File name: Pandora103s1_Downsview_20180730_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010728.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180730_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180730 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180730T101124.0Z 6785.424583 206 1 32.01 2 89.73 64.27 69.08 226.21 0.00 1 0.00 1 0 15 2.840e-02 2.816e-02 2.496e-02 2.481e-02 8.528226e+03 1.640613e+03 6.116435e+02 -6.000000e+00 1.498513e+03 287.12 -2.00 20.00 -2.00 505.39 0.00e+00 3.289653e-03 6.733620e-04 1.881559e-04 -6.000000e+00 7.854055e-04 287.12 -2.00 20.00 -2.00 500.53 0.00e+00 2.736596e+00 4.781621e-01 5.368840e-02 -6.000000e+00 5.447590e-01 232.51 -2.00 3.57 -2.00 502.12 0.00e+00 19.926 0.154 489.00 513.00 1 8.5996e+00 3.6607e-02 3.5927e-02 -6.0000e+00 4.1696e-02 5.0212e-02 9.3707e-03 2.3146e-03 -6.0000e+00 1.0996e-02 1.7136e-05 2.5181e-03 1.8219e-03 7.2345e-05 -6.0000e+00 2.2048e-03 -1.5283e-02 8.7442e-05 12 8 8 10 0 0 -2.56 14.99 3.99 -0.01528 0.00218 8 1 1 4 0 4000.000 22.19 14.99 19.20 900000 -287 -3563 -2495 53 497 -2871 -600 359 -406 -2408 2745 3472 -3806 2376 603 3260 -5202 2120 -4144 2415 1007 -1523 -2597 1269 -573 1304 4710 -261 -2543 2266 -1282 -95 -1722 -475 -49 -321 4999 -2001 5837 77 6600 -1822 -1783 78 1157 1750 6888 201 -3597 -1035 -3871 -561 -2341 -3138 1667 1973 1516 3391 -2522 3803 1109 6140 536 2564 2282 -2388 -625 -2810 -7162 2548 -1510 -2050 1102 660 -2395 -467 2481 -173 1513 814 -95 -3110 -1495 -2873 3279 -886 -1033 -4557 419 1696 504 -1529 2802 1134 7664 -2279 2698 2570 -6398 3778 -4042 -630 -3421 1795 -1004 918 -1570 -1504 -750 5247 4419 810 -2080 1896 80 1061 2456 2795 -1328 555 -1440 2600 1250 2442 2710 -4217 -4974 5214 -1734 -5672 327 -4505 948 -744 897 -2567 2472 3477 4060 633 1862 1266 2536 1195 -2748 -782 -4618 596 -4839 -675 900000 -257 -3406 -2468 53 502 -3062 -635 378 -425 -2519 2700 3344 -3867 2251 581 3093 -5490 2156 -4566 2492 1053 -1634 -2821 1341 -621 1381 4810 -274 -2619 2155 -1262 -94 -1799 -512 -54 -346 5045 -2134 5704 80 6455 -1960 -1945 85 1252 1879 6948 213 -3872 -1051 -3917 -539 -2291 -3183 1681 2042 1594 3496 -2734 3864 1166 6184 570 2656 2332 -2501 -633 -2879 -7541 2401 -1480 -2038 1078 659 -2456 -459 2306 -163 1393 753 -90 -3030 -1439 -2840 3088 -869 -1008 -4562 398 1597 487 -1541 2725 1099 6767 -2151 2354 2191 -5812 3066 -3576 -558 -3294 1715 -993 882 -1515 -1428 -712 4801 4154 798 -2124 1868 80 1071 2479 2814 -1368 551 -1423 2438 1200 2348 2605 -4349 -5166 4881 -1747 -5934 315 -4464 884 -702 846 -2583 2417 3405 4012 653 1904 1311 2607 1247 -2969 -815 -4851 580 -4941 -672 SO 20180730T101544.0Z 6785.427593 210 1 32.01 2 89.02 65.02 69.63 227.15 0.00 1 0.00 1 0 15 1.523e-02 1.507e-02 6.971e-03 6.915e-03 1.356382e+04 4.761343e+02 8.538301e+02 -6.000000e+00 8.035854e+02 287.12 -2.00 20.00 -2.00 505.58 0.00e+00 3.949364e-03 1.903402e-04 2.082196e-04 -6.000000e+00 4.211921e-04 287.12 -2.00 20.00 -2.00 501.07 0.00e+00 1.774486e+00 1.300069e-01 1.033376e-01 -6.000000e+00 2.922476e-01 232.51 -2.00 3.57 -2.00 502.61 0.00e+00 18.572 0.125 489.00 513.00 1 7.5093e+00 9.9396e-03 3.2933e-02 -6.0000e+00 2.2367e-02 -1.5798e-02 2.4984e-03 2.9249e-03 -6.0000e+00 5.9013e-03 6.5218e-05 1.6569e-03 4.9742e-04 9.2460e-05 -6.0000e+00 1.1827e-03 -8.3095e-04 -2.3897e-05 12 8 8 10 0 0 27.79 15.00 4.53 -0.00083 0.01066 8 1 1 4 0 4000.000 22.19 15.00 19.18 900000 -5012 -3902 -1746 -1165 -535 773 942 764 661 -905 168 -559 -1941 -2193 -2309 -1163 858 686 2153 731 449 1065 1682 671 595 1313 949 -75 -1612 -1443 -2629 -2114 304 1782 427 570 79 754 291 -204 -124 1957 1266 2245 2570 582 1593 1756 1687 -621 -3174 -1641 -1935 -1839 1181 509 1011 1189 783 335 1413 801 2419 1154 2529 -997 -249 254 -1407 -612 -1476 -789 -547 -115 -534 234 -1889 -881 -1598 -597 -2435 -561 -1029 53 -342 -796 -2019 296 -1110 -109 17 1916 3074 1769 492 362 -648 -829 -3362 -2726 -1195 -1262 -112 644 2139 -356 -342 -1152 -653 -649 885 -415 1152 1453 2635 2143 1825 2131 -661 856 250 -1243 1543 941 1743 487 -44 1237 194 323 -578 -693 -1884 -2010 -2755 -1916 -42 711 498 1805 850 -49 221 2020 2347 23 -1597 -2272 -3029 -2820 900000 -4293 -3427 -1573 -1080 -504 736 911 744 638 -870 158 -523 -1811 -2033 -2143 -1079 800 665 2102 724 446 1054 1662 678 607 1328 962 -76 -1581 -1366 -2518 -2048 300 1820 451 594 82 766 294 -207 -128 2002 1327 2371 2733 631 1694 1839 1734 -633 -3218 -1608 -1902 -1862 1212 498 1001 1175 774 332 1399 807 2405 1157 2467 -989 -241 243 -1351 -574 -1396 -749 -527 -112 -525 223 -1794 -817 -1485 -549 -2299 -524 -971 51 -331 -775 -1978 280 -1062 -104 17 1859 2973 1694 460 327 -572 -718 -2927 -2326 -1016 -1117 -104 629 2100 -357 -337 -1127 -641 -653 895 -430 1182 1491 2681 2228 1948 2284 -719 898 258 -1276 1554 970 1793 510 -47 1285 205 342 -603 -709 -1943 -2075 -2913 -2077 -46 776 555 2014 964 -57 255 2300 2657 26 -1808 -2528 -3381 -3188 SO 20180730T101949.8Z 6785.430437 214 1 33.56 2 88.35 65.72 70.15 228.02 0.00 1 0.00 1 0 22 1.398e-02 1.370e-02 8.138e-04 8.085e-04 1.653596e+04 5.501283e+01 1.076911e+03 -6.000000e+00 7.376025e+02 287.12 -2.00 20.00 -2.00 505.49 0.00e+00 4.491540e-03 2.217037e-05 2.445925e-04 -6.000000e+00 3.866055e-04 287.12 -2.00 20.00 -2.00 501.22 0.00e+00 1.542209e+00 1.510048e-02 1.119235e-01 -6.000000e+00 2.682189e-01 232.51 -2.00 3.57 -2.00 502.69 0.00e+00 16.886 0.094 489.00 513.00 1 5.0347e+00 1.1559e-03 2.9298e-02 -6.0000e+00 2.0529e-02 -6.9838e-02 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