File name: Pandora103s1_Downsview_20180729_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010827.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180729_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180729 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180729T101005.0Z 6784.423669 215 1 32.01 2 89.77 63.88 77.60 233.14 0.00 1 0.00 1 0 15 1.765e-02 1.761e-02 1.603e-02 1.594e-02 1.462762e+04 1.122507e+03 9.482807e+02 -6.000000e+00 9.312461e+02 287.11 -2.00 20.00 -2.00 505.43 0.00e+00 2.048082e-03 4.332345e-04 1.099037e-04 -6.000000e+00 4.881138e-04 287.11 -2.00 20.00 -2.00 500.63 0.00e+00 2.201723e+00 3.061151e-01 9.461230e-02 -6.000000e+00 3.387600e-01 232.55 -2.00 3.57 -2.00 502.20 0.00e+00 19.989 0.156 489.00 513.00 1 8.1801e+00 2.3413e-02 3.6532e-02 -6.0000e+00 2.5926e-02 3.8290e-02 5.9708e-03 3.0119e-03 -6.0000e+00 6.8410e-03 2.7098e-05 7.1483e-04 1.1382e-03 8.7747e-05 -6.0000e+00 1.3708e-03 -5.3756e-03 -2.7529e-06 12 8 8 10 0 0 89.21 15.00 2.01 -0.00538 -0.00042 8 1 1 4 0 4000.000 22.09 15.00 19.16 900000 1391 -1915 -873 -1220 -2016 -1039 -804 1874 -127 -648 -2573 -668 -1959 -2887 -1715 613 -1669 23 1504 1399 1534 1167 -76 1516 -3263 2432 2362 -1608 -1296 258 -1162 -1429 -1400 1787 1613 1560 2201 -746 63 -331 2549 -978 599 558 3194 314 1874 1717 2635 83 -1989 -2713 -4649 609 2091 3804 -1195 1385 256 736 2522 39 -277 1943 -979 -1722 886 -3138 2604 -812 768 1373 -1535 -1357 2267 -776 -418 -145 -2302 418 -2203 -2423 271 -2273 -630 988 -1421 1239 1531 1317 163 24 3756 -376 1878 -600 388 2656 -1399 -2508 -3014 217 -809 -2989 2497 347 -1119 878 -2624 2806 -710 -198 2407 1681 1093 2021 2524 1905 -107 -1650 -1601 -1707 -204 -411 1848 1857 1816 -676 3638 -3175 -40 -653 -542 -2503 -54 -1056 -83 -1232 813 -3444 2563 -199 1237 1358 -369 481 -1172 -1730 -2711 -128 900000 1201 -1762 -831 -1203 -2042 -1067 -839 1913 -131 -659 -2633 -663 -1935 -2849 -1672 590 -1679 23 1555 1448 1586 1211 -80 1585 -3595 2530 2453 -1710 -1318 250 -1135 -1419 -1442 1870 1722 1649 2279 -785 65 -341 2578 -1036 633 598 3367 340 1976 1786 2665 83 -1972 -2654 -4620 589 2079 3835 -1282 1450 269 767 2598 41 -296 2022 -1033 -1792 884 -3227 2501 -792 736 1320 -1540 -1384 2235 -770 -402 -137 -2205 388 -2115 -2348 257 -2243 -621 961 -1406 1182 1447 1249 159 24 3615 -368 1726 -543 336 2203 -1183 -2113 -2579 187 -749 -2988 2420 342 -1100 831 -2575 2668 -711 -198 2361 1659 1086 2017 2564 1963 -111 -1699 -1605 -1678 -198 -407 1798 1812 1776 -674 3490 -3259 -39 -626 -517 -2429 -51 -1057 -84 -1275 839 -3754 2656 -213 1313 1441 -397 506 -1222 -1771 -2782 -130 SO 20180729T101414.0Z 6784.426551 219 1 32.01 2 89.10 64.59 78.18 233.94 0.00 1 0.00 1 0 29 1.155e-02 1.140e-02 2.037e-03 2.022e-03 1.831290e+04 1.400079e+02 1.181377e+03 -6.000000e+00 6.094041e+02 287.11 -2.00 20.00 -2.00 505.54 0.00e+00 3.721550e-03 5.551564e-05 2.092976e-04 -6.000000e+00 3.194185e-04 287.11 -2.00 20.00 -2.00 501.16 0.00e+00 1.914379e+00 3.782024e-02 1.229496e-01 -6.000000e+00 2.216611e-01 232.55 -2.00 3.57 -2.00 502.67 0.00e+00 18.747 0.128 489.00 513.00 1 6.0397e+00 2.8840e-03 3.3888e-02 -6.0000e+00 1.6965e-02 -4.7157e-02 7.3547e-04 3.4478e-03 -6.0000e+00 4.4761e-03 2.7278e-04 7.5394e-04 1.4133e-04 1.2261e-04 -6.0000e+00 8.9697e-04 4.4021e-03 -5.7744e-05 12 8 8 10 0 0 99.30 15.00 3.69 0.00440 0.00963 8 1 1 4 0 4000.000 22.09 15.00 19.16 900000 -3643 -2439 -1194 -223 731 917 1439 1165 662 -5 -41 -896 -960 -1379 -1300 -1248 -259 429 859 654 926 708 638 872 911 1398 793 -43 -1524 -2047 -1878 -1601 144 1056 1417 1079 341 -285 -269 71 -345 853 875 1572 1800 1314 1185 792 379 -860 -1986 -2622 -1935 -1680 -223 500 1089 1039 1016 812 1457 1204 1349 955 696 195 -273 -188 -873 -1262 -1380 -927 -589 213 230 -523 -1731 -1116 -1819 -1400 -854 -723 -1047 -579 -646 -386 -438 -168 68 329 439 1038 1615 1304 1256 496 -285 -651 -2016 -2480 -2277 -1324 -257 588 955 248 -663 -1238 -1133 -403 -289 826 833 1332 1811 2082 1812 1370 372 333 -406 -134 364 652 502 822 416 474 383 676 -294 -562 -1297 -1318 -1111 -362 203 281 868 460 751 380 817 988 1210 79 -443 -2091 -2565 -2275 900000 -3215 -2204 -1031 -198 656 843 1341 1095 620 -5 -37 -818 -863 -1234 -1162 -1129 -238 406 829 634 895 688 623 861 907 1386 790 -43 -1470 -1916 -1753 -1516 139 1068 1457 1103 347 -289 -270 71 -351 871 909 1651 1907 1400 1253 829 392 -872 -1974 -2573 -1884 -1681 -230 529 1083 1035 1008 806 1452 1216 1367 969 698 193 -267 -183 -843 -1204 -1318 -891 -574 210 227 -510 -1664 -1051 -1714 -1310 -801 -683 -999 -559 -635 -379 -428 -162 65 314 425 1024 1594 1256 1158 442 -266 -598 -1845 -2249 -2086 -1164 -239 580 963 252 -670 -1240 -1140 -413 -302 861 871 1386 1880 2196 1972 1519 413 361 -431 -139 378 687 534 878 448 509 414 731 -314 -590 -1368 -1394 -1194 -372 213 297 932 505 830 426 915 1105 1347 88 -485 -2277 -2794 -2507 SO 20180729T101809.8Z 6784.429281 223 1 13.68 2 88.46 65.26 78.73 234.69 0.00 1 0.00 1 0 22 8.889e-03 8.736e-03 3.693e-04 3.680e-04 1.756056e+04 2.516854e+01 1.138856e+03 -6.000000e+00 4.690532e+02 287.11 -2.00 20.00 -2.00 505.43 0.00e+00 3.653004e-03 1.005814e-05 2.115372e-04 -6.000000e+00 2.458532e-04 287.11 -2.00 20.00 -2.00 501.00 0.00e+00 1.648034e+00 6.922666e-03 1.136596e-01 -6.000000e+00 1.706069e-01 232.55 -2.00 3.57 -2.00 502.50 0.00e+00 17.164 0.098 489.00 513.00 1 2.8055e+00 5.2925e-04 2.9818e-02 -6.0000e+00 1.3057e-02 -4.6770e-02 1.3501e-04 3.1427e-03 -6.0000e+00 3.4449e-03 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