File name: Pandora103s1_Downsview_20180724_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010754.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180724_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180724 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180724T100501.0Z 6779.420151 295 1 32.01 2 89.77 62.23 118.64 268.61 0.00 1 0.00 1 0 22 7.898e-02 7.487e-02 7.574e-02 7.322e-02 5.266343e+03 4.886141e+03 3.308683e+02 -6.000000e+00 4.165220e+03 287.01 -2.00 20.00 -2.00 505.18 0.00e+00 6.982580e-03 1.985954e-03 4.115632e-04 -6.000000e+00 2.185002e-03 287.01 -2.00 20.00 -2.00 499.66 0.00e+00 4.659596e+00 1.505898e+00 7.179141e-02 -6.000000e+00 1.522735e+00 232.74 -2.00 3.57 -2.00 501.32 0.00e+00 19.988 0.156 489.00 513.00 1 9.5150e+00 1.1551e-01 3.7181e-02 -6.0000e+00 1.1644e-01 1.2092e-01 3.0040e-02 2.2533e-03 -6.0000e+00 3.0871e-02 5.5847e-06 1.8158e-03 5.3763e-03 9.7864e-05 -6.0000e+00 6.1555e-03 -1.9361e-02 -1.7615e-04 12 8 8 10 0 0 -13.29 15.00 9.25 -0.01936 -0.00677 8 1 1 4 0 4000.000 22.09 15.00 19.20 900000 13094 5214 -3547 -5727 9463 12562 6973 7408 -2491 -4165 2292 24 465 -11307 1689 9732 350 -10213 7212 -9125 -2495 -2760 -7173 5565 -2022 392 4486 -8482 10648 3942 5191 11587 -226 -1102 397 -10768 836 3162 10632 -9160 2406 -786 -8566 12398 15563 2289 11388 2957 -3086 -7070 -4471 1207 -3217 2047 -8355 -3669 2136 2480 -5298 -9542 -1709 67 4184 -2735 -899 12414 2448 1686 5661 16129 -8443 -2689 9427 -2618 3886 -5798 -10331 3807 -12604 7163 -4260 3670 -9502 2981 -9473 -1824 10787 -2736 -3523 10186 19944 2366 -4765 7642 -12847 -2506 6230 17042 -9127 -2156 -1603 629 -6001 -7806 4321 16498 -6752 674 3104 10047 -6544 7275 751 15824 3732 287 2602 -14789 -197 8376 823 5229 -5944 -5181 -7048 482 9142 1107 16972 1106 11799 2744 -11169 8271 -4687 -15061 876 17251 -543 -4157 -6982 17029 11037 6307 -5375 -8398 9699 -2661 -3744 15651 900000 11532 5090 -3936 -6732 9786 12865 7669 8146 -2988 -4964 2519 26 503 -13516 1769 9454 379 -12589 7700 -11425 -2917 -3230 -8764 6055 -2394 453 4965 -10528 10564 3987 5118 10822 -243 -1254 458 -13721 934 3409 10519 -10939 2584 -883 -10533 12628 15523 2601 11728 3252 -3532 -8163 -4858 1211 -3336 2047 -9605 -4164 2331 2702 -6177 -11509 -1915 75 4457 -3100 -986 11695 2486 1701 5417 13640 -8964 -2707 8512 -2696 3771 -6057 -10934 3445 -13244 6168 -4107 3289 -9655 2694 -9749 -1742 9039 -2584 -3325 8401 15074 2167 -4765 6744 -13517 -2326 5165 12347 -8283 -1781 -1308 511 -5408 -7477 3726 12489 -6278 571 2565 7920 -6206 6149 685 12593 3350 269 2403 -16212 -185 7086 735 4398 -5586 -4911 -6841 436 7613 992 13060 998 9456 2341 -10741 6520 -4197 -15290 781 13285 -502 -4022 -6954 13462 9297 5584 -5325 -8455 7961 -2382 -3330 11619 SO 20180724T100923.0Z 6779.423183 299 1 32.01 2 89.07 62.98 119.40 269.33 0.00 1 0.00 1 0 15 5.195e-02 4.974e-02 4.670e-02 4.551e-02 1.198433e+04 3.297969e+03 7.447020e+02 -6.000000e+00 2.741058e+03 287.01 -2.00 20.00 -2.00 505.24 0.00e+00 9.488420e-04 1.236415e-03 9.249981e-05 -6.000000e+00 1.436636e-03 287.01 -2.00 20.00 -2.00 499.74 0.00e+00 3.408943e+00 9.228341e-01 7.725440e-02 -6.000000e+00 9.983541e-01 232.74 -2.00 3.57 -2.00 501.41 0.00e+00 18.689 0.127 489.00 513.00 1 9.3769e+00 7.0730e-02 3.2415e-02 -6.0000e+00 7.6394e-02 1.1110e-01 1.8214e-02 2.4963e-03 -6.0000e+00 2.0173e-02 9.1240e-06 4.1185e-03 3.2646e-03 5.4870e-05 -6.0000e+00 4.0370e-03 -1.6573e-02 2.0757e-05 12 8 8 10 0 0 -6.16 15.00 4.13 -0.01657 0.01199 8 1 1 4 0 4000.000 22.19 15.00 19.20 900000 -4533 6102 -2675 2453 1773 592 -974 8202 -4668 375 11167 -1229 4664 -4826 908 3046 4408 -5409 394 -2788 2048 -4081 -2029 -5146 856 -3385 2274 -2060 -2027 5203 1948 435 -1168 4082 -1669 -1914 3389 -319 721 2839 -2268 -2568 -4305 6196 -880 6953 -4453 6180 402 2033 -9675 -5294 4990 1235 -5267 2969 15261 -8526 899 2926 4095 -6064 2547 -2974 6679 1205 11679 -3011 -2219 -5122 7461 -7837 -1935 -8850 4515 8505 2735 8862 -3729 5659 -3819 9696 -8085 1360 -7648 -1059 -6402 -47 -3859 5873 -3517 7696 2360 -4876 -4099 10497 -4774 -4823 294 -416 3125 -3283 12732 -544 -2461 2935 10386 2902 -869 -2822 6047 -5084 -1175 -333 6533 -4934 1035 816 2843 -5368 1301 -4825 2110 9470 -4352 -1885 1247 6473 -4555 7872 -4128 2721 -5747 4698 -5006 1710 -6270 -2949 3461 11540 -7140 120 -6531 8073 9736 3325 -2725 -1041 207 1213 900000 -4702 5893 -2938 2636 1952 674 -1143 8824 -5624 422 11167 -1366 4810 -5400 960 3184 4661 -6511 457 -3327 2331 -4922 -2400 -6322 995 -4079 2580 -2391 -2249 5201 2007 462 -1307 4536 -1985 -2251 3723 -358 790 3036 -2560 -2938 -5064 6656 -1017 7405 -5222 6424 432 2074 -10689 -5484 4669 1230 -5810 3105 14298 -10034 956 3034 4219 -6930 2671 -3265 6555 1219 10485 -3085 -2219 -5172 6652 -8176 -1932 -9604 4282 7554 2497 7509 -3538 4882 -3639 8141 -8100 1260 -7827 -1016 -6417 -44 -3710 5141 -3411 6818 2203 -4752 -3814 8165 -4164 -4111 233 -327 2410 -2801 9876 -504 -2354 2638 8507 2509 -781 -2637 5259 -4957 -1105 -310 5689 -4867 981 777 2609 -5214 1153 -4458 1835 7765 -4086 -1730 1109 5437 -4277 6541 -3760 2272 -5178 3813 -4540 1499 -6047 -2785 3118 9719 -7249 114 -6657 7137 8427 3014 -2548 -934 183 1072 SO 20180724T101339.0Z 6779.426146 303 1 32.01 2 88.38 63.71 120.14 270.04 0.00 1 0.00 1 0 22 2.885e-02 2.833e-02 2.458e-02 2.417e-02 1.594552e+04 1.783588e+03 1.128091e+03 -6.000000e+00 1.522277e+03 287.01 -2.00 20.00 -2.00 505.29 0.00e+00 2.311894e-03 6.539730e-04 1.270063e-04 -6.000000e+00 7.978578e-04 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