File name: Pandora103s1_Downsview_20180723_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010707.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180723_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180723 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180723T100403.0Z 6778.419479 313 1 32.01 2 89.77 61.93 125.61 278.37 0.00 1 0.00 1 0 29 2.599e-02 2.544e-02 2.206e-02 2.181e-02 1.615379e+04 1.585156e+03 9.501793e+02 -6.000000e+00 1.370892e+03 286.99 -2.00 20.00 -2.00 505.31 0.00e+00 1.710229e-03 5.898913e-04 1.045232e-04 -6.000000e+00 7.185862e-04 286.99 -2.00 20.00 -2.00 500.16 0.00e+00 1.693241e+00 4.289173e-01 1.137300e-01 -6.000000e+00 4.991095e-01 232.77 -2.00 3.57 -2.00 501.78 0.00e+00 19.985 0.155 489.00 513.00 1 8.5450e+00 3.2839e-02 3.6833e-02 -6.0000e+00 3.8195e-02 1.0442e-01 8.4194e-03 3.2200e-03 -6.0000e+00 1.0080e-02 1.9554e-05 1.5618e-03 1.5401e-03 7.5570e-05 -6.0000e+00 2.0187e-03 -2.3682e-02 1.0303e-04 12 8 8 10 0 0 1.42 14.99 2.74 -0.02368 -0.01285 8 1 1 4 0 4000.000 22.09 14.99 19.19 900000 -2986 -413 -28 -2356 -627 -1251 925 -827 121 -4409 3775 -3644 -608 996 2225 -2395 2289 -2093 3871 -2808 1592 -576 934 1000 478 2045 -736 -1088 -617 3767 -3916 -282 2834 2062 -166 2537 -4708 277 -1308 2915 -1704 1854 2562 2488 -1008 910 3350 785 2346 -1169 1257 -2547 2323 25 -537 -2989 286 2967 6538 1314 797 -1804 4144 -1469 2254 -144 -3231 908 -1440 -1269 -4619 3806 -3564 999 -27 -1093 -1999 1442 -4274 -1190 -1375 2711 -3964 -1262 -443 983 -2525 1734 -4241 2613 -1341 -2134 3206 2486 2493 1112 -5797 -3307 716 727 -4324 -1352 6032 1278 652 288 686 -654 -1941 -1029 7161 -201 2663 -196 2272 -1632 -2951 1931 1913 674 -1456 4003 342 6656 -446 4350 -1703 1285 -3369 4339 240 -142 -1415 1490 -973 -1957 -1083 5534 -1088 -3294 2690 -1645 2632 -1389 -658 128 -928 -4981 1658 -5735 900000 -2887 -402 -29 -2514 -670 -1376 1012 -923 132 -4944 3860 -3951 -629 1003 2209 -2509 2343 -2313 4126 -3190 1733 -640 1023 1103 533 2235 -823 -1201 -650 3666 -4091 -289 2916 2237 -187 2753 -5393 298 -1412 3011 -1851 1968 2734 2694 -1136 1004 3565 843 2430 -1211 1231 -2533 2197 24 -557 -3269 307 3101 6547 1378 845 -1973 4281 -1593 2320 -149 -3375 902 -1443 -1247 -4679 3583 -3654 997 -27 -1086 -1948 1338 -4154 -1118 -1302 2482 -3892 -1225 -433 947 -2500 1627 -4185 2413 -1302 -2130 3046 2310 2218 961 -5170 -2816 575 575 -3635 -1149 5087 1195 627 277 645 -611 -1840 -986 6436 -195 2511 -189 2143 -1621 -3038 1912 1869 650 -1392 3551 315 5853 -422 3932 -1634 1190 -3271 3910 220 -127 -1281 1309 -889 -1860 -1039 5030 -1072 -3360 2607 -1672 2574 -1410 -660 125 -897 -4885 1514 -5686 SO 20180723T100825.0Z 6778.422512 317 1 32.01 2 89.07 62.68 126.36 279.18 0.00 1 0.00 1 0 22 1.216e-02 1.215e-02 1.004e-02 9.963e-03 1.889431e+04 7.390239e+02 1.231656e+03 -6.000000e+00 6.414257e+02 286.99 -2.00 20.00 -2.00 505.41 0.00e+00 3.311391e-03 2.704192e-04 1.774230e-04 -6.000000e+00 3.362302e-04 286.99 -2.00 20.00 -2.00 500.45 0.00e+00 2.160533e+00 1.938970e-01 1.085644e-01 -6.000000e+00 2.334596e-01 232.77 -2.00 3.57 -2.00 502.04 0.00e+00 18.688 0.127 489.00 513.00 1 7.8458e+00 1.4822e-02 3.3308e-02 -6.0000e+00 1.7867e-02 4.5905e-02 3.7730e-03 3.2389e-03 -6.0000e+00 4.7138e-03 4.4355e-05 1.8878e-03 6.8862e-04 1.0523e-04 -6.0000e+00 9.4443e-04 -1.0004e-02 3.7549e-05 12 8 8 10 0 0 32.42 15.00 2.25 -0.01000 0.00309 8 1 1 4 0 4000.000 22.19 15.00 19.20 900000 -2135 -2255 -1217 -857 -228 -404 637 -35 -416 1179 -661 -269 -3078 -50 -1680 -1160 812 1267 -590 1618 -581 -164 -71 585 -252 -91 1674 -632 78 -363 1670 -1577 -45 -281 1775 -531 1210 838 -196 -26 2135 -76 1463 -94 1131 245 178 120 161 302 -1468 109 -3247 293 -778 809 -2022 768 -608 2244 576 2328 1231 2191 -1015 1468 -1154 431 -1079 1304 558 205 -43 715 -454 -245 30 -1505 -682 -375 1163 -1226 12 -2450 2255 -278 1365 341 1113 -1907 1246 561 1894 1203 555 -40 1290 -809 -810 -238 -1269 672 -858 855 822 925 -210 -137 -764 -122 -1120 770 -1136 83 -1101 2987 1935 -5 -127 -1909 -1320 -832 1523 -769 106 226 664 -527 406 -2049 -1306 -549 579 -1689 1335 -1267 -110 -425 1587 -1389 510 819 612 3228 -732 -71 486 -817 -3442 -1459 900000 -1965 -2146 -1197 -866 -233 -423 672 -38 -439 1202 -677 -271 -3133 -49 -1669 -1158 814 1306 -632 1695 -622 -174 -76 625 -274 -98 1773 -673 79 -358 1610 -1590 -46 -304 1912 -577 1277 877 -205 -27 2197 -81 1557 -103 1233 269 193 129 169 306 -1468 105 -3237 290 -809 854 -2218 820 -653 2338 614 2458 1313 2304 -1083 1499 -1188 433 -1085 1260 542 202 -43 722 -462 -243 29 -1450 -646 -353 1083 -1174 11 -2423 2160 -273 1307 325 1044 -1842 1185 548 1827 1132 503 -35 1070 -671 -660 -190 -1036 561 -776 807 793 890 -201 -129 -726 -117 -1108 752 -1129 82 -1092 2897 1944 -5 -130 -1935 -1293 -794 1427 -748 103 220 644 -514 394 -2036 -1257 -514 535 -1596 1247 -1250 -109 -426 1592 -1454 528 851 638 3279 -768 -73 486 -809 -3478 -1465 SO 20180723T101231.1Z 6778.425360 321 1 24.17 2 88.41 63.38 127.06 279.95 0.00 1 0.00 1 0 29 9.663e-03 9.388e-03 2.310e-03 2.296e-03 2.592930e+04 1.723041e+02 1.665656e+03 -6.000000e+00 5.096733e+02 286.99 -2.00 20.00 -2.00 505.44 0.00e+00 3.865549e-03 6.262867e-05 2.205716e-04 -6.000000e+00 2.671108e-04 286.99 -2.00 20.00 -2.00 500.82 0.00e+00 1.919650e+00 4.374355e-02 1.419788e-01 -6.000000e+00 1.850193e-01 232.77 -2.00 3.57 -2.00 502.33 0.00e+00 17.051 0.096 489.00 513.00 1 6.2711e+00 3.3446e-03 3.0524e-02 -6.0000e+00 1.4170e-02 -3.0003e-02 8.4628e-04 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