File name: Pandora103s1_Downsview_20180802_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010726.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180802_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180802 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180802T101421.0Z 6788.426632 205 1 32.01 2 89.76 65.33 45.45 197.26 0.00 1 0.00 1 0 22 5.610e-02 5.404e-02 4.548e-02 4.459e-02 8.800696e+03 3.065066e+03 2.097892e+02 -6.000000e+00 2.961602e+03 287.18 -2.00 20.00 -2.00 505.28 0.00e+00 4.457737e-03 1.213617e-03 3.037898e-04 -6.000000e+00 1.551482e-03 287.18 -2.00 20.00 -2.00 499.94 0.00e+00 3.797447e+00 8.862604e-01 1.381216e-01 -6.000000e+00 1.072707e+00 232.39 -2.00 3.57 -2.00 501.60 0.00e+00 19.976 0.155 489.00 513.00 1 9.1022e+00 6.8109e-02 3.7663e-02 -6.0000e+00 8.2178e-02 9.5064e-02 1.7384e-02 2.9866e-03 -6.0000e+00 2.1536e-02 9.3165e-06 5.1916e-04 3.2703e-03 6.5330e-05 -6.0000e+00 4.3476e-03 -1.9766e-02 1.8945e-04 12 8 8 10 0 0 94.36 15.00 4.40 -0.01977 -0.01617 8 1 1 4 0 4000.000 22.09 15.00 19.08 -13909 2306 -9411 6791 -234 10613 -375 5819 -2089 7256 -3905 9548 779 1999 -5376 3441 -1507 2547 3141 -1379 -5300 -5118 1971 412 -2510 -258 -750 -1244 10494 -6899 -1592 -2584 2827 -6510 -2982 -360 6006 -1882 5401 12217 5406 -7915 -3266 6266 -656 2561 1609 1596 -498 3050 -2582 -1967 -1205 -3423 3922 -2428 2776 488 897 -1320 10504 3854 -491 2055 437 6874 -3754 -1552 5176 7547 -6088 -6107 5277 -9639 -3912 -888 -6692 -4348 3198 2902 11385 -3960 4600 -3922 -3887 2013 781 4233 -2210 2658 187 -3165 -12148 -146 -3136 4112 -9849 8519 -7231 3497 1430 12234 -8509 18716 4103 8358 -362 2582 635 4888 -5483 -7796 10755 3806 -3319 5041 12568 -1799 7412 -4452 3107 -796 7396 -5584 -26 -11356 9467 -8326 4920 3048 -4970 -1346 4082 -4408 3776 -3015 535 476 2247 6328 -1154 2828 1994 718 -5467 -9289 2333 -2961 2638 4115 42 -15195 2175 -10284 6626 -252 10466 -421 6237 -2421 7577 -4448 9414 825 2053 -5865 3441 -1594 2649 3357 -1570 -6246 -6015 2160 459 -2907 -295 -857 -1420 10498 -7814 -1653 -2704 2845 -7457 -3451 -411 6367 -2120 5593 11697 5527 -9286 -3711 6580 -747 2844 1798 1761 -552 3192 -2759 -2022 -1206 -3493 3825 -2622 2929 532 973 -1450 10240 4032 -538 2198 471 6838 -4049 -1610 4971 6967 -6295 -6301 4907 -10500 -4091 -898 -6973 -4307 2902 2617 9424 -3829 4107 -3809 -3815 1883 738 3835 -2108 2404 173 -3073 -13161 -141 -3071 3637 -9673 6779 -6536 2776 1139 8844 -7771 13836 3645 7178 -334 2271 560 4160 -5279 -7825 9122 3482 -3261 4578 10735 -1793 6750 -4474 2840 -738 6248 -5402 -24 -11804 8059 -8427 4355 2762 -4865 -1243 3501 -4069 3204 -2771 490 444 2083 5720 -1131 2676 1912 701 -5672 -9956 2194 -2845 2337 3573 39 SO 20180802T101837.0Z 6788.429595 209 1 32.02 2 89.06 66.06 45.67 198.70 0.00 1 0.00 1 0 15 2.480e-02 2.473e-02 2.089e-02 2.075e-02 7.291272e+03 1.354682e+03 4.980309e+02 -6.000000e+00 1.309185e+03 287.18 -2.00 20.00 -2.00 505.34 0.00e+00 2.152354e-03 5.625302e-04 1.205126e-04 -6.000000e+00 6.861114e-04 287.18 -2.00 20.00 -2.00 500.35 0.00e+00 2.290382e+00 4.028759e-01 4.993057e-02 -6.000000e+00 4.761502e-01 232.39 -2.00 3.57 -2.00 501.96 0.00e+00 18.664 0.127 489.00 513.00 1 8.6446e+00 3.0826e-02 3.2048e-02 -6.0000e+00 3.6441e-02 7.3306e-02 7.9644e-03 2.0833e-03 -6.0000e+00 9.6183e-03 2.0574e-05 2.3408e-03 1.5381e-03 5.6710e-05 -6.0000e+00 1.9266e-03 -1.1398e-02 1.0716e-05 12 8 8 10 0 0 2.72 15.00 2.23 -0.01140 0.00484 8 1 1 4 0 4000.000 22.09 15.00 19.08 900000 -3564 -2761 918 297 2750 -1092 1432 526 962 -2127 -435 -2644 111 -4901 -2086 -2721 2481 -1185 1509 239 -2046 4176 3459 4703 -917 4489 -1870 1268 -4300 1183 -3455 -2667 1243 -484 392 2205 -1065 1044 1517 -1024 -1471 -328 846 -777 3189 1882 2642 -854 4904 -1886 -3385 -2826 914 -5423 4322 -261 1753 -1138 2968 -713 -1485 3365 812 841 1161 1315 -1973 4111 -4221 -3206 -1325 4381 -2998 -444 1383 3389 297 3473 -5354 617 -1635 -1409 1340 -3596 2703 1672 412 229 -1684 1879 2715 239 3159 -1545 2157 -3342 1487 907 1206 779 854 -3210 2465 1324 -1274 1542 -22 -4071 1817 3553 -1169 -4635 827 3231 -4252 779 -896 4417 -757 -2395 421 500 -2653 1017 -1628 2340 -2246 3293 -3121 37 1911 -2288 2236 -2975 43 -377 3357 195 2984 -3415 4258 234 584 -585 1487 -2939 2858 -162 -5238 -1296 900000 -3386 -2687 901 302 2782 -1173 1525 566 1021 -2280 -453 -2774 111 -5111 -2115 -2800 2484 -1272 1611 258 -2258 4336 3622 4907 -1016 4699 -2074 1342 -4600 1158 -3531 -2743 1277 -530 432 2358 -1157 1097 1567 -1081 -1570 -351 905 -856 3402 2029 2791 -918 4886 -1941 -3421 -2783 867 -5605 4233 -275 1836 -1223 3043 -754 -1592 3466 858 882 1195 1324 -2016 3921 -4302 -3180 -1288 4065 -3033 -446 1362 3196 281 3145 -5244 569 -1555 -1345 1250 -3566 2553 1596 396 219 -1635 1766 2563 236 3059 -1539 2014 -3199 1319 789 1021 652 721 -2915 2235 1268 -1263 1471 -21 -3947 1669 3277 -1150 -4769 814 3110 -4410 778 -921 4313 -765 -2407 403 471 -2598 974 -1601 2219 -2225 3073 -3114 36 1778 -2169 2010 -2796 40 -361 3164 192 2895 -3557 4132 238 593 -603 1498 -3039 2714 -154 -5191 -1251 SO 20180802T102251.0Z 6788.432535 213 1 32.01 2 88.36 66.79 45.90 200.11 0.00 1 0.00 1 0 22 1.284e-02 1.263e-02 7.873e-03 7.839e-03 1.357173e+04 5.392907e+02 8.839469e+02 -6.000000e+00 6.777159e+02 287.18 -2.00 20.00 -2.00 505.43 0.00e+00 4.086295e-03 2.133851e-04 2.159731e-04 -6.000000e+00 3.552076e-04 287.18 -2.00 20.00 -2.00 500.77 0.00e+00 1.723096e+00 1.496228e-01 9.306295e-02 -6.000000e+00 2.464167e-01 232.39 -2.00 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