File name: Pandora103s1_Downsview_20180728_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010732.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180728_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180728 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180728T100925.0Z 6783.423206 210 1 32.01 2 89.71 63.59 86.23 239.77 0.00 1 0.00 1 0 15 2.647e-02 2.577e-02 2.342e-02 2.321e-02 1.275830e+04 1.629295e+03 8.496565e+02 -6.000000e+00 1.396690e+03 287.09 -2.00 20.00 -2.00 505.34 0.00e+00 2.410546e-03 6.298149e-04 1.352898e-04 -6.000000e+00 7.320273e-04 287.09 -2.00 20.00 -2.00 500.30 0.00e+00 1.695612e+00 4.538409e-01 7.717849e-02 -6.000000e+00 5.083049e-01 232.58 -2.00 3.57 -2.00 501.91 0.00e+00 19.905 0.154 489.00 513.00 1 8.6168e+00 3.4749e-02 3.6030e-02 -6.0000e+00 3.8899e-02 9.2821e-02 8.9160e-03 2.7013e-03 -6.0000e+00 1.0268e-02 1.8331e-05 2.0303e-03 1.6686e-03 8.2998e-05 -6.0000e+00 2.0561e-03 -5.5468e-03 -2.6406e-05 12 8 8 10 0 0 4.02 15.00 1.84 -0.00555 0.00854 8 1 1 4 0 4000.000 22.19 15.00 19.20 900000 -2033 1077 -5132 -645 -1916 6293 -1785 2030 -3462 -3599 -80 395 -286 444 1480 -2016 -1123 1376 1486 -1091 3010 -2820 -467 884 1539 -3223 102 -929 2063 -2854 3040 -541 164 -795 1591 859 561 1859 879 -215 -70 -512 222 1390 1072 4281 -1652 3036 -4176 1610 1280 2733 1457 2549 -471 -1877 -366 1911 -1025 -131 5427 -1726 1877 2025 70 165 177 -1284 2541 -3194 -785 -3396 2018 -5104 1110 -3682 809 -2742 1980 448 2 -858 -247 2872 -932 1137 -1068 1528 1216 -495 -1385 5249 -4419 791 1182 2644 300 -3365 -1208 9334 -5958 -1524 -2044 3263 422 2150 -2182 -1294 4167 2968 2256 -3178 5508 -3355 3823 -2272 1070 -1067 2105 -1234 -5573 2281 -2320 -501 3403 -1812 9 2233 206 53 173 2384 634 -1321 -2207 3922 -5567 4607 -456 -2217 1584 6409 -1873 3081 -2295 1771 -3641 1732 -3744 -5114 900000 -1913 1015 -5367 -666 -2040 6329 -1971 2167 -3855 -3932 -83 404 -289 442 1455 -2068 -1168 1445 1593 -1197 3173 -3142 -509 960 1669 -3646 111 -1007 2083 -2915 2923 -546 171 -874 1737 933 602 1944 916 -226 -74 -550 240 1506 1172 4530 -1829 3162 -4569 1611 1244 2565 1381 2453 -486 -2023 -394 2009 -1100 -139 5483 -1882 1976 2118 73 169 178 -1302 2446 -3195 -765 -3427 1960 -5404 1106 -3750 768 -2655 1817 415 2 -817 -235 2687 -917 1097 -1046 1444 1145 -475 -1356 4921 -4574 760 1089 2316 260 -2953 -1016 6981 -5222 -1328 -1900 3034 410 2040 -2120 -1225 3750 2757 2147 -3214 5134 -3407 3624 -2314 1076 -1100 2075 -1228 -5633 2096 -2239 -481 3160 -1773 8 2089 197 51 162 2136 573 -1214 -2074 3580 -5680 4303 -454 -2274 1573 6110 -1942 3044 -2378 1737 -3664 1613 -3647 -5108 SO 20180728T101340.0Z 6783.426157 214 1 32.01 2 89.02 64.33 86.87 240.52 0.00 1 0.00 1 0 22 1.480e-02 1.445e-02 2.489e-03 2.471e-03 1.927291e+04 1.749373e+02 1.239316e+03 -6.000000e+00 7.810359e+02 287.09 -2.00 20.00 -2.00 505.52 0.00e+00 3.637539e-03 6.743327e-05 1.995765e-04 -6.000000e+00 4.093894e-04 287.09 -2.00 20.00 -2.00 501.14 0.00e+00 2.019690e+00 4.597039e-02 1.283470e-01 -6.000000e+00 2.841814e-01 232.58 -2.00 3.57 -2.00 502.64 0.00e+00 18.579 0.125 489.00 513.00 1 6.3005e+00 3.5140e-03 3.3576e-02 -6.0000e+00 2.1749e-02 -5.2481e-02 8.8680e-04 3.5624e-03 -6.0000e+00 5.7394e-03 2.1341e-04 1.9544e-03 1.6986e-04 1.3142e-04 -6.0000e+00 1.1499e-03 1.6167e-03 -5.1610e-05 12 8 8 10 0 0 95.01 15.00 5.91 0.00162 0.01517 8 1 1 4 0 4000.000 22.19 15.00 19.20 900000 -4884 -3461 -1984 -505 199 1693 1368 1250 459 220 -1186 -1066 -1774 -1613 -2286 -1472 -679 476 985 1118 733 1116 833 1112 1864 1403 1617 38 -1204 -2990 -1728 -1872 195 1442 1771 1425 276 -86 -215 460 -48 1091 1413 1941 2212 2229 1365 1321 215 -1090 -2126 -3248 -2670 -893 -632 1302 855 1294 694 1649 1603 1834 1856 1228 1286 44 121 -766 -1015 -1863 -1730 -1882 -318 -173 392 -901 -1147 -2002 -2491 -1714 -1033 -949 -578 -859 -216 -221 -699 -419 -39 456 614 1581 1864 2072 1262 648 -139 -1530 -3032 -2843 -3005 -1659 -160 1110 1175 284 -872 -1257 -882 -560 -440 604 795 1652 2459 2434 2813 1350 1012 -133 -250 -784 604 436 1472 1050 1143 222 497 145 49 -1018 -1668 -1372 -1646 -671 189 756 736 425 296 669 757 1158 854 543 -1555 -2227 -2843 -2401 900000 -4142 -3001 -1778 -462 184 1588 1311 1206 442 209 -1128 -1000 -1652 -1487 -2123 -1373 -645 463 977 1108 730 1111 836 1127 1892 1431 1642 38 -1188 -2905 -1659 -1831 195 1383 1724 1378 267 -82 -205 436 -46 1056 1388 1930 2218 2234 1367 1307 211 -1050 -2007 -3044 -2490 -844 -622 1302 872 1315 706 1661 1632 1883 1913 1270 1311 44 121 -765 -1003 -1828 -1696 -1869 -316 -175 396 -899 -1118 -1942 -2412 -1642 -991 -917 -561 -851 -216 -222 -699 -412 -38 444 607 1583 1869 2011 1180 583 -121 -1334 -2639 -2438 -2619 -1492 -153 1112 1208 295 -902 -1286 -905 -588 -470 644 847 1747 2585 2611 3098 1420 1058 -138 -271 -834 639 437 1470 1060 1159 226 509 149 49 -1016 -1676 -1379 -1692 -707 201 811 806 476 335 761 864 1317 971 613 -1751 -2474 -3170 -2706 SO 20180728T101738.1Z 6783.428913 218 1 16.21 2 88.38 65.01 87.47 241.21 0.00 1 0.00 1 0 29 1.193e-02 1.169e-02 8.751e-04 8.714e-04 2.044460e+04 6.111067e+01 1.310891e+03 -6.000000e+00 6.292956e+02 287.09 -2.00 20.00 -2.00 505.45 0.00e+00 3.406981e-03 2.380065e-05 1.959923e-04 -6.000000e+00 3.298039e-04 287.09 -2.00 20.00 -2.00 500.98 0.00e+00 1.667042e+00 1.633563e-02 1.291011e-01 -6.000000e+00 2.283696e-01 232.58 -2.00 3.57 -2.00 502.49 0.00e+00 16.959 0.095 489.00 513.00 1 4.5944e+00 1.2485e-03 2.9758e-02 -6.0000e+00 1.7491e-02 -5.7404e-02 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