File name: Pandora103s1_Downsview_20180727_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010806.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180727_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180727 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180727T100804.0Z 6782.422269 240 1 32.01 2 89.77 63.20 94.68 246.21 0.00 1 0.00 1 0 38 3.662e-02 3.641e-02 3.496e-02 3.463e-02 1.473575e+04 2.470394e+03 9.903696e+02 -6.000000e+00 1.932233e+03 287.07 -2.00 20.00 -2.00 505.42 0.00e+00 3.628400e-03 9.410408e-04 1.333242e-04 -6.000000e+00 1.012640e-03 287.07 -2.00 20.00 -2.00 500.40 0.00e+00 3.028631e+00 6.718341e-01 8.513340e-02 -6.000000e+00 7.012008e-01 232.62 -2.00 3.57 -2.00 502.01 0.00e+00 19.980 0.155 489.00 513.00 1 8.8962e+00 5.1438e-02 3.6405e-02 -6.0000e+00 5.3705e-02 4.4103e-02 1.3010e-02 2.9084e-03 -6.0000e+00 1.4094e-02 1.2150e-05 3.7613e-03 2.4853e-03 8.5010e-05 -6.0000e+00 2.8396e-03 2.6718e-03 -2.2981e-05 12 8 8 10 0 0 -0.34 15.00 6.09 0.00267 0.02876 8 1 1 4 0 4000.000 22.09 15.00 19.18 -5491 -510 3968 -3546 866 -8801 2467 -429 -2321 -1416 2909 -6091 -4551 -1814 -3412 -6156 -2007 -1945 -5766 4319 -65 -1034 3570 187 6004 -2402 5049 7405 3983 -2647 -983 1427 -1958 8435 6953 -788 -738 904 -3872 1138 -2174 2431 2972 132 319 -2576 477 2808 8638 -824 2001 -1777 -1381 2746 -704 1567 3748 937 2348 -1070 3382 -3023 -2183 -2565 1556 3849 -3551 2434 4903 -2957 1320 -1904 4395 -662 -2023 -3383 141 1266 1895 2154 1053 973 -1367 4290 -334 5003 -4229 5390 -2749 9828 -2360 1966 -408 4327 4841 -2740 2909 -551 606 -1973 -59 -7746 -2522 4902 4857 -2022 3900 -2224 3671 -5874 -1588 2407 1595 -1550 3914 5716 1120 -2795 -8090 74 3761 -1656 2060 -135 -2139 3557 1364 5598 -7139 6454 -2151 -2419 -5509 6657 879 430 -8011 -3908 -259 2427 -5136 -1231 -4055 1113 3374 -809 2297 -2197 -2613 2488 -995 -5151 -463 3571 -3590 864 -9833 2528 -459 -2530 -1509 2914 -6583 -4776 -1824 -3452 -6403 -2027 -2014 -6412 4429 -69 -1114 3679 200 6130 -2674 5212 7443 4055 -2748 -974 1383 -1996 8108 7078 -874 -807 959 -4249 1177 -2325 2507 3093 143 350 -2929 524 2981 8532 -873 1992 -1780 -1353 2593 -708 1606 3866 1003 2474 -1157 3493 -3350 -2414 -2845 1646 3912 -3797 2416 4707 -3015 1270 -1891 4143 -666 -2092 -3525 139 1196 1756 1974 973 906 -1308 3905 -323 4639 -4281 4924 -2685 8437 -2288 1855 -403 4073 4401 -2575 2489 -471 503 -1642 -48 -6836 -2205 4250 4423 -1995 3602 -2140 3289 -5825 -1545 2290 1540 -1548 3705 5330 1111 -2944 -9005 75 3584 -1619 1912 -130 -2119 3345 1316 5187 -7449 5938 -2146 -2358 -5437 5815 812 407 -8488 -4043 -262 2430 -5600 -1301 -4432 1161 3439 -855 2316 -2253 -2632 2379 -999 SO 20180727T101223.0Z 6782.425266 244 1 32.01 2 89.07 63.95 95.37 246.92 0.00 1 0.00 1 0 36 1.820e-02 1.770e-02 6.361e-03 6.297e-03 1.591806e+04 4.419090e+02 1.025097e+03 -6.000000e+00 9.605282e+02 287.07 -2.00 20.00 -2.00 505.62 0.00e+00 3.955927e-03 1.737818e-04 2.039524e-04 -6.000000e+00 5.034713e-04 287.07 -2.00 20.00 -2.00 501.21 0.00e+00 1.860982e+00 1.178480e-01 1.147500e-01 -6.000000e+00 3.494219e-01 232.62 -2.00 3.57 -2.00 502.73 0.00e+00 18.680 0.127 489.00 513.00 1 7.3825e+00 9.0130e-03 3.3486e-02 -6.0000e+00 2.6743e-02 -3.8481e-02 2.2522e-03 3.2352e-03 -6.0000e+00 7.0551e-03 7.2224e-05 2.4177e-03 4.4805e-04 1.0392e-04 -6.0000e+00 1.4139e-03 -8.3451e-03 2.8136e-05 12 8 8 10 0 0 96.81 15.00 7.03 -0.00835 0.00843 8 1 1 4 0 4000.000 22.09 15.00 19.18 900000 -6206 -5299 -2711 89 1152 1291 302 864 1449 -1465 -974 -2032 -1912 -2379 -1598 -1039 -820 911 788 -114 150 1753 1622 447 433 2755 1806 669 -1324 -3441 -2720 -1588 310 1864 1708 1367 160 399 -484 953 -810 2595 1590 2812 2492 3187 1771 282 720 -293 -723 -2894 -2775 -742 975 1033 1517 320 400 1573 2922 2543 1582 1310 1639 -885 98 -972 -953 -2409 -915 -2349 -785 780 -811 -1506 -2610 -2498 -2785 -1235 -2322 -491 -1624 388 -201 904 -1289 -283 -696 -81 1352 1682 2668 2865 1551 -922 1939 -2196 -2292 -4326 -3174 -2181 6 1706 1125 443 209 -2074 -1129 165 -102 954 2629 2979 2202 2172 2518 2069 336 -316 -1864 37 -702 2063 826 541 957 -23 1597 1407 -710 -860 -2532 -2448 -1675 -780 -972 1156 208 969 783 606 1362 1165 1220 -351 -1425 -2446 -2969 -3486 900000 -5253 -4613 -2412 80 1042 1196 288 822 1356 -1385 -906 -1888 -1748 -2166 -1445 -946 -765 866 767 -112 147 1695 1578 446 436 2708 1789 660 -1275 -3277 -2576 -1513 303 1884 1758 1397 164 403 -489 950 -831 2618 1649 2932 2634 3343 1865 298 742 -296 -711 -2855 -2740 -742 1001 1004 1489 318 396 1536 2846 2512 1584 1310 1610 -875 95 -941 -911 -2300 -861 -2270 -760 759 -801 -1462 -2499 -2359 -2621 -1143 -2192 -459 -1546 369 -195 868 -1257 -271 -663 -77 1290 1639 2589 2700 1423 -834 1648 -1908 -1956 -3721 -2739 -1945 5 1657 1122 444 207 -2067 -1124 166 -105 983 2678 3029 2264 2278 2699 2249 367 -340 -1981 38 -732 2128 868 574 1014 -25 1689 1492 -752 -895 -2672 -2586 -1790 -854 -1087 1282 238 1115 911 712 1597 1370 1430 -413 -1650 -2801 -3409 -3774 SO 20180727T101619.5Z 6782.428003 248 1 4.97 2 88.43 64.62 96.00 247.56 0.00 1 0.00 1 0 29 1.245e-02 1.228e-02 3.404e-03 3.392e-03 1.879767e+04 2.320213e+02 1.208797e+03 -6.000000e+00 6.571363e+02 287.07 -2.00 20.00 -2.00 505.43 0.00e+00 3.747350e-03 9.247702e-05 2.111872e-04 -6.000000e+00 3.444449e-04 287.07 -2.00 20.00 -2.00 501.06 0.00e+00 1.482059e+00 6.356322e-02 1.216522e-01 -6.000000e+00 2.390548e-01 232.62 -2.00 3.57 -2.00 502.55 0.00e+00 17.091 0.097 489.00 513.00 1 5.5411e+00 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