616 -499 -558 -604 -662 -558 -108 1228 2844 3084 2186 2018 1046 -847 -2263 -4459 -4426 -3361 -1819 953 2161 1115 93 -1547 -2469 -1502 -669 133 1195 2073 2251 3233 4430 4050 2769 1168 232 -985 -512 982 1263 954 1589 542 543 908 1081 -1065 -1172 -3081 -2700 -2409 -518 95 1030 1187 1092 774 896 1295 1782 1550 -32 -2009 -3839 -4182 -3197 900000 -6825 -4547 -2244 -1154 165 1441 1683 1751 809 -110 -652 -1947 -2312 -3035 -2638 -2227 -1086 773 1945 1067 1431 1033 1554 1536 1775 1809 2015 409 -2098 -3293 -3551 -2418 404 2436 2836 2153 891 507 -86 193 293 1600 2519 3432 3686 3528 2356 1722 327 -1549 -3935 -3740 -3725 -1978 443 1375 2181 1659 2240 2130 2566 3190 2360 2475 1363 -455 -658 -1333 -1984 -2528 -2060 -1361 -776 258 -164 -1550 -2569 -2861 -3219 -2985 -1626 -1575 -1392 -597 -490 -549 -592 -644 -541 -105 1199 2803 3045 2124 1896 959 -768 -2042 -4034 -3965 -3031 -1689 919 2167 1146 96 -1596 -2540 -1550 -703 141 1272 2202 2394 3424 4728 4437 3088 1304 256 -1075 -549 1050 1370 1044 1740 601 601 1010 1200 -1180 -1278 -3417 -2986 -2715 -593 102 1115 1308 1220 875 1020 1478 2029 1764 -36 -2273 -4333 -4736 -3651 SO 20180721T101030.2Z 6776.423960 346 1 34.33 2 88.43 62.77 137.35 306.50 0.00 1 0.00 1 0 71 2.104e-02 2.029e-02 1.291e-03 1.280e-03 1.431412e+04 8.449155e+01 9.254166e+02 -6.000000e+00 1.109363e+03 286.95 -2.00 20.00 -2.00 505.50 0.00e+00 3.601309e-03 3.510771e-05 1.747489e-04 -6.000000e+00 5.814487e-04 286.95 -2.00 20.00 -2.00 501.30 0.00e+00 1.474400e+00 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