File name: Pandora103s1_Downsview_20180725_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010726.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180725_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180725 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180725T100602.0Z 6780.420857 291 1 32.01 2 89.77 62.55 111.03 260.30 0.00 1 0.00 1 0 22 1.406e-01 1.236e-01 1.214e-01 1.148e-01 1.910904e+04 8.566574e+03 2.018381e+03 -6.000000e+00 7.415080e+03 287.03 -2.00 20.00 -2.00 505.17 0.00e+00 -1.369080e-03 3.065961e-03 1.293642e-04 -6.000000e+00 3.890054e-03 287.03 -2.00 20.00 -2.00 499.73 0.00e+00 -3.178255e+00 2.276404e+00 7.499507e-02 -6.000000e+00 2.711836e+00 232.70 -2.00 3.57 -2.00 501.37 0.00e+00 19.983 0.155 489.00 513.00 1 1.0649e+01 1.7275e-01 3.5807e-02 -6.0000e+00 2.0735e-01 2.5014e-01 4.6317e-02 2.0115e-03 -6.0000e+00 5.5016e-02 3.4855e-06 1.1230e-02 8.0316e-03 1.2964e-04 -6.0000e+00 1.0960e-02 2.8531e-02 -5.0754e-04 12 8 8 10 0 0 -2.92 14.99 2.91 0.02853 0.10643 8 1 1 4 0 4000.000 22.19 14.99 19.23 900000 -1399 3508 15212 -1359 8630 -203 7785 -5631 -6271 12656 2467 -7539 -5784 20159 -4060 4368 6400 18188 -577 1229 9752 20631 -5469 3015 -7051 -12898 4274 -18987 10835 2248 -3478 -456 -759 -5721 12264 -2669 11328 2727 -3405 -11267 3312 -4531 -1245 -14395 6784 10023 3755 -15389 21750 -5132 21290 -11742 -14703 30300 -5202 20 -15564 5698 -10519 1159 -8422 -2174 10544 15764 12116 16822 16987 27935 -13619 -18020 -11455 14850 2682 -3260 14823 -5475 11336 -10512 -801 -8975 34586 -1333 5842 -10296 -1265 3780 9435 -4452 20898 3175 46100 15673 -8999 19440 8274 -4831 12596 5502 11382 10125 -29496 19529 7229 24073 -19107 -13011 -4878 8814 -7776 6208 -7506 16528 -26732 -9923 7653 -10676 3557 18156 3987 24216 -450 9616 437 -22339 17726 -7313 47730 254 6561 -5905 24837 -13081 2123 -11171 41848 10557 10249 -14662 -3725 770 -7170 21394 -4297 -3022 2500 26324 19455 4138 -9892 15529 900000 -1454 3594 14488 -1554 9105 -239 8556 -7038 -7771 12807 2721 -9007 -6668 17907 -4550 4561 6727 17637 -680 1418 10358 19657 -6695 3417 -8799 -16900 4714 -25592 10458 2289 -3747 -485 -844 -6943 12593 -3117 11377 2931 -3828 -13619 3491 -5197 -1398 -18539 7137 10155 3982 -19302 18611 -5487 17109 -12718 -16438 22660 -5690 22 -19457 5785 -12380 1215 -9756 -2385 10226 14435 11295 14690 14596 21431 -15348 -20892 -12507 12734 2631 -3444 13085 -5722 9830 -11105 -765 -9255 23712 -1300 5368 -11274 -1288 3667 8607 -4589 16784 3032 29579 13663 -9853 15559 7022 -4439 9463 4348 8357 7468 -32517 14134 6324 18944 -23209 -14801 -5025 7808 -8100 5743 -7981 13899 -33853 -10591 6880 -11646 3460 15407 3804 18465 -419 7953 395 -25411 13690 -7177 27535 229 5553 -5589 16980 -12599 1759 -10499 24110 8427 8292 -15192 -3530 706 -7132 16227 -4161 -2872 2233 18384 14125 3399 -9237 11459 SO 20180725T101021.0Z 6780.423854 295 1 32.01 2 89.07 63.29 111.77 260.98 0.00 1 0.00 1 0 15 8.861e-02 8.395e-02 9.299e-02 8.963e-02 2.244674e+03 5.607474e+03 2.676712e+02 -6.000000e+00 4.673197e+03 287.03 -2.00 20.00 -2.00 505.26 0.00e+00 -5.404717e-04 2.423653e-03 8.598585e-05 -6.000000e+00 2.451604e-03 287.03 -2.00 20.00 -2.00 499.63 0.00e+00 5.308619e+00 1.824307e+00 1.512970e-02 -6.000000e+00 1.709056e+00 232.70 -2.00 3.57 -2.00 501.34 0.00e+00 18.695 0.127 489.00 513.00 1 9.9709e+00 1.3976e-01 3.1779e-02 -6.0000e+00 1.3068e-01 9.4312e-02 3.6423e-02 1.7523e-03 -6.0000e+00 3.4671e-02 4.5195e-06 -1.0830e-03 6.7419e-03 2.8905e-05 -6.0000e+00 6.9076e-03 1.1992e-02 -4.0677e-04 12 8 8 10 0 0 -6.42 14.99 2.43 0.01199 0.00448 8 1 1 4 0 4000.000 22.19 14.99 19.23 900000 -7651 2412 6943 -16918 682 6282 -2197 -3252 -7892 10907 -4554 12346 -8604 -5920 -1247 5405 1799 1298 -3324 13312 -4527 -4378 -7238 2192 -3307 -6336 10671 14626 840 -6364 -3307 -8699 7518 1107 14224 -4399 3286 6978 10030 -8723 -7289 5246 9886 5689 5055 2771 -927 6987 2725 12498 -16695 2486 23165 2071 138 6468 -3611 -9776 -7350 8190 -8011 5590 21679 10117 -4497 -6966 5269 1687 -9772 3497 -5257 2715 -11558 -5629 5107 11467 5860 3196 -532 -2810 3585 14026 -308 11559 10288 -1104 18561 -6321 -3208 -1651 12894 -5684 6734 16619 10566 -108 5263 -13114 1704 14159 -6395 19829 8398 9392 -7652 2540 -5016 6243 764 6227 -288 -14073 -12188 -8740 6788 -10812 -2125 7550 1616 4814 24562 -6654 -3659 3391 -4530 -10352 11769 -13053 5960 -4181 16508 -3292 14232 -9523 41 -3879 -9297 -2737 -7943 6756 -949 11165 -15350 9304 -2527 15773 -212 -8537 -4764 11574 900000 -8190 2392 6853 -21856 759 6757 -2620 -3957 -10013 11345 -5416 12333 -10350 -6837 -1368 5581 1956 1463 -4045 13902 -5608 -5413 -9182 2546 -4080 -8026 11404 14924 950 -7365 -3648 -10170 7682 1259 14729 -5443 3707 7488 10279 -10600 -8717 5593 10157 6154 5543 3105 -1065 7306 2913 11800 -20124 2416 18140 2002 140 6419 -4026 -11605 -8445 8014 -9151 5625 18686 9709 -4910 -7621 5010 1636 -10459 3226 -5210 2498 -12325 -5761 4760 9900 5181 2835 -484 -2597 3127 11163 -282 9490 8666 -1044 14481 -6238 -3061 -1552 10572 -5658 6043 13519 8931 -99 4467 -12909 1414 10181 -5580 13693 6738 7837 -7692 2293 -4775 5209 664 5183 -260 -14738 -12679 -8852 5925 -11227 -2047 6641 1487 4215 17468 -6282 -3348 2938 -4260 -10282 9449 -13254 5028 -3917 12561 -2962 10637 -8856 35 -3492 -9098 -2560 -7915 5909 -898 9429 -16887 8124 -2480 12877 -197 -8330 -4385 9117 SO 20180725T101436.0Z 6780.426806 299 1 32.01 2 88.39 64.02 112.50 261.64 0.00 1 0.00 1 0 22 7.028e-02 6.831e-02 6.848e-02 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