File name: Pandora103s1_Downsview_20180726_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010807.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180726_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180726 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180726T100702.1Z 6781.421552 284 1 32.15 2 89.77 62.87 103.00 252.96 0.00 1 0.00 1 0 22 1.973e-02 1.928e-02 1.691e-02 1.681e-02 1.591101e+04 1.201526e+03 1.009418e+03 -6.000000e+00 1.040812e+03 287.05 -2.00 20.00 -2.00 505.40 0.00e+00 3.461868e-03 4.553463e-04 1.822265e-04 -6.000000e+00 5.455638e-04 287.05 -2.00 20.00 -2.00 500.54 0.00e+00 1.664514e+00 3.239219e-01 1.082128e-01 -6.000000e+00 3.787396e-01 232.66 -2.00 3.57 -2.00 502.12 0.00e+00 19.984 0.155 489.00 513.00 1 8.2521e+00 2.4758e-02 3.6926e-02 -6.0000e+00 2.8985e-02 6.0497e-02 6.3111e-03 3.1948e-03 -6.0000e+00 7.6482e-03 2.5664e-05 3.9873e-03 1.1909e-03 9.5794e-05 -6.0000e+00 1.5323e-03 -1.2296e-03 -2.5606e-05 12 8 8 10 0 0 -6.89 14.99 3.45 -0.00123 0.02643 8 1 1 4 0 4000.000 22.19 14.99 19.19 900000 -2267 -506 -1103 -2322 131 -3556 4117 -1330 359 -1704 352 -1113 -606 -442 -2013 -16 -336 -326 312 -1380 1267 1797 -490 976 538 4708 362 461 -761 -2746 -3299 5010 -1128 892 2916 2341 -300 -227 115 -1511 512 985 2487 1921 424 451 1084 176 325 -1502 -406 180 128 -636 248 -2903 936 -560 2414 302 288 -3288 212 -170 2650 2278 -1560 141 -836 840 -698 822 30 3720 -344 651 -2704 -2708 -1567 -24 -575 -1475 1243 -2575 1581 428 1980 -394 332 -1051 -2066 -1912 2348 -3509 3541 -648 2943 -1261 -1268 -2271 -3579 -425 1521 1996 -766 -902 2030 -3140 -301 -90 -489 2352 -664 2696 -154 4675 1625 4130 -112 -1537 -2097 187 -2348 748 2834 1044 1096 9054 -1230 -255 -58 -1920 -2042 -2555 185 -485 3038 -1626 2473 -1299 -995 -1242 2270 -800 -676 -1274 -836 -1556 -1884 -1027 900000 -2068 -470 -1077 -2360 133 -3814 4158 -1417 371 -1763 353 -1115 -595 -429 -1984 -16 -337 -339 328 -1470 1317 1856 -519 1030 573 4804 384 479 -765 -2728 -3298 4702 -1171 948 3073 2449 -317 -237 119 -1582 530 1030 2601 2050 462 489 1155 187 336 -1531 -397 173 122 -633 255 -3163 994 -602 2505 319 307 -3651 228 -182 2716 2296 -1607 142 -835 812 -685 804 30 3649 -349 638 -2668 -2638 -1497 -23 -547 -1423 1175 -2565 1531 419 1891 -380 316 -1018 -2051 -1935 2279 -3496 3163 -579 2457 -1076 -1059 -1893 -3066 -368 1380 1897 -759 -889 1910 -3061 -288 -87 -487 2290 -667 2618 -154 4542 1661 4144 -116 -1565 -2087 179 -2320 728 2711 1020 1071 8147 -1229 -252 -55 -1842 -1954 -2455 176 -480 2951 -1669 2483 -1369 -1052 -1324 2344 -849 -713 -1330 -847 -1552 -1879 -1031 SO 20180726T101102.9Z 6781.424339 288 1 9.78 2 89.12 63.56 103.66 253.59 0.00 1 0.00 1 0 29 1.312e-02 1.292e-02 1.469e-03 1.462e-03 2.000555e+04 1.013228e+02 1.309245e+03 -6.000000e+00 6.921126e+02 287.05 -2.00 20.00 -2.00 505.47 0.00e+00 4.539426e-03 4.014391e-05 2.523980e-04 -6.000000e+00 3.627783e-04 287.05 -2.00 20.00 -2.00 501.13 0.00e+00 1.636597e+00 2.745634e-02 1.259152e-01 -6.000000e+00 2.519056e-01 232.66 -2.00 3.57 -2.00 502.61 0.00e+00 18.801 0.129 489.00 513.00 1 4.7671e+00 2.0971e-03 3.4325e-02 -6.0000e+00 1.9278e-02 -6.2140e-02 5.3332e-04 3.5492e-03 -6.0000e+00 5.0879e-03 9.7366e-04 1.7007e-03 1.0009e-04 1.5272e-04 -6.0000e+00 1.0190e-03 -6.3388e-03 -7.9302e-06 12 9 9 12 1 1 72.31 15.00 4.30 -0.00634 0.00546 6 4 1 4 0 1373.510 22.19 15.00 19.19 900000 -4044 -2620 -1206 -124 588 1170 1857 1800 1146 239 -293 -720 -1454 -1486 -1653 -1260 -295 572 1168 964 979 806 1049 939 1528 1326 1429 139 -1384 -2273 -2570 -1913 -288 1294 1317 1045 506 221 -287 -331 -21 705 1231 1788 1664 1779 1181 703 141 -1038 -2437 -2817 -2628 -1565 -341 868 1204 985 1106 869 1208 1365 1575 1125 808 122 -275 -787 -1364 -1602 -1233 -831 -139 169 -214 -286 -1416 -1685 -1997 -1385 -1062 -858 -682 -345 -215 -378 -353 -529 -164 -168 753 1500 1714 1835 1112 809 164 -1157 -2359 -2677 -2714 -1640 -306 808 712 15 -902 -1379 -1320 -734 20 520 947 1466 1781 2274 2464 1999 564 201 -584 -338 365 911 891 1094 785 648 578 290 -125 -571 -1474 -1724 -1177 -584 91 861 919 668 568 640 904 1233 802 143 -1241 -2063 -2602 -1887 900000 -3583 -2373 -1071 -113 543 1103 1771 1727 1097 227 -276 -673 -1349 -1368 -1525 -1171 -279 555 1097 908 923 764 996 905 1479 1287 1385 135 -1304 -2199 -2494 -1782 -275 1282 1330 1049 504 219 -283 -328 -21 711 1259 1764 1663 1778 1177 695 138 -1046 -2416 -2752 -2565 -1559 -334 870 1224 1004 1122 884 1237 1412 1634 1169 831 124 -277 -790 -1361 -1579 -1211 -822 -139 172 -219 -286 -1396 -1644 -1941 -1334 -1027 -835 -668 -343 -217 -383 -355 -526 -161 -166 748 1517 1740 1806 1053 771 151 -1066 -2164 -2430 -2498 -1561 -294 818 709 15 -901 -1365 -1317 -747 21 538 979 1507 1831 2373 2647 2095 594 208 -617 -348 376 952 940 1160 839 692 594 300 -133 -597 -1554 -1828 -1210 -618 97 926 1009 717 617 701 992 1348 878 156 -1343 -2203 -2786 -2037 SO 20180726T101518.8Z 6781.427301 292 1 33.53 2 88.43 64.29 104.37 254.26 0.00 1 0.00 1 0 29 1.013e-02 9.920e-03 5.009e-04 4.987e-04 1.961862e+04 3.463579e+01 1.276260e+03 -6.000000e+00 5.342776e+02 287.05 -2.00 20.00 -2.00 505.46 0.00e+00 3.990436e-03 1.364569e-05 2.300567e-04 -6.000000e+00 2.800330e-04 287.05 -2.00 20.00 -2.00 501.05 0.00e+00 1.574727e+00 9.330328e-03 1.246021e-01 -6.000000e+00 1.943012e-01 232.66 -2.00 3.57 -2.00 502.55 0.00e+00 17.100 0.097 489.00 513.00 1 4.0829e+00 7.1117e-04 3.0076e-02 -6.0000e+00 1.4871e-02 -5.6303e-02 1.8201e-04 3.4108e-03 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