File name: Pandora103s1_Downsview_20180813_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010716.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180813_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180813 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180813T102646.8Z 6799.435264 358 1 13.61 2 89.69 69.87 113.69 52.88 0.00 1 0.00 1 0 43 2.257e-02 2.213e-02 2.445e-03 2.429e-03 1.783955e+04 1.682952e+02 1.122405e+03 -6.000000e+00 1.192230e+03 287.40 -2.00 20.00 -2.00 505.51 0.00e+00 3.829349e-03 6.665826e-05 1.855618e-04 -6.000000e+00 6.244757e-04 287.40 -2.00 20.00 -2.00 501.15 0.00e+00 1.978612e+00 4.527699e-02 1.241831e-01 -6.000000e+00 4.312544e-01 231.98 -2.00 3.57 -2.00 502.65 0.00e+00 19.869 0.153 489.00 513.00 1 5.6760e+00 3.4708e-03 3.6961e-02 -6.0000e+00 3.3041e-02 -5.9540e-02 8.6909e-04 3.5003e-03 -6.0000e+00 8.6583e-03 3.3414e-04 1.5218e-03 1.6961e-04 1.1963e-04 -6.0000e+00 1.7490e-03 -8.7683e-03 1.2045e-04 12 9 9 12 1 1 -1184.40 15.00 9.63 -0.00877 0.00179 3 2 1 4 0 3360.120 22.19 15.00 19.29 -8813 -7186 -4910 -2354 -788 124 1175 2229 2357 936 -496 -849 -1912 -2874 -2925 -3092 -1956 -543 1795 2013 1740 1359 1911 1736 2428 2553 2294 2265 498 -1763 -3323 -3540 -1885 261 2424 2556 1562 957 454 -209 -47 552 1101 2279 3067 3266 3118 2331 1758 57 -1530 -3069 -4045 -3225 -1891 733 2163 2568 2162 1639 1573 2498 2563 2809 2722 1011 759 -342 -436 -1318 -2424 -2300 -1315 -298 482 -90 -917 -2408 -2343 -3026 -2563 -1035 -1008 -1286 -539 -504 64 -660 -915 -353 -192 1660 3227 3173 2223 1550 1046 -253 -1635 -3855 -3928 -3411 -1903 481 1842 1170 -149 -1171 -1863 -1642 -670 -281 1222 2028 2600 3200 3998 3954 2322 964 -96 -530 -980 1016 1143 1611 1633 571 513 725 -292 -1068 -1283 -2858 -2737 -2194 -914 186 1241 987 924 233 929 1452 1661 1596 -83 -2019 -4147 -4687 -3569 -7944 -6480 -4498 -2206 -702 112 1076 2056 2180 869 -458 -780 -1753 -2624 -2652 -2814 -1784 -502 1683 1923 1667 1309 1836 1681 2368 2507 2258 2227 490 -1699 -3157 -3380 -1805 256 2444 2613 1596 972 459 -211 -47 527 1063 2214 3009 3230 3086 2303 1725 56 -1473 -2914 -4071 -3231 -1814 716 2151 2580 2182 1656 1591 2532 2623 2879 2781 1036 765 -344 -436 -1311 -2404 -2284 -1309 -299 490 -92 -920 -2394 -2301 -2974 -2504 -1005 -987 -1273 -540 -512 65 -668 -917 -350 -191 1652 3239 3192 2189 1472 958 -227 -1462 -3465 -3495 -3074 -1771 469 1879 1156 -149 -1162 -1839 -1635 -679 -289 1247 2060 2628 3229 4092 4163 2509 1043 -102 -553 -1010 1037 1186 1676 1711 607 544 774 -315 -1132 -1340 -3035 -2912 -2374 -1011 196 1309 1066 1015 260 1039 1623 1855 1778 -92 -2248 -4626 -5255 -4026 SO 20180813T103117.0Z 6799.438391 362 1 32.01 2 88.92 70.65 113.08 53.83 0.00 1 0.00 1 0 22 1.462e-02 1.452e-02 1.124e-02 1.116e-02 1.599266e+04 8.034733e+02 1.034888e+03 -6.000000e+00 7.723809e+02 287.40 -2.00 20.00 -2.00 505.37 0.00e+00 1.985389e-03 3.027113e-04 9.789785e-05 -6.000000e+00 4.047524e-04 287.40 -2.00 20.00 -2.00 500.40 0.00e+00 1.793360e+00 2.163000e-01 9.780368e-02 -6.000000e+00 2.804709e-01 231.98 -2.00 3.57 -2.00 502.00 0.00e+00 18.344 0.120 489.00 513.00 1 8.0720e+00 1.6537e-02 3.1941e-02 -6.0000e+00 2.1469e-02 6.0911e-02 4.2269e-03 2.9332e-03 -6.0000e+00 5.6641e-03 3.9136e-05 3.6438e-03 7.8371e-04 8.9587e-05 -6.0000e+00 1.1358e-03 -1.4531e-02 4.6740e-05 12 8 8 10 0 0 21.19 14.99 2.36 -0.01453 0.01074 8 1 1 4 0 4000.000 22.19 14.99 19.30 900000 -4407 -2295 -2659 -960 -1015 -634 740 1886 -1932 804 -686 799 -2043 -3738 -1398 -901 -943 -417 3226 2056 2156 13 1273 -735 1214 576 1594 -15 -243 565 585 -2250 839 1110 953 1894 682 -949 -1305 -283 -672 1623 1205 1700 892 123 1638 1625 899 -1369 -2790 -3560 -669 -1653 352 917 1300 1538 1684 878 -353 797 1118 -627 314 365 1217 618 -795 -759 -1123 1113 1234 -343 -804 -1507 824 -1686 -393 -90 -740 -44 -174 567 546 943 100 -102 -664 1676 189 3696 -280 -1057 915 42 -235 -502 1050 -2288 -2469 -1563 970 343 -348 -1129 -1023 -2535 885 -1614 1607 1121 1576 200 880 3187 1590 1870 376 -2275 -916 -1776 1838 1121 1112 -674 450 2071 -515 504 -44 109 -1617 -2572 -1434 -1524 120 1830 1165 223 -1168 1160 -442 320 268 559 50 -2647 -2093 -3058 900000 -4189 -2210 -2682 -981 -1056 -672 786 1985 -2084 829 -710 804 -2076 -3824 -1398 -907 -972 -442 3369 2168 2271 14 1354 -804 1310 623 1700 -15 -248 554 574 -2304 867 1196 1041 2023 726 -1013 -1383 -297 -711 1703 1286 1830 973 135 1746 1706 930 -1400 -2803 -3536 -647 -1659 361 961 1373 1617 1755 919 -377 847 1184 -671 327 373 1214 614 -788 -741 -1101 1077 1212 -348 -815 -1500 782 -1617 -369 -84 -700 -41 -166 545 532 914 97 -98 -637 1576 183 3525 -277 -1022 833 37 -200 -422 852 -1895 -2078 -1361 880 330 -343 -1113 -989 -2447 832 -1586 1553 1093 1531 196 859 3094 1603 1891 379 -2301 -889 -1706 1716 1068 1063 -657 434 1956 -501 484 -42 101 -1512 -2426 -1362 -1493 117 1785 1163 227 -1215 1187 -461 330 275 564 49 -2628 -2058 -3074 SO 20180813T103530.0Z 6799.441320 366 1 32.02 2 88.21 71.37 112.50 54.72 0.00 1 0.00 1 0 22 1.107e-02 1.093e-02 8.979e-03 8.900e-03 1.334168e+04 6.309279e+02 8.843654e+02 -6.000000e+00 5.849342e+02 287.40 -2.00 20.00 -2.00 505.32 0.00e+00 1.834576e-03 2.412081e-04 1.015777e-04 -6.000000e+00 3.065209e-04 287.40 -2.00 20.00 -2.00 500.21 0.00e+00 1.966865e+00 1.744858e-01 7.690554e-02 -6.000000e+00 2.124041e-01 231.98 -2.00 3.57 -2.00 501.83 0.00e+00 16.505 0.087 489.00 513.00 1 8.0844e+00 1.3350e-02 2.7113e-02 -6.0000e+00 1.6258e-02 7.0683e-02 3.4323e-03 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